Sharif Digital Repository

The main objective of this research was to evaluate the application of a new strain of Brevundimonas naejangsanensis which is newly identified sulfate-reducing bacteria (SRB), in bioremediation. A laboratory scale packed bed reactor (PBR) was fabricated and operated to study the new bacteria’s feasibility on SO_4^(2-) reduction. The reactor was packed with polyurethane foam cubes and operated under different feeding and operating conditions of HRT, COD/SO_4^(2-) ratio and salinity. A maximum SO_4^(2-) reduction of 73.6% was achieved in the PBR when operated at an HRT of 12 h with SO_4^(2-) concentration of 670 mg/L, COD/SO_4^(2-) ratio of 1 and salinity of 3%. The results show that this... 

Nowadays a major part of energy, fresh water and sewer water in over the world are transmitted by buried pipe, and always these lines are under the loads and different stresses such as corrosion, earth quick and etc.
In many countries the age of these lines are more than 30 years which causes corrosion of the pipe wall and the necessity of health investigating of transmission lines has a special importance for the governments and leak detection can also keep the natural environment healthyand the costs will come down significantly, scientists and researchers have always tried different ways to check the health of the pipes.
In the field of leak detection and the problems of age... 

Carbon nanotubes, due to their extraordinary electronic and physical properties, have attracted much attention in the last decade. Some of their potential applications are in CNT-field effect transistor, field emission devices, physical and chemical sensors, micro and Nanoelectromechanical systems and Nano antenna. In this thesis, we have first reviewed some features of carbon nanotubes and the advantages of PECVD method compared with thermal CVD. In the second part the role of some of the materials (such as H2/NH3/C2H4) in CNT growth are studied. We created a square pattern on the silicon wafer by photolithography. Afterwards, titanium and nickel deposition is done on the mentioned pattern.... 

Chemical flooding has great potential to recover significant fractions of remaining oil for medium to heavy oil reservoirs not applicable for thermal recovery techniques. Nowadays, with gradual crude oil price increase the chemical process is receiving renewed attention, however, illustration of the possibility of various chemical injection scenarios for medium to heavy oil reservoirs has not been clearly reported and these kinds of reservoirs require more investigation for the applicability of these techniques in the fields. The interfacial active molecules are responsible for providing low IFT range and water/oil emulsions which in many cases could improve the oil displacement efficiency.... 

Nowadays, silicon based devices especially carbon nanotubes received lots of attentions and advancement from researchers and industries. Because of amazing electrical and mechanical properties and wide range of applications, CNTs are received a lot of attention from nanoelectronics experts. There are lots of CNT growth methods such as: Arc Discharge, Laser Ablation, Surface Decomposition, CVD and PECVD.
In this thesis, we are going to use PECVD method to synthesis CNT. A typical PECVD system includes two parallel electrodes that have been packed in vacuum chamber and gases like argon, hydrogen and NH3 are introduced to chamber as a reactant gas.
In this thesis, firs we had fixed... 

In this work, a novel type electrode based on RuO2 nanoparticles-modified vertically aligned carbon nanotubes (RuO2/MWCNTs) was investigated. ThisRuO2/MWCNTs electrode not only shows a high capacity nature,but also possesses a good response to the pH value. In order to develope this sensor, aligned carbon nanotubes were synthesized by the chemical vapor deposition at first and then modified with RuO2 nanopartcles by sol-gel method. Various parameters affecting the growth of nanotubes, such as substrate type, surface finishing, surface roughness, the growth temperature and carbon feed rate was studiedand and optimal conditions for growth were obtained. At last, aligned nanotubes with a... 

In this project, function of anaerobic digestion of organic waste in liquid phase and treating the following sewage in biologic tower(trickling filter) has been investigated in an experimental process. Solid waste were supplied from sharif university restaurant and after weighting and classification is added to tanks which filled by 40% sludge and 60% water. For controlling the function of biologic tower, a control reactor were used. Retention time for digestion of solid waste is 40 day. First solid loading was 500g and 75g organic waste in main & control reactor equal to 5(kg solid waste)/( m^3.reactor.day) 1.3(kg TS)/( m^3.reactor.day) and were doubled in second loading. It seems that... 

An important issue in aerospace propulsion systems is the reacting flow analyses, which involve many different concepts and physics including various chemical reactions mechanisms and radiation and convection heat transfer physics. As known, the computer simulation is a powerful tool to analyze the reacting flow physics in various combusting environments. It can suitably provide details of both chemical reaction occurrences and heat transfer physics. In combustion environments, the temperature gradient is noticeably affected by the density gradient. On the other hand, the accurate modeling of density gradients highly affects the computational results. In practice, the density-based methods... 

Asphaltene precipitation and deposition are sources of a number of problems for petroleum industry. Thus, solving the problem of precipitation and deposition is very important. In order to measure deposition level, study of other asphaltene flocculation is vital; since there is a time interval between precipitation and deposition. Use of chemical inhibitors is one of the best methods for prevention of asphaltene precipitation that could postpone precipitation point and prevent formation of huge flocculations. In this study, effects of asphaltene flocculation size on deposition with or without using inhibitors were investigated. In this regard, QCM was used for measuring the amount of... 

Emission control, especially Carbon Monoxides (CO) as one of the major by-products of combustion processes, is one of the most serious challenges in burning waste-gases with high amounts of humidity and Carbon Monoxide. We investigated an oil waste-gas incinerator serving to a bitumen production line located in Pasargad Oil Company, Shazand, Arak, Iran. The aforementioned incinerator was criticized seriously for its high CO emissions. We were requested to find a solution to reduce the undesirable CO emission from that. Following the environmental standards, there is an upper limit of 150 ppm for the CO produced by an industrial waste oil incinerator. To present an inclusive solution for such... 

