Loading...
Search for: complexation
0.01 seconds

    A study of structural, magnetic and various dielectric parameters of Ca-Substituted W-Type hexaferrites for applications at 1–6 GHz frequencies

    , Article Journal of Electronic Materials ; Volume 48, Issue 11 , 2019 , Pages 7149-7161 ; 03615235 (ISSN) ur Rehman, A ; Shaukat, S. F ; Akhtar, M. N ; Ahmad, M ; Sharif University of Technology
    Springer New York LLC  2019
    Abstract
    Single phase Ca-substituted W-type hexaferrites Sr1-xCaxZn2Fe16O27(x = 0.00(0.25)1.00) have successfully been synthesized by using sol–gel self-combustion at 1300°C. These hexaferrites are investigated by x-ray difrractometry (XRD), scanning electron microscopy, energy dispersive x-ray spectroscopy, Fourier transform infrared spectroscopy, vibrating sample magnetometry, and vector network analysis. XRD analysis confirms the formation of a single W-type hexaferrites phase. The DC electrical resistivity increases with incrementing Ca contents. The morphology of all the hexaferrites shows hexagonal platelet-like structure. The prepared ferrites depict soft magnetic nature with high saturation... 

    Synthesis, characterization and catalytic activity of supported vanadium Schiff base complex as a magnetically recoverable nanocatalyst in epoxidation of alkenes and oxidation of sulfides

    , Article Journal of Organometallic Chemistry ; Volume 897 , 2019 , Pages 200-206 ; 0022328X (ISSN) Bagherzadeh, M ; Bahjati, M ; Mortazavi Manesh, A ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    A new magnetically separable nanocatalyst was successfully synthesized by immobilizing of vanadyl acetylacetonate complex, [VO(acac)2], onto silica coated magnetite nanoparticles previously functionalized with 3-aminopropyltriethoxysilane (3-APTES) and reacted by 5-bromosalicylaldehyde to form Schiff base moiety. The obtained nanocatalyst was characterized by elemental analysis (CHN), FT-IR spectroscopy, Powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), inductively coupled plasma optical emission spectrometry (ICP-OES) and thermogravimetric analysis (TGA). Eventually, the resulting nanoparticles were used as catalyst for epoxidation of alkenes and... 

    Enhanced stabilization diagram for automated modal parameter identification based on power spectral density transmissibility functions

    , Article Structural Control and Health Monitoring ; Volume 26, Issue 7 , 2019 ; 15452255 (ISSN) Afshar, M ; Khodaygan, S ; Sharif University of Technology
    John Wiley and Sons Ltd  2019
    Abstract
    Operational modal analysis based on power spectral density transmissibility (PSDT) functions is a useful tool to identify the modal parameters with low sensitivity to excitations. For pole extraction from the PSDT function, a proper parametric identification method such as the polyreference least squares complex frequency-domain method or poly-Max method can be used. Then, the poles are selected from a stabilization diagram (SD) with overestimating the system model order. Therefore, spurious modes can be identified that must be distinguished and removed from the system poles. To reach this aim, many techniques have been proposed and applied. In this paper, a new algorithm is proposed to... 

    Pt-M (M = Au and Tl) Dative Bonds Using Bis(cyclometalated)platinum(II) Complexes

    , Article Organometallics ; Volume 38, Issue 8 , 2019 , Pages 1709-1720 ; 02767333 (ISSN) Rajabi, S ; Jamali, S ; Naseri, S ; Jamjah, A ; Kia, R ; Samouei, H ; Mastrorilli, P ; Shahsavari, H. R ; Raithby, P. R ; Sharif University of Technology
    American Chemical Society  2019
    Abstract
    Symmetrical and unsymmetrical biscyclometalated platinum(II) complexes [Pt(ptpy)2], 1, and [Pt(ptpy)(bppy)], 2, in which ptpy = deprotonated 2-(p-tolyl)pyridine and bppy = deprotonated 2-(3-bromophenyl)pyridine, have been prepared from the reaction between tris(pentafluorophenyl)borane, B(C6F5)3 and 1 equiv of monocyclometalated complexes [PtMe(ptpy)(ptpyH)], B, and [PtMe(ptpy)(bppyH)], C, respectively. The solid-state structures of 1 and 2 have been determined by X-ray crystallography. The reaction of 1 with 1 equiv of TlPF6 or [Au(PPh3)]OTF resulted in the production of heteronuclear complexes [Pt(ptpy)2Tl]PF6, 3 and {Pt(ptpy)2[Au(PPh3)]}OTF, 4, respectively. X-ray diffraction data showed... 

