Loading...
Search for: wettability-alteration
0.008 seconds
Total 107 records

    Investigation of Low Salinity Waterflooding Predictive Capability and the Development of a Tool for Screening Candidates

    , M.Sc. Thesis Sharif University of Technology Golmohammadi, Meysam (Author) ; Mahani, Hassan (Supervisor) ; Ayatollahi, Shahab (Supervisor)
    Abstract
    Among different enhanced oil recovery (EOR) methods, low salinity waterflooding (LSWF) has been attractive to researchers because of its relative simplicity and lower environmental problems compared to other conventional EOR methods. Numerous researchers have attempted to find the main cause of the low salinity effect (LSE). According to previous studies, several experimental techniques have been proposed for predicting LSE and screening potential field candidates. However, there is a lack of a systematic investigation of all (or even some of) the methods to compare and determine their LSE predictive capability. Predictive capability development is essential because it saves costs and time... 

    Low Salinity Water Assisted by Surfactants for Enhanced Oil Recovery: Mechanistic Study and Spontaneous Imbibition Tests

    , M.Sc. Thesis Sharif University of Technology Heidari, Mehdi (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Enhanced Oil Recovery (EOR) techniques have become of the main priorities of the oil industry during the high oil price era. It is interesting to note that the common method to increase production from reservoirs is the water injection method, which recovers a very low amount of oil from the oil-wet matrices due to the lack of water imbibition. Previous studies have shown that changing the wettability of rock would critically increase the oil recovery efficiency. This could be achieved by the low-salinity water injection method. In recent years, extensive studies have been conducted on this technique to evaluate its effectiveness for various types of oil reservoirs. Simultaneous injection... 

    Atomistic insight into the behavior of ions at an oil-bearing hydrated calcite surface: implication to ion-engineered waterflooding

    , Article Energy and Fuels ; Volume 35, Issue 16 , 2021 , Pages 13039-13054 ; 08870624 (ISSN) Badizad, M. H ; Koleini, M. M ; Greenwell, H. C ; Ayatollahi, S ; Ghazanfari, M. H ; Sharif University of Technology
    American Chemical Society  2021
    Abstract
    This research provides an atomistic picture of the role of ions in modulating the microstructural features of an oil-contaminated calcite surface. This is of crucial importance for the rational design of ion-engineered waterflooding, a promising technique for enhancing oil recovery from carbonate reservoirs. Inspired by a conventional lab-scale procedure, an integrated series of molecular dynamics (MD) simulations were carried out to resolve the relative contribution of the major ionic constituent of natural brines (i.e., Na+, Cl-, Mg2+, Ca2+, and SO42-) when soaking an oil-bearing calcite surface in different electrolyte solutions of same salinity, namely, CaCl2, MgCl2, Na2SO4, MgSO4, and... 

    Experimental study on enhanced oil recovery by low salinity water flooding on the fractured dolomite reservoir

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 40, Issue 5 , 2021 , Pages 1703-1719 ; 10219986 (ISSN) Ebrahimzadeh Rajaee, S ; Gerami, S ; Safekordi, A. A ; Bahramian, A. R ; Ganjeh Ghazvini, M ; Sharif University of Technology
    Iranian Institute of Research and Development in Chemical Industries  2021
    Abstract
    Enhanced Oil Recovery from carbonate reservoirs is a major challenge especially in naturally fractured formations where spontaneous imbibition is a main driving force. The Low Salinity Water Injection (LSWI) method has been suggested as one of the promising methods for enhanced oil recovery. However, the literature suggests that LSWI method, due to high dependence on rock mineralogy, injected and formation water salt concentration, and complexity of reactions is not a well-established technology in oil recovery from carbonate reservoirs. The underlying mechanism of LSWI is still not fully understood. Due to lack of LSWI study in free clay dolomite fractured reservoir, and to investigate of... 

    Experimental investigation on the dominating fluid-fluid and rock-fluid interactions during low salinity water flooding in water-wet and oil-wet calcites

    , Article Journal of Petroleum Science and Engineering ; Volume 204 , 2021 ; 09204105 (ISSN) Farhadi, H ; Fatemi, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Low salinity water flooding (LSWF) has the potential to enhance the oil recovery by affecting the fluid-fluid and rock-fluid interactions. Therefore, a systematic investigation on the effect of initial wetting state (water-wet or oil-wet) of pure calcite is conducted to study the importance of these interactions on the effectiveness of LSWF. In the case of initially water-wet cores, more oil recovery efficiency is observed for more saline water cases. To shed light on the possible involved mechanisms, dynamic IFT, dynamic contact angle (CA), oil/brine and rock/brine surfaces zeta potentials, and effluent pH are measured. It is shown that the short-term effect of IFT reduction and long-term... 

