Loading...

Highly efficient Michael addition reaction of amines catalyzed by silica-supported aluminum chloride

Saidi, M. R ; Sharif University of Technology | 2009

937 Viewed
  1. Type of Document: Article
  2. DOI: 10.1080/00397910802499559
  3. Publisher: 2009
  4. Abstract:
  5. Aliphatic and aromatic amines undergo smooth nucleophilic addition to α,β-unsaturated compounds in the presence of a catalytic amount of silica-supported aluminum chloride at 60°C and under solvent-free conditions to produce the corresponding β-amino compounds in excellent yields. This method is simple and convenient and works efficiently under mild conditions. This catalyst can used again without losing its activity three times. Copyright © Taylor & Francis Group, LLC
  6. Keywords:
  7. α,β-unsaturated olefins ; Amines ; Michael addition ; Silica-supported aluminum chloride ; Acrylic acid methyl ester ; Aliphatic amine ; Aluminum chloride ; Aniline ; Aromatic amine ; Nucleophile ; Silicon dioxide ; Article ; Catalysis ; Catalyst ; Chemical structure ; Temperature
  8. Source: Synthetic Communications ; Volume 39, Issue 6 , 2009 , Pages 1109-1119 ; 00397911 (ISSN)
  9. URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-60849103789&doi=10.1080%2f00397910802499559&partnerID=40&md5=a9fd41a893ffd5d5bb07821baacd1fd3