    Complex modal analysis and coupled electromechanical simulation of energy harvesting piezoelectric laminated beams

    , Article Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science ; Volume 233, Issue 7 , 2019 , Pages 2526-2537 ; 09544062 (ISSN) Pasharavesh, A ; Ahmadian, M. T ; Zohoor, H ; Sharif University of Technology
    SAGE Publications Ltd  2019
    Abstract
    In this paper, coupled electromechanical behavior of a vibrational energy harvesting system composed of a unimorph piezoelectric laminated beam with a large attached tip mass is investigated. To achieve this goal, first the electromechanically coupled partial differential equations governing the lateral displacement and output voltage of the harvester are extracted through exploiting the Hamilton’s principle. Considering vibration damping due to mechanical to electrical energy conversion, a complex modal analysis is performed to extract the complex eigenfrequencies and eigenfunctions of the system. Furthermore, an exact analytical solution is presented for the system response to the harmonic... 

    Finding an optimal core on a tree network with M/G/c/c state-dependent queues

    , Article Mathematical Methods of Operations Research ; Volume 89, Issue 1 , 2019 , Pages 115-142 ; 14322994 (ISSN) Moshtagh, M ; Fathali, J ; Smith, J. M. G ; Mahdavi Amiri, N ; Sharif University of Technology
    Springer Verlag  2019
    Abstract
    We consider the stochastic queue core problem on a tree network. Our aim is to find an optimal path on a tree network subject to the average travel time of particles moving along the tree for service given by a server traversing along the optimal path. We assume that particles originating at a node on a tree network request their demands for service randomly and the server is modeled first by an M/M/1 and then by an M/G/1 queue using the FIFO discipline. We consider that all paths along which the particles travel are modeled with an M/G/c/c state-dependent queue with the particles being independent of each other having demands according to the Poisson distribution. Two algorithms are... 

    Seismic analysis of reservoir-gravity dam-massed layered foundation system due to vertically propagating earthquake

    , Article Soil Dynamics and Earthquake Engineering ; Volume 116 , 2019 , Pages 174-184 ; 02677261 (ISSN) Sotoudeh, P ; Ghaemian, M ; Mohammadnezhad, H ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    Seismic analysis of complex structures such as concrete dams has been the subject of numerous studies. One of the challenges in seismic analysis of such systems is proper modelling of massed foundation. Since concrete dams’ foundations are usually layered, this makes the homogenous half-space assumption relatively unrealistic. In this paper, the effects of massed layered foundation on seismic response of concrete gravity dams in dam-reservoir-foundation systems are investigated. Seismic finite element analysis of the system carried out using domain reduction method. This approach is compared with another available method named, free-field column. First set of analysis considers the effect of... 

    Different operational alternatives of aquifer thermal energy storage system for cooling and heating of a residential complex under various climatic conditions in Iran

    , Article Scientia Iranica ; Volume 26, Issue 3B , 2019 , Pages 1281-1292 ; 10263098 (ISSN) Ghaebi, H ; Bahadori, M. N ; Saidi, M. H ; Sharif University of Technology
    Sharif University of Technology  2019
    Abstract
    In this research, a confined aquifer with low groundwater flow was considered to meet the cooling and heating requirements of residential complexes. The complexes were located in the cities of Ahvaz, Ardabil, Bandar Abbas, Esfahan, Kerman, Rasht, Tehran, and Zahedan. The complex in Ardabil mostly required heating, the ones in Ahvaz and Bandar Abbas mostly required cooling, and the complexes in other cities required both heating and cooling. Four different alternatives of Aquifer Thermal Energy Storage (ATES) were analyzed in this study. These alternatives consisted of using ATES: 1) alone for cooling, 2) coupled with a conventional refrigeration system or a chiller for cooling, 3) by... 

    Seismic analysis of reservoir-gravity dam-massed layered foundation system due to vertically propagating earthquake

    , Article Soil Dynamics and Earthquake Engineering ; Volume 116 , 2019 , Pages 174-184 ; 02677261 (ISSN) Sotoudeh, P ; Ghaemian, M ; Mohammadnezhad, H ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    Seismic analysis of complex structures such as concrete dams has been the subject of numerous studies. One of the challenges in seismic analysis of such systems is proper modelling of massed foundation. Since concrete dams’ foundations are usually layered, this makes the homogenous half-space assumption relatively unrealistic. In this paper, the effects of massed layered foundation on seismic response of concrete gravity dams in dam-reservoir-foundation systems are investigated. Seismic finite element analysis of the system carried out using domain reduction method. This approach is compared with another available method named, free-field column. First set of analysis considers the effect of... 

