Sharif Digital Repository

Superparamagnetic iron oxide nanoparticles (SPION) with proper surface coatings are increasingly being evaluated for clinical applications such as hyperthermia, drug delivery, magnetic resonance imaging, transfection, and cell/protein separation. Since the particles with various sizes exhibit different flow rates in the same environment (same capillary size), it is essential to use particles of a desirable size for targeted drug delivery and imaging. Particles of different sizes may be exposed to different viscosities and behave differently, particularly with regard to their velocities as they move through capillaries. In the present work, SPION with different size, purity, shape and... 

The removal of ethylene glycol, one of the most widely used antifreez, with moving bed biofilm reactor (MBBR) was studied. Beside of ethylene glycol, the synthetic wastewater contained molasses and other salts as nutrient source. The packings were composed of polyethylene and shaped like small cylinders with a surface area of 500 m2 per m3 bulk volume of carriers(KMT). The COD of the feed was adjusted by varying the ratio of ethylene glycol to molasses. The total COD was 1252.5, 1345 and 1500 mg/L. The resulted showed that when the biofilm grows on the packings and its thickness is good enough, the removal efficiency increased. The increase was attributed to higher concentration of biomass... 

One of the most significant consequents of industrial world is environmental pollutions which displays its mortal effects in all aspects of human life including water, atmosphere and soil. After different applications of water, variable substances like organic and mineral components, toxics, heavy metal, etc is added to the water and wastewater. One of these organic components which appear in runoff and industrial wastes specially refinery companies’ is Ethylene Glycol (EG). It is used in Poly ethylene Glycol, Poly Viniles and Resin product industries, etc. In this research the effect of EG on COD removal and performance of an Anaerobic Baffled Reactor during treating Ethylene Glycol... 

In the present study , operation of a laboratory scale sequencing batch reactor (SBR) was evaluated to treatment of synthetic wastewaters containing ethylene glycol. Studies carried out with a plexiglass bioreactor whith effective volume of 18 lit.Aeration was supplied via two air diffusers that set at the bottom of the reactor. Synthestic wastewater containing ethylene glycol and molasses as carbon source and other nutrient such as diammonium hydrogen phosphate as phosphor source and urea as nitrogen source for biological activities was composed at the laboratory. To optimization of this reactor three parameters – aeration time, chemical oxygen demand and sudden change in arganic loading... 

In this research, MBBR was used to study petrochemical and gas refinery industry's low strength wastewater COD removal for reuse purposes. Reactor's feed was synthesized based on data analysis conducted by fourth wastewater treatment facility operating in phases 6,7 and 8. Inlet COD was 70 mg/L and this COD was provided by different portions of Mono ethylene glycol and Tri ethylene glycol. COD removal was studied under 1, 2 and 3 hours hydraulic retention time. Reactor's feed was provided with COD ratio of ( 〖COD〗_MEG/〖COD〗_total ) 65%, 60% and 50%. For the first time, hybrid combination of activated sludge system and MBBR was carried out and recycle stream was used in this system. The... 

Biocompatible porous polymeric scaffolds provide a suitable 3-D environment for proliferation of stem cells in human body. For instance, growth and proliferation concurrent with differentiation of stem cells in such scaffolds can regenerate the tissues or organs. In this attitude we fabricated a porous Gelatin-based scaffold using both of freeze-drying and freeze-extraction methods.Also, effect fo gamma irradiation on microstructure of scaffolds was investigated. In addition, poly(ethylene glycol) was employed to make the scaffold softer. Moreover, effects of various parameters including freezing temperature, cross-linking agent concentration, gelatin and PEG concentrations and their... 

A novel thermo responsive decorated system is designed by coating Fe3O4 magnetic nanoparticles with conjugated Pluronic-ATPEG copolymer incorporated into the PEG-PMDA Hydrogel for drug delivery to the cartilage tissue. Grafted copolymer was synthesized by reaction between carboxylated Pluronic and amino terminated Poly ethylene glycol (ATPEG) and confirmed by FTIR and NMR analysis. The magnetic nanoparticles were modified with the produced copolymer and characterized by TEM, HRTEM, XRD, DLS, and VSM. A typical product has 13 nm magnetic core and 105 nm hydrodynamic diameter with narrow size distribution. DLS results showed that there was an increase in size by increasing temperature from 25℃... 

Surface phenomena is one of the fundamental branches of science that has many applications in industries related to multiphase processes. One of the most important issues of this knowledge is inter-phase transport phenomena in contacting gas - liquid and liquid – liquid systems. Multiphase systems generally include dispersions such that in many cases are associated with the relative motion between the continuous and dispersed phase. One of the most widely used inter-phase flow systems is dispersion of gas bubbles in the bulk of liquid. The overall efficiency of these systems is often determined by the characteristics of the gas phase. In order to understand the dynamic behavior of such... 