    Experimental investigation on synergic effect of salinity and pH during low salinity water injection into carbonate oil reservoirs

    , Article Journal of Petroleum Science and Engineering ; Volume 202 , 2021 ; 09204105 (ISSN) Mehraban, M. F ; Ayatollahi, S ; Sharifi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Interaction between rock-fluid and fluid-fluid can have a significant effect on oil recovery. Changing the wettability of reservoir rock toward more water-wet or less oil-wet state is one of the expected mechanisms during low salinity water injection (LSWI). pH and salinity are of the most eminent factors of injection water controlling the wettability state of a crude oil/brine/rock system during any waterflooding operation. A small change in pH can affect the surface charges at the rock/water and oil/water interfaces leading to wettability alteration in a porous medium. In this study, the synergic effect of salinity and pH on the wettability state of carbonate rocks is evaluated through... 

    The impact of the electrical behavior of oil-brine-rock interfaces on the ionic transport rate in a thin film, hydrodynamic pressure, and low salinity waterflooding effect

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 620 , 2021 ; 09277757 (ISSN) Pourakaberian, A ; Mahani, H ; Niasar, V ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Wettability alteration is the principal low-salinity-effect (LSE) in many oil-brine-rock (OBR) systems. Our recent experimental results have demonstrated that wettability alteration by low salinity is slow. It is expected that the electrical behavior of oil/brine and rock/brine interfaces and the water film geometry control both the transient hydrodynamic pressure, and the time-scale of ionic transport in the film, thus the kinetics and degree of wettability alteration. In this paper, the electro-diffusion process induced by the imposed ionic strength gradient is simulated by solving Poisson-Nernst-Planck equations in a water film bound between two charged surfaces, using a finite... 

    Simulation of two-phase flow by injecting water and surfactant into porous media containing oil and investigation of trapped oil areas

    , Article Journal of Petroleum Exploration and Production ; Volume 11, Issue 3 , 2021 , Pages 1353-1362 ; 21900558 (ISSN) Sajadi, S. M ; Jamshidi, S ; Kamalipoor, M ; Sharif University of Technology
    Springer Science and Business Media B.V  2021
    Abstract
    Nowadays, as the oil reservoirs reaching their half-life, using enhanced oil recovery methods is more necessary and more common. Simulations are the synthetic process of real systems. In this study, simulation of water and surfactant injection into a porous media containing oil (two-phase) was performed using the computational fluid dynamics method on the image of a real micro-model. Also, the selected anionic surfactant is sodium dodecyl sulfate, which is more effective in sand reservoirs. The effect of using surfactant depends on its concentration. This dependence on concentration in using injection compounds is referred to as critical micelle concentration (CMC). In this study, an... 

    Pore-doublet computational fluid dynamic simulation of the effects of dynamic contact angle and interfacial tension alterations on the displacement mechanisms of oil by low salinity water

    , Article International Journal of Multiphase Flow ; Volume 143 , 2021 ; 03019322 (ISSN) Alizadeh, M ; Fatemi, M ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Using our recently developed model, for the first time in the literature, the effect of fluid/fluid and rock/fluid interactions on the performance of Low Salinity Waterflooding (LSWF, as an Enhanced Oil Recovery process) at pore-doublet scale is investigated. The model is incorporated into OpenFOAM and both the Navier-Stokes equation for oil/water two-phase flow and the advection-diffusion equation for ion transport (at both fluid/fluid and rock/fluid interface) are solved via direct numerical simulation (DNS). The model is validated against imbibition and drainage pore-doublet experiments reported in the literature, and then applied to investigate the sole effect of wettability alteration... 

    Mechanistic study of the effects of dynamic fluid/fluid and fluid/rock interactions during immiscible displacement of oil in porous media by low salinity water: Direct numerical simulation

    , Article Journal of Molecular Liquids ; Volume 322 , 2021 ; 01677322 (ISSN) Alizadeh, M ; Fatemi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Low salinity waterflooding (LSWF) is a process in which by lowering the ionic strength and/or manipulation of the composition of the injection water, the long term equilibrium in oil/brine/rock system is disturbed to reach a new state of equilibrium through which the oil production will be enhanced due to fluid/fluid and/or rock/fluid interactions. In spite of recent advances in the simulation of the LSWF at core scale and beyond, there are very few works that have modelled and simulated this process at the pore scale specially using direct numerical simulation (DNS). As a result the effects of wettability alteration and/or Interfacial Tension (IFT) change on the distribution of the phases... 

