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Studies on the oxygen barrier and mechanical properties of low density polyethylene/organoclay nanocomposite films in the presence of ethylene vinyl acetate copolymer as a new type of compatibilizer

Dadfar, S. M. A ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1016/j.matdes.2010.12.028
  3. Abstract:
  4. Nanocomposite films based on low density polyethylene (LDPE), containing of 2, 3, and 4. wt.% organoclay (OC) and ethylene vinyl acetate (EVA) copolymer as a new compatibilizer were prepared and characterized using rheological tests, X-ray diffraction, differential scanning calorimetry, oxygen permeation measurements, and tensile tests. There was no exfoliation or intercalation of the clay layers in the absence of EVA, while an obvious increase in d-spacing was observed when the samples were prepared with EVA present. This issue was reflected in the properties of nanocomposites. The oxygen barrier properties of the LDPE/EVA/OC film were significantly better than those of the LDPE/OC film. The average aspect ratio of clay platelets in nanocomposites was determined from permeability measurements and using Lape-Cussler model. In addition to barrier properties, the LDPE/EVA/OC film also had better elastic modulus than their counterparts without EVA. The modulus reinforcement of nanocomposites was studied using Halpin-Tsai equations, which are universally used for composites reinforced by flake-like or rod-like fillers
  5. Keywords:
  6. A. Nanoclay ; A. Nanocomposite ; B. Film ; A. Nanocomposite ; B. Film ; Barrier properties ; Clay layers ; Clay platelets ; D-spacing ; Ethylene vinyl acetate copolymer ; Halpin-Tsai equations ; Low density ; Nano clays ; Nanocomposite film ; Oxygen barrier properties ; Oxygen barriers ; Oxygen permeation ; Permeability measurements ; Rheological test ; Tensile tests ; Aspect ratio ; Capillary flow ; Copolymerization ; Copolymers ; Density (specific gravity) ; Differential scanning calorimetry ; Ethylene ; Film preparation ; Geologic models ; Low density polyethylenes ; Mechanical properties ; Nanostructured materials ; Oxygen ; Polyvinyl acetates ; Tensile testing ; X ray diffraction ; Nanocomposites
  7. Source: Materials and Design ; Volume 32, Issue 4 , 2011 , Pages 1806-1813 ; 02641275 (ISSN)
  8. URL: http://www.sciencedirect.com/science/article/pii/S0261306910007569