Sharif Digital Repository

Different concentrations of CaF2 were incorporated in mica glass-ceramics to evaluate their effects on the crystallization and microstructure. The kinetics of phase transformations, and the microstructures of the final crystalline phase were found to be dependent on the concentration of nucleation agents. The results showed that CaF2 in high concentration had a synergistic effect and enhanced the formation of interlocked mica crystals. Non-isothermal DTA experiments showed that the crystallization activation energies of base glasses were changed in the range of 235-405 kJ/mol, while the crystallization activation energies of samples with addition of CaF2 were changed in the range of 419-747... 

CeO 2-TiO 2 nanoparticles were prepared by the sol-gel process using 2-hydroxylethylammonium formate as room-temperature ionic liquid and calcined at different temperatures (500-700°C). CeO 2-TiO 2-graphene nanocomposites were prepared by hydrothermal reaction of graphene oxide with CeO 2-TiO 2 nanoparticles in aqueous solution of ethanol. The photocatalysts were characterized by X-ray diffraction, BET surface area, diffuse reflectance spectroscopy, scanning electron microscopy, and Fourier transformed infrared techniques. The results demonstrate that the room-temperature ionic liquid inhibits the anatase-rutile phase transformation. This effect was promoted by addition of CeO 2 to TiO 2.... 

Turn-to-turn fault (TTF) is one of the most prominent reasons for transformer failure. This fault typically initiates by involving only a few turns and can progress to a much more severe fault in a very short time. Therefore, it is critical for the transformer protective relays to detect the TTF in the early stages of its occurrence. The conventional differential relays, in general, cannot detect a minor TTF, and thus, a supplementary protective algorithm is usually required to improve the sensitivity of differential relays against TTFs. This paper proposes a percentage-based fault-related incremental currents method for the precise detection of a low-level TTF. The proposed method employs... 

The bonding temperature is an important parameter for optimization of the Transient Liquid Phase (TLP) bonding process in order to achieve a sound joint with good mechanical properties. However, the bonding temperature used can also be restricted by the microstructural stability of the base metal. In this study, the effect of bonding temperature (1050-1200 °C) on the joint microstructure and mechanical properties was studied for TLP bonding of FSX-414 superalloy using MBF-80 interlayer with thickness of 50 μm. Increasing bonding temperature from 1050 to 1150 °C caused reduction in the time required for complete isothermal solidification in agreement with models based on the diffusion induced... 

The technological and industrial needs for development of fully dense nanocomposites have led to significant advances in spark plasma sintering (SPS) technique and its enhanced forms. This technique has opened up a new prospect over carbon nanotube (CNT)-metal matrix nanocomposites (MMNCs) with superior physical or mechanical characteristics. To date, a large number of authentic papers have been published over this ongoing field, but have not been comprehensively reviewed. The pertinent research works cover some significant aspects of CNT-MMNCs requiring a concise review on (i) the potential phase transformations of pure CNTs and microstructure evolution; (ii) the novel approaches for... 

The inclusion of carbon nanotubes (CNTs) into metallic systems has been the main focus of recent literature. The aim behind this approach has been the development of a new property or improvement of an inferior one in CNT-dispersed metal matrix nanocomposites. Although it has opened up new possibilities for promising engineering applications, some practical challenges have restricted the full exploitation of CNTs’ unique characteristics. Non-uniform dispersion of CNTs in the metallic matrix, poor interfacial adhesion at the CNT/metal interface, the unfavorable chemical reaction of CNTs with the matrix, and low compactability are the most significant challenges, requiring more examination.... 

Titanium dioxide nanopowders were synthesized by the diffusion controlled sol-gel process (LaMer model) and characterized by DTA-TG, XRD, and SEM. The prepared TiO 2 nanoparticles have uniform size and morphology, and the phase transformation kinetics of obtained material was studied by interpretation of the X-ray diffraction patterns peaks on the base of Avrami equation. The stating point of anatase-rutile phase transformation temperature in the prepared nanoparticles was found between 100 and 200 C. A decreasing trend on the intensity of X-ray peaks of anatase phase was observed up to 600 C when the presence of the rutile phase became predominant. Results indicated that the transition... 

Porous shape memory alloys (SMAs) exhibit the interesting characteristics of porous metals together with shape memory effect and pseudo-elasticity of SMAs that make them appropriate for biomedical applications. In this paper, a 3-D phenomenological constitutive model for the pseudo-elastic behavior and shape memory effect of porous SMAs is developed within the framework of irreversible thermodynamics. Comparing to micromechanical and computational models, the proposed model is computationally cost effective and predicts the behavior of porous SMAs under proportional and non-proportional multiaxial loadings. Considering the pressure dependency of phase transformation in porous SMAs, proper... 

