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Tailoring dicobalt pacman complexes of schiff-base calixpyrroles towards dioxygen reduction catalysis

Askarizadeh, E ; Sharif University of Technology | 2010

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  1. Type of Document: Article
  2. DOI: 10.1039/b923189g
  3. Publisher: 2010
  4. Abstract:
  5. By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water
  6. Keywords:
  7. Calixpyrrole derivative ; Cobalt derivative ; Hydroxyl group ; Macrocyclic compound ; Oxygen ; Porphyrin derivative ; Pyrrole derivative ; Schiff base ; Unclassified drug ; Water ; Asymmetric synthesis ; Catalysis ; Chemical reaction kinetics ; Chemical structure ; Electron ; Reduction kinetics ; Structure analysis ; Cobalt ; Molecular structure ; Organometallic compounds ; Oxidation-reduction ; Pyrroles ; Schiff Bases
  8. Source: Chemical Communications ; Volume 46, Issue 5 , 2010 , Pages 710-712 ; 13597345 (ISSN)
  9. URL: http://pubs.rsc.org/en/Content/ArticleLanding/2010/CC/B923189G#!divAbstract