    Different operational alternatives of aquifer thermal energy storage system for cooling and heating of a residential complex under various climatic conditions in Iran

    , Article Scientia Iranica ; Volume 26, Issue 3B , 2019 , Pages 1281-1292 ; 10263098 (ISSN) Ghaebi, H ; Bahadori, M. N ; Saidi, M. H ; Sharif University of Technology
    Sharif University of Technology  2019
    Abstract
    In this research, a confined aquifer with low groundwater flow was considered to meet the cooling and heating requirements of residential complexes. The complexes were located in the cities of Ahvaz, Ardabil, Bandar Abbas, Esfahan, Kerman, Rasht, Tehran, and Zahedan. The complex in Ardabil mostly required heating, the ones in Ahvaz and Bandar Abbas mostly required cooling, and the complexes in other cities required both heating and cooling. Four different alternatives of Aquifer Thermal Energy Storage (ATES) were analyzed in this study. These alternatives consisted of using ATES: 1) alone for cooling, 2) coupled with a conventional refrigeration system or a chiller for cooling, 3) by... 

    The amount and temporal structure of center of pressure fluctuations during quiet standing in patients with chronic low back pain

    , Article Motor Control ; Volume 24, Issue 1 , 2020 , Pages 91-112 Azadinia, F ; Ebrahimi Takamjani, I ; Kamyab, M ; Asgari, M ; Parnianpour, M ; Sharif University of Technology
    Human Kinetics Publishers Inc  2020
    Abstract
    The characteristics of postural sway were assessed in quiet standing under three different postural task conditions in 14 patients with nonspecific chronic low back pain and 12 healthy subjects using linear and nonlinear center of pressure parameters. The linear parameters consisted of area, the mean total velocity, sway amplitude, the SD of velocity, and the phase plane portrait. The nonlinear parameters included the Lyapunov exponent, sample entropy, and the correlation dimension. The results showed that the amount of postural sway was higher in the patients with low back pain compared with the healthy subjects. Assessing the nonlinear parameters of the center of pressure showed a lower... 

    A joint encryption, channel coding and modulation scheme using QC-LDPC lattice-codes

    , Article IEEE Transactions on Communications ; Volume 68, Issue 8 , 2020 , Pages 4673-4693 Bagheri, K ; Eghlidos, T ; Sadeghi, M. R ; Panario, D ; Khodaiemehr, H ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2020
    Abstract
    We propose a new nonlinear Rao-Nam like symmetric key encryption scheme. In our design, we employ a specific type of coded modulation schemes namely quasi-cyclic low-density parity-check (QC-LDPC) lattice-codes which have low-complexity encoding and decoding algorithms. Due to the application of coded modulation schemes in our design, the proposed scheme performs encryption, encoding and modulation simultaneously. Therefore, we regard the proposed scheme as a joint cryptosystem. The proposed joint cryptosystem withstands all variants of chosen plaintext attacks applied on Rao-Nam like cryptosystems due to its nonlinearity. Moreover, some conditions implying the uniformity of the ciphertexts... 

    Characterization and calcination behavior of a low-grade manganese ore

    , Article Materials Today Communications ; Volume 25 , 2020 Cheraghi, A ; Becker, H ; Eftekhari, H ; Yoozbashizadeh, H ; Safarian, J ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Characterization and calcination behavior of a low-grade manganese ore, as a part of Mn ferroalloys production, was studied by XRF, ex-situ XRD, in-situ XRD, and SEM-EDS techniques. Calcination experiments were carried out at and up to 900 °C (1173 K) in air and argon atmospheres. The samples were in particles and powder forms. The results indicated that both quartz and calcite phases in the ore exhibit a bimodal spatial distribution; as relatively large regions and finely distributed in the Mn- and Fe-containing phases. By Rietveld analysis of the in-situ XRD data, the reactions occurring upon heating during the calcination process were deduced. Thermal decomposition and reactive diffusion... 

    Lightweight and DPA-resistant post-quantum cryptoprocessor based on binary ring-LWE

    , Article 20th International Symposium on Computer Architecture and Digital Systems, CADS 2020, 19 August 2020 through 20 August 2020 ; 2020 Ebrahimi, S ; Bayat Sarmadi, S ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2020
    Abstract
    With the exponential growth in the internet of things (IoT) applications such as smart city and e-health, more embedded devices and smart nodes are connected to the network. In order to provide security for such resource-constrained devices, different cryptographic schemes such as public key encryption (PKE) are required. However, considering the high complexity and vulnerability of classic PKE schemes against quantum attacks, it is necessary to consider other possible options. Recently, lattice-based cryptography and especially learning with errors (LWE) have gained high attention due to resistance against quantum attacks and relatively low-complexity operations. During the past decade,... 

    Lightweight and fault-resilient implementations of binary ring-lwe for iot devices

    , Article IEEE Internet of Things Journal ; Volume 7, Issue 8 , 2020 , Pages 6970-6978 Ebrahimi, S ; Bayat Sarmadi, S ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2020
    Abstract
    While the Internet of Things (IoT) shapes the future of the Internet, communications among nodes must be secured by employing cryptographic schemes such as public-key encryption (PKE). However, classic PKE schemes, such as RSA and elliptic curve cryptography (ECC) suffer from both high complexity and vulnerability to quantum attacks. During the past decade, post-quantum schemes based on the learning with errors (LWEs) problem have gained high attention due to the lower complexity among PKE schemes. In addition to resistance against theoretical (quantum and classic) attacks, every practical implementation of any cryptosystem must also be evaluated against different side-channel attacks such... 

