Sharif Digital Repository

Dye-sensitized solar cells (DSSCs) are Photoelectrochemical cells using wide band gap nanoporous oxide semiconductors sensitized by dye molecules. For achieving high efficiency DSSCs preparation of photoanode electrode with high surface aea which leads to adequate dye absorption is necessary. In order to achieve proper morphology, thickness, particles size and porosity, producing a TiO2 nano-structured paste is required. TiO2 powder was prepared using sol-gel method. following a calcination process at 300 degrees, XRD patterns showed presence of anatase and brookite structures with average crystallite size of 9 nm. Additives such as diethylene glycol, acetylacetone and Triton X-100 were used... 

In this research, we focus on study and investigation of the role of Tin(IV) Sulfide (SnS2) nanostructured layer as electron transport layer in perovskite and chalcogenide thin film solar cells. For this purpose, SnS2 powder was prepared through hydro/solvo-thermal method, utilizing different ratios of water and ethanol as solvent and various sulfur sources (thioacetamide and thiourea). Afterwards, different solvents were investigated to achieve a stable ink (about one month) with uniform dispersion. After determining the appropriate ink and powder, thin films of SnS2 were prepared employing spin coating, spray pirolysis and laser pulsed deposition (PLD) methods and characterized. With each... 

In just a decade, perovskite solar cells have emerged as the next generation of photovoltaic technologies due to their high efficiency, low manufacturing cost, and easy fabrication methods compared to silicon solar cells. To date, highly efficient perovskite cells (with an efficiency of approximately 25.5%) have been fabricated on small substrates by a spin-coating process. In the spin coating process, perovskite precursor is spread on the substrate through shear force. However, the reproducibility of the cells coated with this method varies between research laboratories. Furthermore, since the solution is wasted during the deposition of the perovskite precursor on large substrates, a... 

Solution-processed quantum dots (QDs) have attracted significant attention for the low-cost fabrication of optoelectronic devices. Here, we synthesized PbS QDs via hot injection method and passivated the trap states by using short thiols and dopant elements for photovoltaic application. In order to study the effect of dopants on photovoltaic application, PbS QDs were doped by using three different cations: Cadmium, Calcium, and Zinc. The results showed that Cd dopant has a better improvement than Ca and Zn dopants in order to increase the efficiency of the PbS QDs solar cells. We achieved solar power conversion efficiencies of 5.81% using Cd therapy. Recently, hybrid nanocomposites... 

In this thesis, we focus on studying and fabrication of doped titanium dioxide electrodes and their application in nanostructured dye sensitized solar cells (DSSCs). For this purpose, non-metallic nitrogen (N) and metallic neodymium (Nd) elements were selected. N-doped titanium dioxide nanoparticles were synthesized via solvothermal method and their structural and optoelectrical properties were investigated in comparison to undoped titanium dioxide synthesized by the same method. Based on the obtained results, doping of titanium dioxide by nitrogen resulted in shifting the Fermi level up-ward, increase in charge carriers density, shift of optical absorbance to higher wavelength, and decrease... 

Thin film solar cells have low efficiency compared to crystalline silicon solar cells; however, they are low-cost and flexible. In manufacturing these solar cells, thin films are deposited at high temperatures (higher than 200℃) on a thick metal, plastic, or glass substrate using sputtering and plasma enhanced chemical vapor deposition (PECVD) methods. Since the thin films and substrate have different thermal expansion coefficients, cooling the system from deposition temperature to room temperature induces thermal residual stresses in both the films and substrate. In addition, these stresses, especially those induced in the amorphous silicon layer can change the carrier mobility and band gap... 

In recent years, thin-film photovoltaic cells with thicknesses of less than 1-2 µm have been developed with potentially lower production costs. Due to the small thickness of the absorbing semiconductor in these cells, the absorption is inevitably low at energies close to the electronic band gap of the semiconductor. This is particularly a problem for thin-film devices. Recently، periodic metallic nanostructures supporting surface plasmons have been introduced as alternative solutions to achieve light trapping in thin-film solar cells.Full numerical methods are usually used for the analysis of these periodic structures. The main drawback of these methods is that they are time-consuming and... 

Dye Sensitized Solar cell (DSC) is the third class of solar cell, which consists of a nanocrystalline, mesoporous of semiconductor(The best one is Tio2), covered with a monolayer of dye molecules, platinum coated on FTO as a counter electrode and a redox electrolyte. This Photovoltaic cell which is promising low-cost materials, works on electron separation of dye molecule, and electron injection to semiconductor’s conduction photo- electrode structure and its porosity is affected the DSC’s performance. Recently, use of electrophoretic deposition (EPD) for TiO2 electrode (which best found for photo-electrode in DSC) fabrication has gained increased interests. In this method charged particles... 

In recent years, the use of thin film solar cells has been widely considered due to the ability of their solution-based coatings. One of these is the chalcopytie solar cell copper indium gallium di-selenide (CIGS). The absorber layer of copper indium gallium diselenide was carried out by a spray pyrolysis method. then by using a chemical bath deposition, a buffer layer was fabricated to form the p-n junction. Subsequently, silver nanoparticles and zinc oxide alumina sputtering were used to form a transparent conductive film. with using the substrate Molybdenum and by optimizing the test conditions, such as temprature and deposition time to adjust thickness of layers, Cell with an... 

