Sharif Digital Repository

Novel vanadyl Schiff base complexes with the general formula VOLx (x = 7-18) were synthesized and characterized by physicochemical methods. Only an orange polymeric form was obtained for VOL13, both brown polymeric and green monomeric forms were obtained for VOLx, x = 16, 17. These observations suggest that in these complexes oxovanadium(IV) exhibit a coordination number of five. Systematic substitution on the ancillary ligand have allowed V(V)/V(IV) reduction potentials to be tuned over a range of approximately 130mV. The complexes are catalysts for the aerobic oxidation of cyclohexene. Catalytic activity increases with increasing V(V)/V(IV) reduction potential and the catalytic selectivity... 

The acidity and stability constants of M (MNPPAP) (MNPPAP: 2((4-methyl-5-nitro-6-(pyrrolidine-l-yl)pyrimidine-2-yl)amino)propionic acid) M: Cu2+, Cu (Bpy)2+ (Bpy: 2,2'-Bipyridine), or Cu(Phen) (Phen: 1,10-Phenanthroline) complexes were determined by potentiometric pH titration. It is shown that the stability of the binary Cu (MNPPAP) complex is determined by the basicity of the carboxylate group on one side and amine group on the other side. It is demonstrated that the equilibrium, Cu(Har)2+ (H ar: Heteroaromatic ligand such as Bpy or Phen) + Cu(MNPPAP) ^ Cu(Har)(MNPPAP) + Cu2+, is displacement due to the well known experience that mixed ligand complexes formed by a divalent 3d ion, a... 

The binuclear cyclometalated complexes [Pt2Me 2(ppy)2(μ-dppm)], 1a, and [Pt2Me 2(bhq)2(μ-dppm)], 1b, in which ppy = 2-phenylpyridyl, bhq = benzo{h}quinoline and dppm = bis(diphenylphosphino)methane, were synthesized by the reaction of [PtMe(SMe2)(ppy)] or [PtMe(SMe 2)(bhq)] with 1/2 equiv of dppm at room temperature, respectively. Complexes 1a and 1b were fully characterized by multinuclear (1H, 31P, 13C, and 195Pt) NMR spectroscopy and were further identified by single crystal X-ray structure determination. A comparison of the intramolecular Pt-Pt and π-π interactions in complexes 1a and 1b has been made on the basis of data on crystal structures and wave functions analysis. The binuclear... 

In this paper, we consider abnormality detection via diffusive molecular communications (MCs) for a network consisting of several sensors and a fusion center (FC). If a sensor detects an abnormality, it injects a number of molecules into the medium which is proportional to its sensing output. Two transmission schemes for releasing molecules into the medium are considered. In the first scheme, each sensor releases a different type of molecule (DTM), whereas in the second scheme, all sensors release the same type of molecule (STM). The molecules released by the sensors propagate through the MC channel and some may reach the FC where the final decision regarding whether or not an abnormality... 

Observability of complex systems/networks is the focus of this paper, which is shown to be closely related to the concept of contraction. Indeed, for observable network tracking it is necessary/sufficient to have one node in each contraction measured. Therefore, nodes in a contraction are equivalent to recover for loss of observability, implying that contraction size is a key factor for observability recovery. Here, developing a polynomial order contraction detection algorithm, we analyze the distribution of contractions, studying its relation with key network properties. Our results show that contraction size is related to network clustering coefficient and degree heterogeneity.... 

Node cooperation approaches improve physical layer security in wireless networks without applying data encryption. Selecting the appropriate nodes to cooperate as relays or friendly jammers, to degrade eavesdropper's link, is a challenging problem which has attracted a lot of attention in recent years. Various approaches, based on conventional exhaustive search, have been suggested for optimal relay-jammer selection and power allocation in the literature. The complexity of these methods is proportional to the number of intermediate nodes. As the number of intermediate nodes exceeds a specific bound, conventional exhaustive search appears infeasible due to high computational complexity. In... 

Oxygen evolution was observed upon mixing solid manganese(III) bidentate Schiff base complexes with aqueous solutions of cerium(IV) ammonium nitrate. However, oxygen evolution was not observed upon mixing solutions of the complexes (in acetonitrile) with Ce(IV). Electron-withdrawing substituents on the Schiff base ligands (NO2, Br) enhanced the reactivity of the manganese complexes toward oxygen evolution. Oxygen evolution was also affected by R groups on the ligands, in the order Me > Et Bz. © 2009 Springer Science+Business Media B.V  

Given a terrain and a query point p on or above it, we want to count the number of triangles of terrain that are visible from p. We present an approximation algorithm to solve this problem. We implement the algorithm and then we run it on the real data sets. The experimental results show that our approximation solution is very close to the real solution and compare to the other similar works, the running time of our algorithm is better than their algorithm. The analysis of time complexity of algorithm is also presented. Also, we consider visibility testing problem, where the goal is to test whether p and a given triangle of train are visible or not. We propose an algorithm for this problem... 

The compute-and-forward (CMF) method has shown a great promise as an innovative approach to exploit interference towards achieving higher network throughput. The CMF was primarily introduced by means of information theory tools. Although there have been some recent works discussing different aspects of efficient and practical implementation of CMF, there are still some issues that are not covered. In this study, the authors first introduce a method to decrease the implementation complexity of the CMF method. They then evaluate the exact outage probability of the authors proposed simplified CMF scheme, and hereby provide an upper bound on the outage probability of the optimum CMF in all... 

This letter presents a complex network model for the BitTorrent; the most popular peer-to-peer network. Three important topological characteristics; (i) degree distribution, (ii) clustering coefficient and (iii) average path length of this network are analytically modeled. The analytical computations are confirmed by simulations. Moreover, the accuracy of the proposed model was confirmed by exploiting a BitTorrent simulator