    Direct numerical simulation of the effects of fluid/fluid and fluid/rock interactions on the oil displacement by low salinity and high salinity water: Pore-scale occupancy and displacement mechanisms

    , Article Journal of Petroleum Science and Engineering ; Volume 196 , 2021 ; 09204105 (ISSN) Alizadeh, M ; Fatemi, M ; Mousavi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Laboratory experiments have shown that performance of waterflooding in oil reservoirs could be significantly increased by lowering the ionic strength and/or manipulation of its composition, which is generally known as low salinity waterflooding (LSWF). The involved mechanisms in additional oil production can be generally categorized in two categories, fluid/fluid and fluid/rock interactions. The distribution of the phases and the involved displacement mechanisms would be strongly affected by the inter-relations between capillary and viscous forces. Although there have been recent advances in the simulation of the LSWF at core scale and beyond and some models are included in commercial... 

    Micromodel Investigation of the Non-Monotonic Effect of Injection Water Salinity on Wettability and Oil Recovery

    , M.Sc. Thesis Sharif University of Technology Karimpour Khamaneh, Mehran (Author) ; Mahani, Hassan (Supervisor)
    Abstract
    Based on numerous laboratory and field evidence, low-salinity waterflooding or engineered salinity waterflooding can lead to enhanced oil production. According to the literature, the mechanisms involved in this process can be divided into two general categories: fluid-fluid interactions and solid-liquid interactions. These mechanisms are caused by intermolecular and electrostatic forces at the rock and fluid interfaces. The most important controlling factor of the electrostatic forces is the concentration of ions at/near fluids-rock interface. Therefore, improving the concentration of ions causes a shift in wettability toward a more water-wetting state, eventually leading to increased oil... 

    Pore-doublet computational fluid dynamic simulation of the effects of dynamic contact angle and interfacial tension alterations on the displacement mechanisms of oil by low salinity water

    , Article International Journal of Multiphase Flow ; Volume 143 , 2021 ; 03019322 (ISSN) Alizadeh, M ; Fatemi, M ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Using our recently developed model, for the first time in the literature, the effect of fluid/fluid and rock/fluid interactions on the performance of Low Salinity Waterflooding (LSWF, as an Enhanced Oil Recovery process) at pore-doublet scale is investigated. The model is incorporated into OpenFOAM and both the Navier-Stokes equation for oil/water two-phase flow and the advection-diffusion equation for ion transport (at both fluid/fluid and rock/fluid interface) are solved via direct numerical simulation (DNS). The model is validated against imbibition and drainage pore-doublet experiments reported in the literature, and then applied to investigate the sole effect of wettability alteration... 

    Mechanistic study of the effects of dynamic fluid/fluid and fluid/rock interactions during immiscible displacement of oil in porous media by low salinity water: direct numerical simulation

    , Article Journal of Molecular Liquids ; Volume 322 , 2021 ; 01677322 (ISSN) Alizadeh, M ; Fatemi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Low salinity waterflooding (LSWF) is a process in which by lowering the ionic strength and/or manipulation of the composition of the injection water, the long term equilibrium in oil/brine/rock system is disturbed to reach a new state of equilibrium through which the oil production will be enhanced due to fluid/fluid and/or rock/fluid interactions. In spite of recent advances in the simulation of the LSWF at core scale and beyond, there are very few works that have modelled and simulated this process at the pore scale specially using direct numerical simulation (DNS). As a result the effects of wettability alteration and/or Interfacial Tension (IFT) change on the distribution of the phases... 

    Direct numerical simulation of the effects of fluid/fluid and fluid/rock interactions on the oil displacement by low salinity and high salinity water: pore-scale occupancy and displacement mechanisms

    , Article Journal of Petroleum Science and Engineering ; Volume 196 , 2021 ; 09204105 (ISSN) Alizadeh, M ; Fatemi, M ; Mousavi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Laboratory experiments have shown that performance of waterflooding in oil reservoirs could be significantly increased by lowering the ionic strength and/or manipulation of its composition, which is generally known as low salinity waterflooding (LSWF). The involved mechanisms in additional oil production can be generally categorized in two categories, fluid/fluid and fluid/rock interactions. The distribution of the phases and the involved displacement mechanisms would be strongly affected by the inter-relations between capillary and viscous forces. Although there have been recent advances in the simulation of the LSWF at core scale and beyond and some models are included in commercial... 

