Sharif Digital Repository

This study investigates the effects of polymer concentration and solvent type on the pore size distribution (PSD) of the fabricated gas-liquid membrane contactors (MCs). Eighteen flat-sheet MCs are fabricated using polysulfone (PSf) and polyethersulfone (PES) polymers, with polymer concentration of 10%, 15%, and 20%. Dimethylformamide (DMF) and n-methyl-2-pyrrolidone (NMP) solvents are used to prepare the polymeric solutions. The role of polyvinylpyrrolidone (PVP) on the mean pore size of MCs is also studied. Scanning electron microscope (SEM) analysis is applied to visualize the pore system of the fabricated MCs. Image processing technique is used to obtain the PSD of the fabricated MCs... 

This study investigates the effect of stress magnitude and stress history on porosity and permeability values of anhydride and carbonate rocks. Porosity and permeability properties are measured for twelve anhydride and carbonate core samples under stress loading and unloading conditions. The results of permeability measurements show that tighter core samples are more stress dependent while the anhydride samples are generally more sensitive to the stress. The gap between stress loading and unloading (hysteresis) is more considerable at lower effective stress values. The results also indicate that the hysteresis is more noticeable in the anhydride core samples. The gas slippage factor is also... 

The on-fiber standardization technique for solid-coated solid-phase microextraction (SPME) was studied, and a theoretical model is proposed for the isotropic behavior of adsorption and desorption, based on Fick's law of diffusion and the Langmuir model. The isotropy of the adsorption and desorption of analytes onto and from the surface of porous solid SPME fiber was validated with the use of a commercially available fiber, a 50-μm Carbowax/ templated resin for carbamate pesticide analysis in various sample matrixes, and a self-made polypyrrole fiber for diazepam analysis in blood samples. Time constants were comparable for the adsorption and desorption processes. Equilibrium constants and... 

We report improved performance of Li-ion polymer batteries through advanced gel polymer electrolytes (GPEs). Compared to solid and liquid electrolytes, GPEs are advantageous as they can be fabricated in different shapes and geometries; also ionic properties are significantly superior to that of solid and liquid electrolytes. We have synthetized GPE in form of membranes by trapping ethylene carbonate and propylene carbonate in a composite of polyvinylidene fluoride and N-methylpyrrolidinore. By applying phase-transfer method, we synthetized membranes with micro-pores, which led to higher ionic conductivity. The proposed membrane is to be modified further to have higher capacity, stronger... 

This study proposes a mathematical model to evaluate the impact of oxygen carriers and scaffold geometry on oxygen distribution and cell growth in a 3D cardiac construct using computational fluid dynamics (CFD). Flow equations, oxygen balance equation and cell balance equation were solved using special initial and boundary conditions. The modeling results revealed that 55% increase in cardiac cell density occurred by using 6.4% perfluorocarbon oxygen carrier (PFC) compared to pure culture medium without PFC supplementation. Moreover, the effects of the scaffold geometry on cell density were examined by changing the channel numbers and the construct length. A 30% increase in the average cells... 

Geostatistical methods are grouped in two main divisions: univariate and multivariate. When there is adequate amount of primary data, univariate methods such as kriging and SGS give a good representation of property distribution in the reservoir, but practical difficulties appear when there is no sufficient data. In such a case it is necessary to choose multivariate geostatistical methods in which some covariables are contributed to model the primary variable. Multivariate geostatistics is a broad term that encompasses all geostatistical methods that utilize more than one variable to predict some physical property of the earth. Bivariate geostatistics is obviously the simplest subset of the... 

In this study, microstructural aspects that control fracture and deformation resistance of P/M materials are evaluated. Several low-alloy steels were produced under both experimental and commercial conditions for achieving different matrix phases and porosity levels with varying shape factors. A 'porosity map' was constructed and used for a quantified study of the dominant mechanism controlling mechanical behaviors. The role of inclusion gathering and secondary pores, as well as sintering mechanism and alloying method is considered and discussed. The mechanism assessment was performed by using microstructure examination through optical and scanning electron microscopy. The results... 

Reservoir permeability is an important parameter that its reliable prediction is necessary for reservoir performance assessment and management. Although many empirical formulas are derived regarding permeability and porosity in sandstone reservoirs, these correlations cannot be accurately depicted in carbonate reservoir for the wells that are not cored and for which there are no welltest data. Therefore, having a framework for estimation of these parameters in reservoirs with neither coring samples nor welltest data is crucial. Rock properties are characterized by using different well logs. However, there is no specific petrophysical log for estimating rock permeability; thus, new methods... 

Reservoir permeability is an important parameter that its reliable prediction is necessary for reservoir performance assessment and management. Although many empirical formulas are derived regarding permeability and porosity in sandstone reservoirs, these correlations cannot be accurately depicted in carbonate reservoir for the wells that are not cored and for which there are no welltest data. Therefore, having a framework for estimation of these parameters in reservoirs with neither coring samples nor welltest data is crucial. Rock properties are characterized by using different well logs. However, there is no specific petrophysical log for estimating rock permeability; thus, new methods... 

