Sharif Digital Repository

Yields of prompt and non-prompt J/ψ, as well as Y(1S) mesons, are measured by the CMS experiment via their μ +μ - decays in PbPb and pp collisions at √/s NN = 2.76 TeV for quarkonium rapidity |y| < 2.4. Differential cross sections and nuclear modification factors are reported as functions of y and transverse momentum pT, as well as collision centrality. For prompt J/ψ with relatively high pT (6.5 < pT < 30 GeV/c), a strong, centrality-dependent suppression is observed in PbPb collisions, compared to the yield in pp collisions scaled by the number of inelastic nucleon-nucleon collisions. In the same kinematic range, a suppression of non-prompt J/ψ, which is sensitive to the in-medium b-quark... 

The production of υ(1S), υ(2S), and υ(3S) is investigated in pPb and pp collisions at centre-of-mass energies per nucleon pair of 5.02 TeV and 2.76 TeV, respectively. The datasets correspond to integrated luminosities of about 31 nb-1 (pPb) and 5.4pb-1 (pp), collected in 2013 by the CMS experiment at the LHC. Upsilons that decay into muons are reconstructed within the rapidity interval |ycm| < 1.93 in the nucleonnucleon centre-of-mass frame. Their production is studied as a function of two measures of event activity, namely the charged-particle multiplicity measured in the pseudorapidity interval |η| < 2.4, and the sum of transverse energy deposited at forward pseudorapidity, 4.0 < |η| <... 

Azimuthal dihadron correlations of charged particles have been measured in PbPb collisions at √s NN = 2.76TeV by the CMS collaboration, using data from the 2011 LHC heavy-ion run. The data set incluDes a sample of ultra-central (0-0.2% centrality) PbPb events collected using a trigger based on total transverse energy in the hadron forward calorimeters and the total multiplicity of pixel clusters in the silicon pixel tracker. A total of about 1.8 million ultra-central events were recorDed, corresponding to an integrated luminosity of 120 μb-1. The observed correlations in ultra-central PbPb events are expected to be particularly sensitive to initial-state fluctuations. The single-particle... 

The potentiometric response properties of several PVC-based membrane electrodes using phthalocyanine complexes of aluminum (AlPc), nickel (NiPc) and copper (CuPc) as anion carriers, toward thiosalicylic acid (TSA) were investigated. The influences of lipophilic ionic additives (cationic and anionic) and the pH of the buffered solutions were used for the interpretation of the mechanism of the potentiometric response of sensors. The sensitivity, linear range, detection limit, and potentiometric selectivity of the membrane sensors show a considerable dependence on the nature of central metal of the ionophore. The membrane electrodes based on AlPc demonstrate sub-Nernstian responses toward TSA... 

One of the most relevant negative characteristics of high-capacity cathodes for lithium batteries is indeed non-flat voltage-time (V-t) or voltage-capacity (V-C) behaviour during charge-discharge. A clear rationale for this behaviour has not yet been addressed in the literature. Here, by means of density functional theory (DFT) calculations corroborated by basic experimental electrochemical characterization, we investigated both the thermodynamic and the kinetic aspects relevant to voltage variations during charge-discharge of Li2FeSiO4 intended as a model case. A simple physical model allowed us to take into account all the experimental evidence. We suggested that voltage deviations from... 

Here, SnO2 nanoribbons (NRs) synthetized on the catalyst-free stainless steel (SS) substrate as a possible anode for Li-ion batteries (LIBs) have been reported. SnO2 NRs were synthesized on catalyst-free SS substrate via vapor-solid (VS) growth approach. Morphological and structural characterizations of the SnO2 NRs were confirmed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) microscopes and x-ray diffraction (XRD) respectively. The prepared binder-free electrode demonstrated high initial discharge/charge capacities of 1818/929 mAh g-1 at current density of 300 mA g-1. A reversible capacity of 676 mAh g-1 with a coulombic efficiency of 98.5% has been... 

Multimode macroscopic states consisting of a superposition of spin coherent states that are generated in a trapped ion system are introduced. The role of various parameters that control the entanglement of the system are exposed, and their effects are quantified. In particular, it is shown that the generated states exhibit different entanglement characteristics for odd and even 2nj, where j is the spin of each mode and n is the number of modes. © 2018 Optical Society of America  

According to the importance of polyanion cathode materials in intercalation batteries, they may play a significant role in energy-storage systems. Here, evaluations of LiMBO3 and NaMBO3 (M = Mn, Fe, Co, Ni) as cathode materials of Li-ion and Na-ion batteries, respectively, are performed in the density functional theory (DFT) framework. The structural properties, structural stability after deintercalation, cell voltage, electrical conductivity, and rate capability of the cathodes are assessed. As a result, Li compounds have more structural stability and energy density than Na compounds in the C2/c frame structure. Cell voltage is increased by increasing the atomic number of the transition... 

