Sharif Digital Repository

Recently much attention has been paid to the use of low salinity water (LSW) as an enhanced oil recovery fluid. The change observed in recovery factor during LSW flooding is induced from changes in relative permeability and capillary pressure when different levels of salinity are used. However, a few researchers tried to evaluate how macroscopic flow functions depend on the salinity of the injected water. To this end, a series of oil displacement by water was performed on a sandstone rock aged with crude oil in the presence of connate water. The capillary pressure and relative permeability curves are evaluated from inverse modeling of the obtained pressure drop and oil production data. Then,... 

Lake Urmia, which was once the second-largest saline lake in the world, has been shrinking dramatically. Moreover, Lake Urmia has become supersaturated with total salinity averaging more than 350 g/l. Salt precipitation and dissolved materials brought by inflowing rivers have formed a layer of sediment with low hydraulic conductivity on the lakebed. Considering the flat bathymetry of Lake Urmia, we conducted a series of numerical simulation scenarios to study the groundwater flow pattern in the vicinity of the hypersaline Lake Urmia using COMSOL Multiphysics®. In the first step, we performed the simulations in steady-state conditions. Secondly, we simulated the lake level fall in 10 years at... 

This paper addresses a conceptual study on different aspects of a novel smart treatment method for a relatively new challenge of saline water production from low permeability lenses of high flow gas wells. Selective sealing of such lenses along with minor effect on gas productivity usually faces practical difficulties due to the inherent permeability contrast. Engineered application of salt sensitive gellan biopolymer through a smart treatment scenario that includes a protective gas flow proved its ability for treating such challenge. This paper investigates the importance of the gel rigidity and its coverage in the smart treatment scenario through considering the brine salinity and the... 

In order to evaluate the long-term viability, the iron content stability, and the labeling efficiency of mammalian cells using magnetic cell labeling; dextran-coated ultrasmall superparamagnetic iron oxide (USPIOs) nanoparticles with plain surfaces having a hydrodynamic size of 25 nm were used for this study. Tests were carried out in four groups each containing 5 flasks of 5.5 × 10 6 AD-293 embryonic kidney cells. The cell lines were incubated for 24 h using four different iron concentrations with and without protamine sulfate (Pro), washed with phosphate-buffered saline (PBS) and centrifuged three times to remove the unbounded USPIOs. Cell viability was also verified using USPIOs. There... 

This work concerns with experimental investigation of CO2 WAG injection to light crude oil in near miscible conditions which has been rarely attended in the available literature. Here, several core flood experiments at three constant injection rates and four WAG ratios are conducted on sandstone rocks saturated with light crude oil in presence of saline water. The results showed that higher injection rate has a better performance regarding oil recovery for smaller PVs of injected fluids, while lower injection rate showed higher ultimate recovery for a 30% increase in injected PVs. Secondary continuous gas injection showed a superior performance than all the other WAG injections in different... 

A hybrid HDH desalination system integrated with a heat pump was experimentally studied. In this system, heat pump's heating was used to raise the temperature of the air entering the humidifier and its cooling effect was used for dehumidification of humid air and freshwater production. In other words, heat pump's condenser works as the heater of the HDH cycle and its evaporator works as the coolant for the dehumidifier of HDH cycle. The effects of different parameters such as mass flow rate of inlet saline water (relative humidity of the air passing the dehumidification section), volume flow rate of the air passing the dehumidification section and ambient air temperature on freshwater... 

Enhanced Oil Recovery (EOR) methods have been widely used around the world to improve oil production from petroleum reservoirs. Recently, the injection of the low salinity/smart water has gained popularity among the EOR methods. Different mechanisms are believed to exist during low salinity/smart water injection, including dissolution, precipitation, and ion exchange at the rock surface. In this study, a coupled geochemical-transport model is presented for the detailed analysis and investigation of the interactions between brine, sandstone and carbonate rocks. The proposed model presents the coupling of a geochemical software (PHREEQC) and a species transport model. This coupled method makes... 

In salting-out liquid-liquid extraction (SALLE) technique, water-miscible organic solvents are used for extraction of polar analytes from saline solutions. In this study, for the first time, a coupled 1-mL syringes system was utilized to perform a miniaturized SALLE method. Sulfanilamide antibiotic was extracted and determined via the developed method followed by high performance liquid chromatography-ultraviolet detection (HPLC-UV). The extraction process was carried out by rapid shooting of acetonitrile as extraction solvent (syringe B) into saline aqueous sample solution (syringe A), and then the shooting was repeated several times at a rate of 1 cycle s-1. Thereby, an extremely large... 

Microscopic and macroscopic displacements of polymer flooding to heavy oil at various levels of salinity and connate water saturation have been investigated. Both oil-wet and water-wet conditions in fractured five-spot micromodel systems, initially saturated with the heavy crude oil are utilized. The primary contribution is to examine the role of salinity, wettability, connate water, and fracture geometry in the recovery efficiency of the system. The microscopic results revealed that the increase in the connate water saturation decreases the oil recovery, independent of the wettability conditions. Moreover, the increase in salinity of the injected fluids lowers the recovery efficiency due to... 

During the low salinity waterflooding (LSWF) of a viscous asphaltic oil reservoir, fluid-fluid interactions have a large influence on the fluid flow, pore-scale events, and thus oil recovery efficiency and behavior. In-situ water-in-oil (W/O) emulsion formation is a consequence of crude oil and brine interfacial activities. Despite the published studies, the pore-scale mechanisms of W/O emulsion formation and the role of injected brine salinity, injection rate, and pore-scale heterogeneity on emulsion formation and stability requires a deeper understanding. To address these, a series of static and dynamic micro-scale experiments were performed. The salinity dependent oil-brine interactions... 