    Optimal design for solar greenhouses based on climate conditions

    , Article Renewable Energy ; Volume 145 , 2020 , Pages 1255-1265 Esmaeli, H ; Roshandel, R ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Greenhouses require energy in order to provide a proper environment for crop production. Utilizing solar energy in solar greenhouses is a sustainable solution to face this problem. In this study, a solar greenhouse concept is considered, and a dynamic thermal model is developed to predict the inside air temperature. The model is integrated into an optimization procedure to find the optimal greenhouse design that has the best thermal performance by adjusting its structural parameters. This optimization procedure provides a tool to find the optimal solar greenhouse design for each climate condition and predict its performance. For instance, for the case study of Tehran (Iran), the optimal... 

    System identification and robust attitude control of an unmanned helicopter using novel low-cost flight control system

    , Article Proceedings of the Institution of Mechanical Engineers. Part I: Journal of Systems and Control Engineering ; Volume 234, Issue 5 , 27 August , 2020 , Pages 634-645 Khalesi, M. H ; Salarieh, H ; Saadat Foumani, M ; Sharif University of Technology
    SAGE Publications Ltd  2020
    Abstract
    In recent years, unmanned aerial systems have attracted great attention due to the electronic systems technology advancements. Among these vehicles, unmanned helicopters are more important because of their special abilities and superior performance. The complex nonlinear dynamic system (caused by main rotor flapping dynamics coupled with the rigid body rotational motion) and considerable effects of ambient disturbance make their utilization hard in actual missions. Attitude dynamics have the main role in helicopter stabilization, so implementing proper control system for attitude is an important issue for unmanned helicopter hovering and trajectory tracking performance. Besides this,... 

    A novel magnetic polyacrylonotrile-based palladium core−shell complex: a highly efficient catalyst for synthesis of Diaryl ethers

    , Article Journal of Organometallic Chemistry ; Volume 916 , 14 June , 2020 Matloubi Moghaddam, F ; Jarahiyan, A ; Eslami, M ; Pourjavadi, A ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    The present article describes the synthesis of a new magnetic polyacrylonitrile-based Pd catalyst involving polyacrylonitrile modified via 2-aminopyridine as an efficient support to immobilize Pd nanoparticles. The simple reusability, easy separation and high stability of this Pd complex make it an excellent candidate to generate a C–O bond via Ph-X activation which is a really important subject in achieving biologically active compounds. It is worth to note access to good and high yields as well as broad substrate scope have resulted from superior reactivity of this catalyst complex. Furthermore, the structure of the magnetic polyacrylonitrile-based heterogeneous catalyst was characterized... 

    Synthesis and X-ray crystal structure of a Molybdenum(VI) Schiff base complex: Design of a new catalytic system for sustainable olefin epoxidation

    , Article Inorganica Chimica Acta ; Volume 511 , October , 2020 Mahmoudi, H ; Bagherzadeh, M ; Ataie, S ; Kia, R ; Heydar Moravej, S ; Zare, M ; Raithby, P. R ; Ferlin, F ; Vaccaro, L ; Sharif University of Technology
    Elsevier S. A  2020
    Abstract
    A targeted new dioxo molybdenum(VI) ONO Schiff base complex was prepared for catalyzing epoxidation of olefins in water. This complex was characterized by FT-IR, NMR, UV–Vis, and X-ray crystallography techniques. DFT calculations are additionally performed to find ground and transition states for finding electronic structure and UV–Vis assignment. Afterward, a new protocol was defined for sustainable catalytic epoxidation of olefin in water using this complex as a green catalyst, and also remarkable results are obtained, such as turn over number up to 1400. © 2020 Elsevier B.V  

    OptCAM: An ultra-fast all-optical architecture for DNA variant discovery

    , Article Journal of Biophotonics ; Volume 13, Issue 1 , August , 2020 Maleki, E ; Koohi, S ; Kavehvash, Z ; Mashaghi, A ; Sharif University of Technology
    Wiley-VCH Verlag  2020
    Abstract
    Nowadays, the accelerated expansion of genetic data challenges speed of current DNA sequence alignment algorithms due to their electrical implementations. Essential needs of an efficient and accurate method for DNA variant discovery demand new approaches for parallel processing in real time. Fortunately, photonics, as an emerging technology in data computing, proposes optical correlation as a fast similarity measurement algorithm; while complexity of existing local alignment algorithms severely limits their applicability. Hence, in this paper, employing optical correlation for global alignment, we present an optical processing approach for local DNA sequence alignment to benefit both...