This research is focused on fabrication of TiO2 layers by electrophoretic deposition (EPD) for application as photoanode in Dye Sensitized Solar Cell (DSC). DSCs are third generation of solar cells, also known as the Grätzel cell, after its inventor Michael Grätzel. A DSC is composed of a porous layer of wide band gap semiconductor such as TiO2 and ZnO, covered with a molecular dye that absorbs sunlight, and a counter electrode contacted by a liquid redox electrolyte. Dye Sensitized semiconductor (photoanode) has important role in conversion of photon to electricity. To achieve higher efficiency, preparation of photoanode with high surface area resulted to enough dye adsorption is necessary.... 

Today organometallic perovskites are very important in fabrication of solar cells. This materials have advantages like high mobility of charge carriers, changing in range of light aborption with changing in structures atoms, having longer charge carrier diffusion lengths than other materials, high stability and efficiency, Low-cost fabrication process, having capability of studying and processing in low temperatures and having flexibility because of Weak chemical bond in perovskite structure. Due to the low stability and rapid decomposition of this material with the presence of light and moisture, in this study has tried to use PbS quantum dots which is used in sensitive dye solar cells as... 

In the last years, perovskite QDs have emerged as the novel candidate due to their unique optical properties such as high-absorption coefficient, long-range charge transport, low exciton-binding energy, and etc. Nonetheless, poor stability of perovskite in ambient conditions made researchers to consider this issue. Recently, amoung various types of organic-inorganic perovskites, Formamidinium lead iodide has attracted tremendous attention due to its near IR absorption wavelength in addition to the higher stability compared to MAPbI3. In this work, FAPbI3 perovskite stability improvement was investigated by several methods under different conditions. In the first step, FAPbI3 QDs colloidal... 

In this thesis, pure –known as T- and chromium doped titanium dioxide nanoparticles –known as -CTx- with different dopant atomic ratio (0.1 to 5 %at.) were synthesized using a facile, fast and efficient method. FESEM and XRD studies showed no morphologic and structural change via Cr doping of nanoparticles (size in the range of 20-30 nm). However, according to DRS analysis, Cr intrusion in TiO2 crystal structure, drastically reduced band gap energy of pure TiO2 from 3.14 eV to 1.81 eV for CT3 powder and improved absorption range of UV-Vis spectrum. Mott-Schottky plots indicated that, Cr doping, caused reduction in donor density of TiO2 and an upward shift in the conduction band edge.... 

Different structures of TiO2 photoelectrodes were fabricated with different structures and arrangement modes of the layers. TiO2 Nanoparticles were synthesized by solvothermal method and the effect of solvothermal processing parameters on morphology and crystal structure of nanoparticles was studied. Hierarchical and spherical TiO2 particles were synthesized to use in photoanode electrode as light scattering particles. FE-SEM and XRD analyses revealed that TiO2 nanoparticles had uniform and nanometer grains with particle size around 20nm and average crystallite size of 4nm. The optical properties of TiO2 particles were studied through UV–Vis absorption and DRS analysis. The indirect optical... 

Power harvesters are used to generate energy for electronic devices. These electrical energy generators consist of three main parts: energy source, power electronic converter and energy storage. In order to minimize some of the weaknesses of these devices, including low power density and low reliability, the hybrid power harvesting method can be utilized. In this thesis, we design and build a hybrid energy harvester considering the advantages of simultaneous usage of solar and thermal energies for a wearable sensor, focusing on "efficiency enhancement" and "availability improvement". In the designed device, both solar and thermal energy harvesting units operate independently. In the solar... 

In this thesis, the goal is to improve the efficiency of quantum and solar cell. The effect of quantum wells was simulated by Silvaco. Initially, the quantum well has been adjusted to a cell junction GaAs. Then, using quantum wells in cell junction towing and three, improving short-circuit, the returns will be 53.79% and 54.33%. This efficiency is about 10% more than the triple-junction solar cells. To improve the efficiency effects of layer thicknesses, parameters, and the number of quantum wells were studied.Tandem cell is 〖In〗_0.51 〖Ga〗_0.49 P/GaAs, and triple is 〖In〗_0.51 〖Ga〗_0.49 P/GaAs/〖In〗_0.28 〖Ga〗_0.72 As. By adjusting the quantum well and sandwiching the well layers staggered by... 

Today usage of microwave integrated circuits in commercial and military applications is very common, especially with emerging of monolithic microwave integrated circuits that make mass production with good quality and price possible. A lot of attention are paid to designing power amplifiers used in the end of transmitter line. Because of power dispersion in transistor channels, high power amplifier causes excessive heat on the chip. Channel temperature increasing, causes operation retrogradation in circuits that result in destruction of the chip. So it is necessary to transfer this heat to the outside from the chip. It is usual to use a heatsink for this problem, however for low thermal... 

Hand-launched UAVs are type of unmanned aerial vehicles that due to transportability and geometric specification, are operationally valuable and worthy. reconnaissance & surveillance (aerial mapping, aerial filming, inspection, border protection); health care (blood transport, body organ transport, medicine delivery); agriculture (farm monitoring, fertilization, cloud seeding); payload delivery (envelopes posting); network covering (internet supply, telecommunication relay); crisis management (remote area medical) are some of typical applications and missions of this type of aircrafts. These UAVs have almost low altitude short endurance (below 5000 ft. and less than 2 hrs.). To extend their... 

Solar cells are one of the most promising clean and readily available energy sources. Organic solar cells as a new generation of solar cells, have attracted strong attention in recent years, due to the advantages of flexibility, thinness, and simple manufacturing process. This work focuses on the electrical processes in organic solar cells and approaches for enhancing the efficiency of solar cell by employing two-dimensional drift-diffusion model. At the first step. We investigate the role of different parameters such as mobility (considering different recombination mechanisms), active layer thickness, light intensity, barrier injections and energetic disorder on the performance of single...