Sharif Digital Repository

The structural, electrical, optical, and photovoltaic properties of aggregated submicron nitrogen-doped TiO2 particles (NTiO2) and the influence of utilizing them, in comparison with undoped ones, as the light-scattering layer of dye-sensitized solar cells were investigated. Field emission scanning electron microscope, X-ray diffraction, and diffuse reflectance spectra showed that both type samples have similar morphology, crystal phase, and scattering feature. Moreover, photoluminescence, Mott–Schottkey, and photovoltaic characteristics such as IMPS/IMVS and charge extraction analysis indicated that the NTiO2 layer is an efficient scatterer in two aspects: enhancement of light-harvesting... 

In this paper the creation of multiple energy hubs that make up a complex energy network are modeled and optimized for a selection of six scenarios to examine both their financial viability and potential reduction of greenhouse gas emissions. As a proposed case study scenario for the model, three energy hubs are considered: a 'residential complex (RC)', a 'commercial shopping plaza (CS)', and a 'school (S)'. The use of combined heat and power systems, solar photovoltaic, solar collectors and network interaction are also examined for their impact on efficiency and cost. The modeling is undertaken and carried out by General Algebraic Modeling System (GAMS). It is shown that cost can be reduced... 

Solar energy exists extensively in all parts of the world. However the intermittency of solar energy presents critical challenges to PV system. The intermittency can be covered by storing solar energy in chemical bonds such as hydrogen. This process can be performed by photovoltaic powered electrolysis of water. The energy transfer efficiency between PV and electrolyzer is subject to the distance between maximum power points (MPP) of PV module and operating points. The operating points can be adjusted by optimizing the design parameters of the electrolyzer but the maximum power points are function of PV module characteristics, solar radiation and ambient temperature. Therefore the weather... 

Abstract We design a thermo-photovoltaic Tandem cell which produces high open circuit voltage (Voc) that causes to increase efficiency (η). The currently used materials (AlAsSb-InGaSb/InAsSb) have thermo-photovoltaic (TPV) property which can be a p-n junction of a solar cell, but they have low bandgap energy which is the reason for lower open circuit voltage. In this paper, in the bottom cell of the Tandem, there is 30 quantum wells which increase absorption coefficients and quantum efficiency (QE) that causes to increase current. By increasing the current of the bottom cell, the top cell thickness must be increased because the top cell and the bottom cell should have the same current. In... 

The plasmonic effects of infiltrated silver (Ag) nanoparticles, with different contents, inside a nanostructured TiO2 film on the photovoltaic performance of dye-sensitized solar cells (DSSCs) are explored. The synthesized Ag nanoparticles are immobilized onto deposited TiO2 nanoparticles by a new strategy using 3-mercaptopropionic acid (MPA), a bifunctional linker molecule. Transmission electron microscope (TEM) images show that monodispersed Ag and polydispersed TiO2 nanoparticles have an average diameter of 12 ± 3 nm and 5 ± 1 nm, respectively. Moreover, Fourier transform infrared spectroscopy (FTIR) analysis reveals that Ag nanoparticles were successfully functionalized and capped with... 

The application of the renewable energy sources, especially solar energy, for thermal enhanced oil recovery methods as an economical and environmental valuable technique has received many attractions recently. Concentrated Solar Power systems are capable of producing substantial quantities of steam by means of focused sunlight as the heat source for steam generation. This paper aims to investigate viability of using this innovative technology in fractured reservoirs to generate steam instead of using conventional steam generators. A synthetic fractured reservoir with properties similar to those of giant carbonate oil reserves in the Middle East was designed by using commercial thermal... 

Herein, we demonstrate a facile low temperature chemical bath deposition approach to deposit a light scattering layer on a nanostructured mesoporous TiO2 bottom layer in a dye-sensitized solar cell architecture. Large TiO2 nanoparticles were formed on the top surface of photoanode electrodes via hydrolysis of TiCl4 at 70 °C. We controlled the size and agglomeration of these TiO2 nanoparticles by altering the concentration of TiCl4 in the chemical bath during the hydrolysis process. Electron microscope images revealed that mono-dispersed scattering particles having uneven surfaces with diameters between 100 to 300 nm formed on the mesoporous titania layer. The scattering behavior of the... 

The performance of the tower based concentrated solar thermal (CST-tower) plant is very sensitive to the operation strategy of the plant and the incident heat flux on the receiver. To date, most studies have been examined only the design mode characteristics of the cavity receivers, but this paper significantly expands the literature by considering non-design operating conditions of this important sub-component of the CST-tower plants. A feasible non-design operating conditions of the cavity receivers that was considered in this study is the storage mode of operation. Two practical dynamic control strategies were examined then to find the most efficient approach: fixed solar field mass... 

Dielectric scattering particles have widely been used as embedded scattering elements in dye-sensitized solar cells (DSCs) to improve the optical absorption of the device. Here we systematically study rodlike and spherical core-shell silica@Ag particles as more effective alternatives to the dielectric scattering particles. The wavelength-scale silica@Ag particles with sufficiently thin Ag shell support hybrid plasmonic-photonic resonance modes that have low parasitic absorption losses and a broadband optical response. Both of these features lead to their successful deployment in light trapping in high-efficiency DSCs. Optimized rodlike silica@Ag@silica particles improve the power conversion... 

Solar energy will make a valuable contribution for power generation in the future. However the intermittency of solar energy has become an important issue in the utilization of PV system, especially small scale distributed solar energy conversion systems. The issue can be addressed through the management of production and storage of the energy in the form of hydrogen. The hydrogen can be produced by solar photovoltaic (PV) powered electrolysis of water. The amount of transferred energy to an electrolyzer from a PV module is a function of the distance between maximum power points (MPP) of PV module and the electrolyzer operating points. The distance can be minimized by optimizing the number... 