    Super gas wet and gas wet rock surface: state-of- the art evaluation through contact angle analysis

    , Article Petroleum ; 2021 ; 24056561 (ISSN) Azadi Tabar, M ; Dehghan Monfared, A ; Shayegh, F ; Barzegar, F ; Ghazanfari, M. H ; Sharif University of Technology
    KeAi Communications Co  2021
    Abstract
    Recently, super gas wet and gas wet surfaces have been extensively attended in petroleum industry, as supported by the increasing number of publications in the last decade related to wettability alteration in gas condensate reservoirs. In many cases, contact angle measurement has been employed to assess the wettability alteration. Even though contact angle measurement seems to be a straightforward approach, there exist many misuses of this technique and consequently misinterpretation of the corresponding results. In this regard, a critical inspection of the most recent updated concepts and the intervening parameters in the contact angle based wettability evaluation of liquid-solid-gas... 

    The non-linear effect of oil polarity on the efficiency of low salinity waterflooding: A pore-level investigation

    , Article Journal of Molecular Liquids ; January , 2021 ; 01677322 (ISSN) Golmohammadi, M ; Mohammadi, S ; Mahani, H ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B. V  2021
    Abstract
    Oil polarity is an important property impacting the efficiency of low salinity waterflooding (LSWF). It directly affects fluid/fluid and rock/fluid interactions, controlling the interfacial properties and forces. However, the current findings in the literature on the effect of concentration of polar components on oil recovery by LSWF are contradictory. Therefore, the main objective of this paper is to investigate how the type of non-polar fractions and the concentration of acidic polar oil constituents change the trapped oil saturation at the pore-scale during LSWF. In this regard, we conducted a series of microfluidics LSWF experiments in both secondary and tertiary modes, using clay-free... 

    Wettability Alteration of Reservoir Rocks to Super Gas-Wet Condition Using Nanocomposite by Applying Contact Angle Measurement for Gas-Crude Oil System

    , M.Sc. Thesis Sharif University of Technology Zandi, Ahmad (Author) ; Ghazanfari, Mohammad Hossien (Supervisor) ; Fatemi, Mobeen (Supervisor) ; Esmaeilzadeh, Pouriya (Co-Supervisor)
    Abstract
    Today, increasing the productivity of reservoirs is more important than in the past, while the use of nanoparticles to change the wettability of rock and increase the recovery factor from the reservoir has been considered by many researchers. Despite previous studies on the use of nanoparticles to change the wettability of rock to gas-wet, the use of nanocomposites with super gas-wet at high temperature and pressure in the crude oil-gas system has rarely been considered. In this research, several nanocomposites with different structures have been synthesized in the laboratory and nanofluids with different formulations have been used to coat the rock thin sections and measure droplet contact... 

    Core-scale Mechanistic Simulation of Engineered Salinity Waterflooding Using Bond-Product-Sum Method

    , M.Sc. Thesis Sharif University of Technology Almasian, Pourya (Author) ; Mahani, Hassan (Supervisor)
    Abstract
    Considering the world's diminishing oil reserves, as well as the growing demand for oil and energy consumption, Enhanced Oil Recovery (EOR) techniques are becoming increasingly important in the attempt to improve oil production. Engineering salinity waterflooding has gained widespread attention and popularity in the last two decades due to its environmental friendliness, lack of expensive additives, low operating costs, and ease of use as an oil extraction process. The goal of this study is to use an innovative method to develop a mechanistic approach model that simulates and forecasts the mechanism and performance of the engineered water flooding process. Wettability alteration, the most... 

    Mechanistic Investigation of Enhanced Oil Recovery by Engineered Water Using Computational Fluid Dynamics at Pore Scale

    , Ph.D. Dissertation Sharif University of Technology Namaee Ghasemi, Arman (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Despite the proven advantage of the engineered water flooding technique, a coherent and mechanistic understanding of the fundamental phenomena occurring at pore scale is lacking. Most of the available simulation models have a phenomenological approach and have limited predictive capability. One of the key questions is how to justify and relate large (Darcy) scale observations to effects and phenomena that essentially occur at much smaller scales (i.e. pore and molecular level). Furthermore, two-phase flow dynamics and the effect of complex interplay between wettability, capillary number, and ions dispersion in a heterogeneous porous medium on the trapping and mobilization of oil at pore...