Impure rhenium and molybdenum bearing solution was passed through a column of Varian strong base anionic resin for selective adsorption of rhenium and molybdenum ions from the solution. Elution of molybdenum and rhenium was carried out using 2 N NaOH and 0.2 N NH4SCN, respectively. The effect of resin bed height on breakthrough time was investigated. Experimental and theoretical curves were compared with good agreement. The results showed that the behavior pattern of these curves was repeatable and almost constant. © 2006 Elsevier B.V. All rights reserved  

Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the... 

As the first part of a continued research on conversion of carboxymethyl cellulosesodium salt (CMC) to useful biopolymer-based materials, large numbers of cyanide functional groups were introduced onto CMC by grafting with polyacrylonitrile (PAN). The graft copolymerization reactions were carried out under nitrogen atmosphere using ceric ammonium nitrate (CAN) as an initiator. Evidence of grafting was obtained by comparing FTIR spectra of CMC and the graft copolymer as well as solubility characteristics of the products. The synthetic conditions were systematically optimized through studying the effective factors including temperature and concentrations of initiator, acrylonitrile monomer,... 

The gas-phase metal affinities of histidine Li+, Na+ and K+ ions have been determined theoretically employing the hybrid B3LYP exchangecorrelation functional and using 6-311++G** basis sets. All computations indicate that the metal ion affinity decreases on going from Li+ to Na+ and K+ for the considered amino acid. Different types of M+ coordinations on several histidine conformers/tautomers were considered in detail. The optimized structures indicate that Li+ and Na+ prefer a tri-dentate coordination, bonding with a nitrogen atom of imidazole ring (N τ), NH2, and an oxygen atom of a carbonyl, while in the K+-histidine lowest-energy conformer, the cation appears to be bi-coordinated to both... 

In this study, chalcopyrite concentrate produced in Sarcheshmeh copper plant was subjected to oxidative leaching investigation by cupric ion to determine the effect of several parameters on the copper and iron dissolution, including temperature of leaching, time of holding and cupric concentration as oxidant agent in a range of 38–97 °C, 1.5–8.5 h and 0.2–0.8 M, respectively. The leaching media was chloride providing with 3 M HCl 37% and CuCl2. The experiments were designed by central composite design method. The dissolution of copper and iron was examined. The maximum dissolution of copper 62.64%, was obtained at 85 °C, 7 h and oxidant concentration of 0.7 M. The kinetics model of... 

Copper phthalocyanine was used as ion carrier for preparing polymeric membrane selective sensor for detection of iodide. The electrode was prepared by incorporating the ionophore into plasticized poly(vinyl chloride) (PVC) membrane, coated on the surface of graphite electrode. This novel electrode shows high selectivity for iodide with respect to many common inorganic and organic anions. The effects of membrane composition, pH and the influence of lipophilic cationic and anionic additives and also nature of plasticizer on the response characteristics of the electrode were investigated. A calibration plot with near-Nernestian slope for iodide was observed over a wide linear range of five... 

Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the... 

In this study, the Geant4 toolkit is utilized to present a new approach for simulation of the D-T interaction. The neutron production cross-section and the energy/angle distribution of neutrons produced as the D-T data libraries are incorporated in the Geant4, and their performance is evaluated. The spectra shape of the produced neutrons of the D-T interaction simulated by the Geant4 show good agreement compared to the results of the comparative codes (i.e. MCUNED, ENEA-JSI, and DDT). However, some differences are observed, especially, in angular range of 90-95 degrees. The reason for these differences as well as the results of the proposed approach in comparison with the results of the... 

Abstract: The production of Z bosons is studied in the dimuon and dielectron decay channels in PbPb and pp collisions at (Formula presented.) TeV, using data collected by the CMS experiment at the LHC. The PbPb data sample corresponds to an integrated luminosity of about 166 μb−1, while the pp data sample collected in 2013 at the same nucleon-nucleon centre-of-mass energy has an integrated luminosity of 5.4 pb−1. The Z boson yield is measured as a function of rapidity, transverse momentum, and collision centrality. The ratio of PbPb to pp yields, scaled by the number of inelastic nucleon-nucleon collisions, is found to be 1.06 ± 0.05 (stat) ± 0.08 (syst) in the dimuon channel and 1.02 ± 0.08... 

Argon is often considered as an innocent probe that can be attached and detached to study the structure of a particular species without perturbing the species too much. We have investigated whether this assumption also holds for small copper cationic clusters and demonstrated that small but significant charge transfer from argon to metal changes the remaining binding positions, leading in general, to weaker binding of other argon atoms. The exception is binding to just one copper ion, where the binding of the first argon facilitates the binding of the second. © 2020 American Chemical Society