Porous shape memory alloys are a class of very interesting materials exhibiting features typical of porous metals and of shape memory alloys. In contrast to dense shape memory alloys, considerable plastic strain accumulates in porous shape memory alloys even during phase transformation. Moreover, due to the microstructure of porous materials, phase transformation and plasticity phenomena are significantly pressure-dependent. In this article, we propose a three-dimensional phenomenological constitutive model for the thermomechanical behavior of porous shape memory alloys able to predict shape memory effect, pseudo-elastic behavior and plastic behavior under proportional as well as... 

In this study, a particular nickel-based superalloy has been studied by transmission electron microscopy and the results are discussed in terms of phase transformations that may have taken place. The alloy has been found to consist of three major phases; a FCC γ phase containing a random distribution of nearly spherical γ′ - Ni3Al(Ti) - precipitates and elongated thin Ni3Ti(Ta) platelets with a hexagonal structure. The orientation relationships between the different phases have been determined; loss of coherency and possible occurrence of misfit-relieving interfacial dislocations are discussed and compared with experimental observations, and possible mechanisms of phase transformations are... 

Abstract: Nickel–titanium (NiTi) nanoparticles are ultrafine smart materials manifesting shape memory effect at very small scales. We have produced NiTi nanoparticles surrounded by an amorphous carbon shell using an innovative spark discharge system. The resulting nanoparticles were studied using various characterization methods to systematically study their size, morphology, size distribution, composition, structure, and thermal behavior. Field-emission scanning electron microscopy and dynamic light-scattering results indicated that the average size of the produced nanoparticles was about 13 nm. High-resolution transmission electron microscopy, energy-dispersive spectroscopy (EDS), and... 

This paper presents a new phenomenological constitutive model for shape memory alloys, developed within the framework of irreversible thermodynamics and based on a scalar and a tensorial internal variable. In particular, the model uses a measure of the amount of stress-induced martensite as scalar internal variable and the preferred direction of variants as independent tensorial internal variable. Using this approach, it is possible to account for variant reorientation and for the effects of multiaxial non-proportional loadings in a more accurate form than previously done. In particular, we propose a model that has the property of completely decoupling the pure reorientation mechanism from... 

Most devices based on shape memory alloys experience both finite deformations and non-proportional loading conditions in engineering applications. This motivates the development of constitutive models considering finite strain as well as martensite variant reorientation. To this end, in the present article, based on the principles of continuum thermodynamics with internal variables, a three-dimensional finite strain phenomenological constitutive model is proposed taking its basis from the recent model in the small strain regime proposed by Panico and Brinson (J Mech Phys Solids 55:2491-2511, 2007). In the finite strain constitutive model derivation, a multiplicative decomposition of the... 

Bi2O3 compositions were prepared to investigate the effect of rare earth metal oxides as co-dopants on phase stability of bismuth oxide. Compositions containing 9-14 mol% of Y2O3 and Er2O3 were synthesized by solid state reaction. The structural characterization was carried out using X-ray powder diffraction. The XRD results show that the samples containing 12 and 14 mol% total dopants had cubic structure, whereas the samples with lower dopant concentrations were tetragonal. Comparing the lattice parameters of the cubic phases of (Bi 2O3)0.88(Y2O3) 0.06(Er2O3)0.06 and (Bi 2O3)0.86(Y2O3) 0.07(Er2O3)0.07 revealed that lattice parameter decreases by increasing the dopant concentration. The XRD... 

This paper investigates the metallurgical and mechanical response of 2304 duplex stainless steel-as an interesting candidate for automotive body-in-white applications-to resistance spot welding. The results showed the high cooling rate associated with the resistance spot welding process suppressed the postsolidification ferrite-austenite transformation leading to improper ferrite-austenite phase balance with a reduced volume fraction of austenite and consequent precipitation of chromium-rich nitrides. The effects of welding current, as the key parameter determining the weld heat input, on the austenite volume fraction and precipitation are discussed. The minimum fusion zone hardness... 

Implementation of new materials in automotive body-in-white requires through knowledge of their metallurgical response to welding process thermal cycle. This two-part paper aims at understanding the physical and mechanical metallurgy of stainless steels, as interesting candidates for automotive application, during resistance spot welding. The second part addresses the phase transformations in the heat affected zone of three types of stainless steels including austenitic, ferritic and duplex steels. Failure modes and mechanical properties of stainless steel resistance spot welds are discussed. The peak load and energy absorption of stainless steel resistance spot welds are compared with... 

In this study, the effects of stress-assisted heat treatment on the microstructure and phase transformation of a Ti-rich (Ti-49.52 at.% Ni) shape memory alloy were investigated. For this purpose, the alloy was heat treated at temperature of 500 °C for 10 h under applied stresses of 100 and 200 MPa. XRD, TEM, and repeated thermal cycling were employed to study the microstructure and transformation behavior of the heat-treated materials. Room temperature XRD diffractogram of the stress-free heat-treated material showed a weak reflection of austenite (B2), while that for the stress-assisted heat-treated materials had a high intensity implying the presence of residual austenite in the...