Energy and environment crises motivated scientists to develop sustainable, renewable, and clean energy resources mainly based on solar hydrogen. For this purpose, one main challenge is the low cost flexible substrates for designing earth abundant efficient cocatalysts to reduce required water oxidation overpotential. Here, a systematic morphological and electrochemical study has been reported for cobalt oxide/hydroxide nanoflakes simply electrodeposited on four different commercially available substrates, titanium, copper sheet, steel mesh, and nickel foam. Remarkable dependence between the used substrate, morphology, and electrocatalytic properties of nanoflakes introduced flexible porous... 

Herein, we report a double-layer photoanode electrode composed of TiO2 nanoparticles active layer and a mixture of nanoparticles and newly proposed skein-like nanotubes (NTs) top layer. Such structure performs well in solar light harvesting due to first, the top layer exhibits superior light scattering and second, the active layer with high dye-loading can make better use of the back-scattered light. The results reveal that 30-40 nm nanoparticles have anatase structure, whereas 5-7 μm skein-like NTs show a mixture of anatase and rutile phases. Photovoltaic measurements demonstrate that by tuning mass ratio between nanoparticles and skein-like NTs, the cells based on single-layer photoanode... 

Today’s the technology based on dye-sensitized solar cells (DSSCs) has an important role in all photovoltaic system technologies. DSSCs can generate electricity with various degrees of transparency; this makes it suitable for use in various industries, especially in construction industry as smart windows. In fact DSSC can produce electricity and having natural light, simultaneously. It is obvious that DSSCs need to absorb solar radiation as much as possible. Since, the effective use of all incident lights leads to an increase in cell efficiency and this increase in efficiency is related to the amount of dye adsorbed on the surface of nanostructured electrode, so higher amount of dye for... 

Distributed generation (DG) units are often interfaced to the main grid using power electronic converters including voltage-source converters (VSCs). A VSC offers dc/ac power conversion, high controllability, and fast dynamic response. Because of nonlinearities, uncertainties, and system parameters’ changes involved in the nature of a grid-connected renewable DG system, conventional linear control methods cannot completely and efficiently address all control objectives. In this paper, a nonlinear adaptive control scheme based on adaptive backstepping strategy is presented to control the operation of a grid-connected renewable DG unit. As compared to the popular vector control technique, the... 

Today, energy crises attracted many researchers’ attention to renewable energy technologies especially photovoltaic (PV) systems. The main challenge of PV systems is unpredictable nature of solar power generation. To overcome this challenge, a storage system is integrated which reduces demand reliance on electricity grid and uses excess energy that solar panels produce. As investment cost of the storage system is considerable, finding an optimal technology, size, and configuration are crucial. In this paper, the optimal battery system is excluded from existing PV plant installing in a commercial building located in Mashhad/Iran. Here, the sizing procedure is based on a financial evaluation... 

The use of solar energy concentration systems for achieving performance enhancements in the Photovoltaic/thermal hybrid solar systems and reduction of initial costs is an idea that has been studied for years. In this article a new structure for parabolic trough photovoltaic/thermal collector is proposed and its thermal and electrical performances are experimentally investigated. The receiver of this concentrator contains a triangular channel with an outer surface covered with photovoltaic cells and thermoelectric modules with a specific arrangement so that in addition to absorbing heat, a larger portion of the solar radiation is directly converted to electricity. Hence, the performance of... 

Nowadays, fossil fuel limitations and environmental concerns push researchers to find clean and renewable energy resources. Solar hydrogen production via water splitting reactions in electrochemical and/or photo-electrochemical systems has been accepted as a promising route and efficient electrocatalysts are involved in both. Here, cobalt nanoflakes with an oxide/hydroxide surface and a conductive metallic core are grown on commercially available steel mesh modified with carbon based nanocomposites as a support layer. The portion of reduced graphene oxide sheets was changed from 0 to 100 wt% and the correlation of this concentration with the surface morphology and electro-catalytic activity... 

Thin-film solar cells based on hybrid organo-halide lead perovskites achieve over 22% power conversion efficiency (PCE). A photovoltaic technology at such high performance is no longer limited by efficiency. Instead, lifetime and reliability become the decisive criteria for commercialization. This requires a standardized and scalable architecture which does fulfill all requirements for larger area solution processing. One of the most highly demanded technologies is a low temperature and printable conductive ink to substitute evaporated metal electrodes for the top contact. Importantly, that electrode technology must have higher environmental stability than, for instance, an evaporated silver... 

All current highest efficiency perovskite solar cells (PSCs) use highly toxic, halogenated solvents, such as chlorobenzene (CB) or toluene (TLN), in an antisolvent step or as solvent for the hole transporter material (HTM). A more environmentally friendly antisolvent is highly desirable for decreasing chronic health risk. Here, the efficacy of anisole (ANS), as a greener antisolvent for highest efficiency PSCs, is investigated. The fabrication inside and outside of the glovebox showing high power conversion efficiencies of 19.9% and 15.5%, respectively. Importantly, a fully nonhalogenated solvent system is demonstrated where ANS is used as both the antisolvent and the solvent for the HTM.... 

Recent investigations on multifunctional piezoelectric semiconductors have shown their excellent potential as photovoltaic components in high-efficiency third-generation quantum nanostructure (QNS) solar cells. The current work is devoted to studying the electro-elastic behavior of high-density QNS photovoltaic semiconductors within which initial mismatch strains of arrays of quantum dots (QDs) or quantum wires (QWRs) induce coupled electro-mechanical fields. The inter-nanostructure couplings which are of great importance in high-density QNS arrays are incorporated in the presented analytical framework. In practice, QNSs with different geometries such as spherical, cuboidal, or pyramidal QDs...