Sharif Digital Repository

TiO 2 -rGO nanocomposite coatings were obtained by electrophoretic deposition (EPD) technique of TiO 2 nanoparticles and graphene oxide (GO) on stainless steel substrate. First, GO particles were synthesized using a modified Hummers' method. GO was reduced electrochemically to form a coating in the presence of nano-sized TiO 2 particles. The influences of different parameters such as GO concentration, coupling co-electro-deposition parameters (electrophoretic duration and voltage) on thickness, surface morphology and, corrosion behavior of the as-synthesized TiO 2 -rGO nanocomposite coatings were systematically surveyed. The morphology and microstructure were investigated by field emission... 

In this study, the different parts of carthamus tinctorius plant, including petal (SPE), leaf (SLE), and shoot (SSE), have been extracted. Adsorption of the extracts on mild steel in 3.5 wt. % NaCl solution was evaluated employing electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, and electrochemical noise measurements (EN). The field-emission scanning electron microscopy (FE-SEM) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) were employed to appraise the morphology of the samples surface subjected to the test solutions. According to the EIS results, the maximum adsorption efficiency belonged to the solution containing 1 g L−1 of... 

A short lifespan and increased consumption patterns make e-waste the world's fastest-growing waste stream. Computers are one of the most significant parts of e-waste. Recycling of e-waste has been introduced as the main solution to deal with environmental problems and to save natural mines. This research aims to investigate the bioleaching of Cu, Ni, and Al from computer printed circuit boards (CPCBs) using Penicillium simplicissimum. The adaptation phase began at 1 g/l CPCBs powder with 107 spores and final pulp density was reached at 30 g/l. The most effective parameters including pulp density, initial pH, and the sucrose concentration were optimized to achieve maximum simultaneous... 

This work focused on the design of new pH-responsive nanoparticles for controlled delivery of anticancer drug doxorubicin (Dox). Nanoparticles of poly(methacrylic acid)-polysorbate 80-grafted starch (PMAA-PS 80-g-St) were synthesized by using a one-pot method that enabled simultaneous grafting of PMAA and PS 80 onto starch and nanoparticle formation in an aqueous medium. The particles were characterized by FTIR, 1H NMR, TEM, DLS, and potentiometric titration. Dox loading and in vitro release from the nanoparticles were investigated. The FTIR and 1H NMR confirmed the chemical composition of the graft terpolymer. The nanoparticles were relatively spherical with narrow size distribution and... 

CeO 2-TiO 2 nanoparticles were prepared by the sol-gel process using 2-hydroxylethylammonium formate as room-temperature ionic liquid and calcined at different temperatures (500-700°C). CeO 2-TiO 2-graphene nanocomposites were prepared by hydrothermal reaction of graphene oxide with CeO 2-TiO 2 nanoparticles in aqueous solution of ethanol. The photocatalysts were characterized by X-ray diffraction, BET surface area, diffuse reflectance spectroscopy, scanning electron microscopy, and Fourier transformed infrared techniques. The results demonstrate that the room-temperature ionic liquid inhibits the anatase-rutile phase transformation. This effect was promoted by addition of CeO 2 to TiO 2.... 

In this study, a new facile and cost effective method is used to modify polysulfone membrane surface in order to improve the hydrophilicity, antifouling, and blood compatibility. This modification was performed by adding two functional monomers on the dialysis membrane. Polysulfone (PSF) membranes containing polyvinylpyrrolidone were prepared via phase inversion technique. In the next step, free radical polymerization combined with surface polymerization was used to introduce acrylic acid (AA) and 2-hydroxyethyl methacrylate (HEMA) onto the polysulfone membrane surface via circulation of initiator and monomer solutions across the membrane surface, respectively. Various monomer concentrations... 

The effects of different parameters including membrane type (regenerated cellulose and polysulphone), transmembrane pressure (TMP), the content of oil in the feed, the flow velocity of the feed and pH on the ultrafiltration of an emulsion of kerosene in water were studied. It was found that the important factors affecting ultrafiltration were, in order, membrane type, pressure and oil concentration. The greatest flux at the optimum conditions here of 3 bar, an oil content of 3% (v/v) and with membrane type C30F was predicted as 108 L/(m2 h) that was within the range of the confidence limit of the measured value of 106 L/(m2 h). The normalised FTIR results of the virgin cellulosic membranes...