The low salinity water injection has become one of the most important studies in the oil industry for improving oil recovery compared to conventional seawater injection. Thus, extensive studies have been conducted in carbonate and sandstone reservoirs to investigate how the physical properties of rocks and the chemical composition of fluids influence low salinity effect, while, the carbonate reservoir rocks requires more investigation of the effect of molecular and/or ionic interactions. In this experimental work, the effectiveness of various water flooding schemes in carbonate reservoir rock samples is investigated. In this regard, the oil recovery potential of seawater (SW), reservoir... 

According to current researches, graphene oxide (GO) membranes show promising desalination properties due to ease of synthesis, low production cost, and high efficiency. There are several experimental works to study ionic sieving properties of GO membranes. However, it is difficult to characterize atomistic mechanism of water permeation and ion rejection by experimental approaches. On the other hand, there exist a few reports in which the atomistic picture of water permeation across GO membranes is investigated by means of molecular dynamics (MD) simulation. In the present work, in addition to water desalination, the atomic scale mechanism of ion rejection is studied using large scale MD... 

Despite previous researches on ion-engineered waterflooding (IEWF), its underlying mechanisms are not fully understood, particularly in presence of additives, like surfactants. This paper concerned with the contribution of Ca 2+ , Mg 2+ , SO 4 2- and Na + into altering wettability of oil-wet carbonate minerals towards water preferred state. As a mechanistic study, an experiment workflow was conducted to probe the impact of ions' concentrations in SW, either with or without sodium dodecylbenzene sulfonate (SDBS) which is an anionic surfactant. At first, contact angle (CA) measurement was carried out to evaluate the degree of wettability reversal upon treating the oil-aged calcite slabs with... 

During preliminary investigation phase of the national Chabahar-Zahedan railway line, serious geotechnical problems including non-uniform settlements, tensile cracks, and local collapse were reported in parts of the path near the coastline. A follow-up field investigation revealed that the in-situ soil at construction site has a metastable structure being sensitive to saturation and loading. Therefore, a comprehensive series of physical, chemical, electro-chemical, and geotechnical tests were conducted to classify and characterize the soil properties and behavior in its natural state. The natural soil was classified as a clayey loess with moderately dispersive to dispersive characteristics.... 

A new type of collapsible soil was encountered in Southern Iran and caused some serious technical problems including subsidence, collapse and sinkholes during the construction of Zahedan-Chabahar railway. Field observations indicated that in-situ soil contains excessive amount of salts resulting in dispersive features in response to seepage forces in addition to its collapsibility. Therefore, a systematic research plan including field sampling and laboratory testing was carried out to investigate the observed geotechnical features. Results of physio-chemical tests revealed the dominance of Sodium in excess of 70% relative to total dissolved salts, which results in high dispersive potential.... 

Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms, originated from the long-term erosion by acidic rainwater. The dissolved salt poses an extra osmotic water potential being normally neglected in laboratory measurements and numerical analyses. However, ignorance of salinity may result in overestimation of stability, and the design may not be as conservative as thought. Therefore, this research aims to first experimentally examine the influence of pore water salinity on water retention curve and saturated permeability of natural dispersive loess under saline and desalinated conditions. Second, the measured parameters are used for... 

Wettability alteration in porous media is one of the mechanisms for enhancing oil recovery through injecting low-salinity water into carbonate reservoirs, in which active ions can remove the carboxylic oil component from the rock surface, altering the rock's wettability toward a water-wet condition. This study investigated the concomitant effects of low-salinity water and hydrophilic SiO2 nanoparticles on oil-wet dolomite rock. Results revealed that low-salinity water coupled with hydrophilic nano-SiO2 in oil-wet dolomite rock remarkably affected the wettability alteration of the rock, showing that the simultaneous presence of ions in water and hydrophilic nano-SiO2 led to considerable... 

Two main reservoir mechanisms that impact oil recovery factors are wettability alteration and interfacial tension (IFT) change. In this study, these two key mechanisms are evaluated experimentally for samples from the Asmari (carbonate) oil reservoir utilizing silica nanoparticles in the presence of low-salinity water. The nanofluid, rock formation and crude oil samples were prepared meticulously to ensure meaningful experimental could be conducted over a range of low-salinity conditions. The results show that across the range of salinities studied, the absolute value of zeta potential of nanofluids decreases with increasing total dissolved solids (TDS) in the water treated with silica... 

Extraction of thermal heat from a salinity-gradient solar pond (SGSP) as a way of accumulating solar energy, stockpiling and taking merit of it for medium and low temperature demands is presented as an interesting topic in recent decades. This reliable supply of heat can be used for low-temperature refrigeration systems to yield cooling load for residential applications. For this purpose, theoretical investigation of ejector refrigeration cycle (ERC) driven by a SGSP is carried out to produce cooling output. Also, thermoelectric generator (TEG) is used as a potential device replacing condenser of the ERC for the sake of bolstering performance of the fundamental system by producing power,... 

Multi-effect distillation units discard brine at high volume to the environment which results in numerous environmental pollutions, low thermodynamic performance, high exergy destruction rate, and high unit cost for the fresh water. This study aims at introducing a new method of pre-treatment for the brine discarded from each stage of the desalination plant to increase its concentration. The new method per-concentrates the brine by superheating the steam produced in the previous stage via recovering valuable thermal heat of the same effect. Due to a low temperature difference between the heat sink and heat source of this self-superheating scheme (i.e., the temperature difference between the...