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A rapid and convenient synthesis of gem-bis(dithiocarbamate) derivatives from primary aliphatic amines, carbon disulfide, and aromatic aldehydes using boron trifluoride-diethyl etherate

Nemati, F ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1016/j.tetlet.2014.04.106
  3. Abstract:
  4. An efficient route for the synthesis of gem-bis(dithiocarbamate) derivatives is developed using dithiocarbamic acid salts generated from primary aliphatic amines and CS2. The method offers high yields, employs mild reaction conditions, and demonstrates excellent functional group compatibility. The structures of the products were confirmed spectroscopically and by X-ray analysis
  5. Keywords:
  6. Boron trifluoride-diethyl etherate ; Carbon disulfide ; Dithiocarbamic acid salt ; Primary aliphatic amine ; Aldehyde ; Aliphatic amine ; Boron derivative ; Bithiocarbamic acid derivative ; Functional group ; Gem bis(dithiocarbamate) derivative ; Unclassified drug ; Carbon nuclear magnetic resonance ; Catalyst ; Chemical reaction ; Chemical structure ; Infrared spectroscopy ; Proton nuclear magnetic resonance ; Reaction time ; Synthesis ; X ray analysis
  7. Source: Tetrahedron Letters ; Vol. 55, Issue. 25 , 2014 , Pages 3572-3575 ; ISSN: 00404039
  8. URL: http://www.sciencedirect.com/science/article/pii/S0040403914007436