In this thesis NJL and quark-meson models, as effective models for quantum chro-modynamics in low energies, are studied mainly. After reviewing models and phe-nomena related to the strong interaction in zero and non-zero temperature, firstly the critical coupling of NJL model for non-zero temperature and chemical potential is calculated. Then, the contribution of ring diagrams in the effective potential of quark-meson model is presented. Finaly, the effect of ring diagrams of quark-meson model on chiral phase transition is investigated. For NJL model, it is shown that the chemical potential lowers the critical coupling for chiral phase transition. Also for quark-meson model, it is shown that... 

In this research, we have used green tea polyphenols as green reductants for reduction of graphene oxide. Furthermore, for the first time, the presence of some metals such as iron, tungsten and copper in the efficiency of reduction is investigated. XPS spectra indicate that iron can be considered as one of the best choices for helping polyphenols in the reduction process. Hence, we used AFM, XPS, Raman spectroscopy and I-V diagram to characterize graphene oxide reduced by polyphenols and iron. In recent years, hydrazine has been recognized as one of the standard reducing agents for effective reduction of graphene oxide. In our analysis, it is found that the conductivity of our reduced... 

This thesis discusses the work on the production of a rhamnolipid-type biosurfactant by Pseudomonas aeruginosa MR01, its structural characterization and environmental applications. First, results from analytical approaches for screening of biosurfactant producers suggested the oil spreading method as the fastest, simplest and most consistent analytical method. The second part of the thesis describes the properties of the most efficient biosurfactant-producing bacteria isolated from oil fields in south of Iran and according to it’s biochemical characteristics and partial sequenced 16S rRNA gene affiliated with Pseudomonas aeruginosa. Time course study indicated that the maximum biosurfactant... 

Expansion of city boundaries as a result of increased population has reduced the distance from industrial complexes and health effects of industrial air pollution have been intensified. As such, studies are needed to determine appropriate methodologies for quantifying the effect of these industries on the concentration of air pollutants in urban areas. In this study, particulate emissions from a steel mill complex was modeled using ADMS4 and the predicted results were compared with actual measurements made in the adjacent urban area. A receptor model (CMB8.2) was also used to quantify the share of the steel mill on the heavy metals' concentrations in the city by considering other sources... 

Silicon carbide due to its noticeable mechanical and thermal properties, uses in various industries either main substrate or reinforcement. SiC has low specific surface area according to its resistivity against sintering. Recently, a lot of scientists have been worked on SiC in order to fabricating small ones ; subsequently, better sintering will be achieved. Chemical vapor deposition method (CVD) is a method to produce fine SiC with deposition of products by reacting of initial materials from gas environment. In this study normal CVD as proper method and hydrogen, silicon tetrachloride and activated carbon as initial materials are chosen. Using of iron and nickel catalysts in temperature... 

Maghemite (γ-Fe2O3) nanoparticles were produced after high temperature oxidation of gelatin-Fe3O4 nanocomposite, obtained from a common coprecipitation process of Fe2+ and Fe3+ ions in an alkaline medium in the presence of a gelatin protein as an effective mediator. Size, shape, surface morphology and magnetic properties of the prepared γ-Fe2O3 nanoparticles were characterized using XRD, FTIR, TEM, SEM and VSM data. The results revealed that primary, gelatin-Fe3O4 nanocomposite had been formed and next, the gelatin decomposition in furnace produced a spinel structure of γ-Fe2O3. The effects of furnace temperature and time of heating together with the amount of gelatin on the produced... 

In this thesis, photocatalytic oxidation as a potential method for the treatment of organic environmental contaminants is deeply investigated. While the photocatalytic degradation of various organic compounds under UV light irradiation has been widely investigated, visible-light-induced photocatalytic degradation of low-levels of the pollutants such as Dibenzothiophene (DBT) and 2-Nitrophenol (2-NP) are occasionally reported. In the present work, Lanthanide / Polyethylene glycol -modified TiO2 (La/PEG/TiO2) and Fe,Cu,S/TiO2 have been successfully synthesized by a sol–gel method. The photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission... 

The subject of this thesis to assessment environmental impacts of active desalination plants in Kish Island, which explains the problems derived from concentrate discharges in to the sea, sewage network, absorbing wells and ground surface.
It also studies its impacts on land and marine ecosystem and underground aquifers that are strategic resources in Kish Island. In addition, the environmental studies done in other countries, the existing regulations and by laws in the field of environmental impacts of desalination plants and concentrate discharges are re-mentioned. Concentrates contain chemicals, which are used in pre-filtration of MED and Ro systems, which are dangerous for marine... 

Currently PM2.5 is a major air pollution concern in Tehran, Iran due to frequent high levels and possible adverse impacts. In this study, which is the first of its kind to take place in Tehran, composition and sources of PM2.5 and carbonaceous aerosol were determined, and their seasonal trends were studied. In this regard, fine PM samples were collected every six days at four station for two years from February 2014 to February 2015 (first phase) and March 2015 to February 2016 (second phase). The samples were analyzed for ions, organic carbon (including water-soluble and insoluble portions), elemental carbon (EC), and all detectable elements. The source apportionment was performed using... 

Due to their adverse effects on human health and the environment, PM2.5 has been identified as one of the most important pollutants in Tehran. Considering the heterogeneous land use of this city, insufficient information on the amount and chemical components of these particles in its various regions, as well as lack of accurate information about the contribution of each source in the production of pollutants, this research investigates the concentration of fine particulate matter and its constituents in four stations of Tehransar, Sharif University of Technology, Shahid Mahallati and Shahriyar and studies their sources. Initially, the pollutant mass concentration and concentration of its...