Sharif Digital Repository

Briefly in this thesis, these subjects have been investigated: In recent years, water is used as a solvent instead of an organic solvents have become more and more important due to cheap and environmental consideration. In this context, preparation of quinoxaline, pyrrole, new 1,4-dihydropyridine and reduction of imine to amine with 1,4-dihydropyridine derivatives as the reducing agents with the use of one-pot multicomponent reaction have been reported. The existence of several hydrogen bonding groups (NH) in the new dihydropyridines they acts as biologically active compounds in the forthcoming years. In continuation, oxidation of thiols to disulfides in the presence of NBS and NCS and... 

Propylene, as one of the most important raw materials of petrochemical industries, is produced through different methods. One of the major methods is propane dehydrogenation. This reaction is endothermic and many by-products will be produced in high temperature. Therefore catalytic dehydrogenation is preferred. Reduction in catalyst's activity and too many side reactions are the most important problems. Coke formation is the most effective reason of deactivation. Main source of coke is propylene. Experiments show that very small amount of water presence within reaction can reduce rate of coke formation. Water content growth does not always increase activity. If water be more than optimum... 

Today, with expanding industries, wastewater treatment of them is a global problem. Heavy metal is one of the most common and most dangerous contaminants in waste water that over time, with the strict standards of output, find more effective ways of eliminating them has always been a challenge. New methods, especially in the field of adsorption have achieved promising results in many cases.
Polymers composites are one of the adsorbent for the removal of these contaminants have been considered. In this project Aniline and composites to remove arsenic and chromium were studied. In polymers synthesis factors like type of additives and oxidizing materials strongly effected on morphology of... 

The electrical conductivity of the solution has been one of the important physical quantities in many application. In this respect many probes and devices such as conductive sensors have been devised. In this study electrical properties of different water samples at frequency step range of 100-100000 Hz are measured by using the long cylindrical capacitive sensor and a measuring module (LCR-703). Operation of the capacitance measurement module for such probes is based on the auto balancing bridge method. Comparison of the measured capacitances and measured resistances for different water samples shows a decrease by increasing the measurement frequency. In another study the dielectric... 

The transport behavior of water molecules inside a model carbon nanotube is investigated by using nonequilibrium molecular dynamics simulations. The shearing stress between the nanotube wall and the water molecules is identified as a key factor in determining the nanofluidic properties. Due to the effect of nanoscale confinement, the effective shearing stress is not only size sensitive but also strongly dependent on the fluid flow rate. Consequently, the nominal viscosity of the confined water decreases rapidly as the tube radius is reduced or when a faster flow rate is maintained. The effect of ion concentration and temperature rise on fluid flow and shearing stress is also investigated.... 

This thesis presents a research on the physical behavior of water inside carbon nanotubes (CNTs). Molecular simulations are carried out using the Monte Carlo method in the canonical and grand canonical ensembles. Due to the difference between the inter-molecular forces in the axial and radial directions, the anisotropic pressure tensor is calculated for water confined inside the CNTs with the diameters of 0.88, 1.08, 1.28, and 1.48 nm at different densities using the Monte Carlo simulations. Using the assumption of effective extended Lennard-Jones interactions between the nearest neighbors, a set of new equations of state for water confined inside the CNTs is derived and shown to be... 

Considering problems related to energy, including high fuel prices, increasing demand, constraints, and environmental pollution, makes it clear that efficiency is one of the major problems in all over the world. Iran’s southern parts and those countries around Persian Gulf face serious shortage of drinking water. Moreover, on top of the other three types of energy production the need for drinking water is highly sensible. Therefore, the use of CCHPW System is the best solution in these areas. The purpose of this design is to empower the control capability of the combined systems over all factors and apply the necessary changes under different conditions. This endeavor requires a program to... 

The formation of droplets at a T-junction in a micro channel network is primarily influenced by the pressure difference across the interface in the squeezing regime. Accurate measurements of droplet velocity and pressure profiles are difficult to obtain experimentally, yet these are the basic parameters required. Droplet micro fluidics has shown great potential for biological assays, chemical reactions and polymer emulsions. High stability allows the droplets to work as stable and isolated reactors that open up for parallel and serial reactions where each droplet can be screened individually. The purpose was to fabricate such systems, establish stable droplet generation where droplet volumes... 

According to current researches, graphene oxide (GO) membranes show promising desalination properties due to ease of synthesis, low production cost, and high efficiency. There are several experimental works to study ionic sieving properties of GO membranes. However, it is difficult to characterize atomistic mechanism of water permeation and ion rejection by experimental approaches. On the other hand, there exist a few reports in which the atomistic picture of water permeation across GO membranes is investigated by means of molecular dynamics (MD) simulation. In the present work, in addition to water desalination, the atomic scale mechanism of ion rejection is studied using large scale MD... 

Both resources have shaped the development of societies during the course of history. The increase in population, the growthe of middle-class societies, climate changes, economic development, health and environmental concerns, all play roles in magnifying or reducing the growing stresses on the vital resources of water and energy. Projections for water availability and quality, food and enrgy availability, soil and air quality are alarming. These alarms point to a major conclusion:’business as usual’ is no longer viable. Indeed, they call for a fundamental shift in the manner in which we understand and manage resources: a shift away from traditional approaches toward more integrative,... 

Nowadays, water and energy shortage is the main concern of many industries. Every saving that could be done is valuable. In the first step of this project, energy recovery devices that are used in reverse osmosis systems, are reviewed and advantages and disadvantages of each system are investigated. These apparatuses save energy by recovering high-pressure energy from leaving brine and reduce the energy consumption of the device. The main focus of this study is energy consumption of the device that is used for desalination of seawater in reverse osmosis systems and on this basis, different energy recovery devices are compared. According to the investigation, results showed that most of the... 

Energy and water are valuable resources that underpin human prosperity and are to a large extent, interdependent. Water is used in multiple phases of energy production and electricity generation, from fossil-fuel extraction, transport and processing,irrigating crops for biofuels, to providing cooling water for thermoelectric power plants. On the other hand, all such processes, alongside with other industrial and municipal water uses, require sufficient energy required to extract, treat, and deliver water.The key objective of this project is to maximize both water and energy economic potentials while considering the environmental impacts associated with their consumption. In this regard,... 

Biological layers are one of the main problems related to water transfer with pipe lines which are formed through time in the inner surface of the pipes by the water nutrients. Hence, the inner surfaces in the pipe lines and water refineries should be made in order not to let these biological layers to be made. The reason is that when the biofilm is formed on these surfaces, the traversing water is polluted. Dredging of these pipes is not only necessary in most of the countries in the world and needs huge amounts of water but is also very complex and expensive.In this research, nanomaterials, namely ZnO, T〖iO〗_2،S〖iO〗_2 have been used to cover the surface of concrete and steel pipes (The... 

The power supply system is one of the most important and complex systems. Various factors affect this system. Climate change affects different parts of the power supply system. In this study, the effect of climate change on electricity demand and electricity supply system has been investigated by considering the limited water resources. The amount of water withdrawal and GHG emissions in different scenarios. Scenarios are considered in such a way that assess the probable rising prices of fuels and water, and carbon taxes at three levels. Also, scenarios of rising water prices have been considered to evaluate the effect of this policy alone. It is worth noting that power plants are modeled...