In this study, the effects of different corrosion inhibitors on the corrosion of aluminum alloy which is used in the cooling systems of automotive industries were investigated. Also a comparison between the corrosion behaviour of the mentioned aluminum alloy with and without any galvanic connection to 5 different metals consist of solder, stainless steel, mild steel, brass and copper was done. The corrosion rate became more by establishing galvanic coupling. The base solution was ethylene glycol and water which is the base part of all antifreeze compounds. The tests were done at high temperature about 88ºC. Two different industrial corrosion inhibitors were examined in these conditions.... 

A Microbial fuel cell is a Bioreactor in which chemical bands are broken and their energy convert to electricity by bio-catalysts such as microorganisms and enzymes. Depletion of energy resources encouraged researchers to investigate microbial fuel cell as a power bio-resource. MFCs produce electricity or hydrogen without any net carbon emission. Nowadays, real applications of microbial fuel cells are limited because their power density level is very low (about 1000 mW/m2). Many research projects are running to modify MFCs operation and optimize its costs. The most important application of MFCs is electricity production, hydrogen production, waste water treatment and BOD5 biosensor. In this... 

A Microbial fuel cell is a Bioreactor in which chemical bands are broken and their energy convert to electricity by bio-catalysts such as microorganisms and enzymes.In this project, construction, substrate investigation and optimization of operational parameters were done. Microbial fuel cell as a waste water treatment method was considered in this project. As a result, different substrate were used in anode chamber of constructed microbial fuel cell. The most important ones were waste water containing ethylene glycol and crude oil.Consequently, lack of information about cathode operational parameters was led to optimum condition selection for pH, buffer concentration and ionic strength as... 

Titanium dioxide, due to its specific semiconductive properties, has been a highly investigated material for a variety of applications including gas sensors, hydrogen generation by water photoelectrolysis, photocatalysis, dye-sensitized solar cells and purification of water and air. Several recent studies have indicated that titania nanotubes have improved properties compared to any other form of titania for mentioned application. Titania nanotubes have been produced by a variety of methods including deposition into a template and hydrothermal processes. Anodic oxidation of titanium foil in a fluoride-based solution is one of the best methods to produce of titania nanotube arrays. Highly... 

Inhencemant of automobile radiator heat performance is the purpose of this study. Radiator fin shape, coolant fluid properties and influence of nanofluid studied in this research. Plain fin, louvered fin and vortex generator fin is choosen and design. With flow simulation influence of fin shape on heat performance is studied. After that, with considering radiator coolant fluid, the effect of antifreezing on fin heat transfer is evaluated. Then by addin nanoparticles to water and antifreezing solution, effect of nanofluid on heat transfer is evaluated. Results show that with increasing the air velocity for all geometries in the study , heat transfer and pressure drop is increased. But heat... 

In this project, the feasibility of hydrocarbon waste water treatment with low concentration by physical- chemical treatment methods will be discussed. The purpose of this thesis is to investigate the feasibility of reusing the water outlet of the oil and gas refineries, in the region of ASALUYEH where there is an urgent need for water. By using activated carbon and wooden absorbent (absorption method) efficiency of this method was determined. Both coagulation and flocculation methods were investigated. To design and optimize various operating conditions on the adsorption process the RSM method was used. Temperature, residence time, feed concentration, amount of adsorbent, and adsorbent ... 

In this research, nanocomposite containing reduced graphene oxide nanosheets (RGO) and trimetallic three-dimensional (3D) Pt-Pd-Co porous nanostructures was fabricated by galvanic replacement technique. First, GO suspension was drop-casted on the electrode surface, then GO film reduction was carried out by cycling the potential in negative direction to form the RGO on GCE (RGO/GCE). Then, electrodeposition of the cobalt nanoparticles (CoNPs) as sacrificial seeds was performed onto the RGO/GCE by using cyclic voltammetry. Afterward, Pt-Pd-Co 3D porous nanostructures fabrication occurs through galvanic replacement method based on a spontaneous redox process between CoNPs and solution... 

Today, hydrogels have various biomedical applications as three-dimensional networks with the ability to absorb and retain water and biological fluids. This study aimed to prepare nanocomposite hydrogels from polyvinyl pyrrolidone, polyethylene glycol, and barium titanate nanoparticles. Gamma radiation at irradiation doses of 25 and 35 kGy was used as the hydrogel's crosslinking agent. The effects of gamma irradiation dose, percentage of polyethylene glycol, and barium titanate composition on the swelling ratio and gel content were investigated. It was observed that the amount of gel content with the addition of polyethylene glycol and barium titanate nanoparticles reduces the gel content and...