The permeability is one of the most important reservoir parameters and its accurate prediction is necessary for reservoir management and enhancement. Although many empirical formulas are derived regarding permeability and porosity in sandstone reservoirs [1], these correlations cannot be modified accurately in carbonate reservoir for the wells which are not cored and there is no welltest data. Therefore estimation of these parameters is a challenge in reservoirs with no coring sample and welltest data. One of the most powerful tools to estimate permeability from well logs is Artificial Neural Network (ANN) whose advantages and disadvantages have been discussed by several authors [2]. In this... 

Excess pressure drop induced by inertial effects limits the applicability of Darcy's law for modeling of fluid flow through porous media at high velocities. It is expected such additional pressure drop is influenced by pore/morphology of porous media. This work concerns with fundamental understanding of how throat curvature affects intrinsic properties of porous media at non-Darcy flow conditions using network modeling. Conical, parabolic, hyperbolic, and sinusoidal capillary ducts with three types of imposed anisotropy are used to construct the network in a more realistic manner. Solutions of one dimensional Navier-Stokes equation for incompressible fluid flow through converging/diverging... 

Hyperbranched polyethyleneimine functionalized silica (PEI-SiO2) nanoparticles with considerable hydrophilicity were synthesized and incorporated into a polysulfone (PSF)/dimethylacetamide (DMA)/polyvinylpyrrolidone (PVP) membrane casting solution in five different ratios to fabricate PEI-SiO2/PSF nanocomposite membranes using nonsolvent-induced phase separation. The hydrophilic PEI-SiO2 nanoparticles were characterized by TEM, FTIR, TGA, and XPS analyses. Morphology, water contact angles, mean pore sizes, overall porosity, tensile strengths, water flux, antifouling and the dye separation performances of the PEI-SiO2/PSF membranes were also studied. The PEI-SiO2 nanoparticles were uniformly... 

In this paper, a comprehensive analytical study is performed to assess the lycopodium-diesel dual-fuel combustion system in counter-flow premixed configuration. The system is modeled as multiple zones that are coupled together via proper boundary and jump conditions on interfaces. According to the respective reaction and transport phenomena in these zones, conservation equations of mass and energy are derived, non-dimensionalized, and solved by Matlab and Mathematica in an analytical way. The porosity of lycopodium particles and the thermal radiation from the reaction zone and the post-flame zones into the preheating zone are considered, in order to improve the realism and accuracy of the... 

Controlling topographic features at all length scales is of great importance for the interaction of cells with tissue regenerative materials. We utilized an indirect three-dimensional printing method to fabricate polymeric scaffolds with pre-defined and controlled external and internal architecture that had an interconnected structure with macro- (400-500 μm) and micro- (∼25 μm) porosity. Polycaprolactone (PCL) was used as model system to study the kinetics of tissue growth within porous scaffolds. The surface of the scaffolds was decorated with TiO2 and bioactive glass (BG) nanoparticles to the better match to nanoarchitecture of extracellular matrix (ECM). Micrometric BG particles were... 

The fabrication of a suitable scaffold material is one of the major challenges for bone tissue engineering. Poly(lactic acid) (PLA) is one of the most favorable matrix materials in bone tissue engineering owing to its biocompatibility and biodegradability. However, PLA suffers from some shortcomings including low degradation rate, low cell adhesion caused by its hydrophobic property, and inflammatory reactions in vivo due to its degradation product, lactic acid. Therefore, the incorporation of bioactive reinforcements is considered as a powerful method to improve the properties of PLA. This review presents a comprehensive study on recent advances in the synthesis of PLA-based biocomposites... 

In this work, a reliable dimensionless correlation is proposed for prediction of permeability reduction rate in porous media, which is verified by experimental data obtained in this work in glass bead and sand pack as well as the core data from the literature. Although this correlation is based on the data which were obtained in our work in glass bead and sand-packed media at low pressure, it shows considerable flexibility to match with the extracted data for sandstone cores at high pressure, various flow rates, different temperatures and concentrations of calcium, and sulfate ions in brine solutions. In addition, a novel relationship for predicting the rate of precipitation of CaSO4 in... 

There is a need to find cheaper and simpler techniques for rural water filtration system in developing countries. Using a filter made of blocks for the water treatment enables one to make vertical filters. It is expected that the amount of land utilized would decrease by more than 70 % if vertical filters were used. The operation and washing would be simpler than using horizontal sand filters as filters made of blocks would be used instead. The feasibility study focused on finding adequate materials, compositions and methods of making a block with enough resistance to water pressure, sufficient porosity for water transformation, and using inexpensive, readily available materials. A pilot... 

Pervious concrete (PC) has been detecting application in pavement and concrete structures such as dams, small retaining walls, and etc during the past decades. Also, in recent years, the types of resins have been introduced to apply in concrete owing to the enhancing in mechanical and durability characteristics. However, few studies have investigated the mechanical behavior of high performance pervious concrete (HPPC) incorporated by polyester and epoxy resins as polymeric composites, where ordinary cement material has been completely deleted. The purpose of this investigation is to compare the mechanical properties, permeability, and durability of HPPCs made by polymeric composites (i.e....