Sharif Digital Repository

In this work we have studied conformation of ranitidine by dynamic nuclear magnetic resonance spectroscopy (DNMR) in four different solvents: chloroform, acetone, dimethylsulfoxide, and deuteriumoxide. Ranitidine has three tatumeric forms of enamine, nitoic acid, and imine, but its stable structure is enamine. Temperature dependent 1HNMR spectra of ranitidine which reportet at 500MHz were consistent with the following free activation of energies ΔG# (kcal mol-1): chloroform = 16.2; acetone = 15.4; dimethylsulfoxide = 15.1. The experimental results were confirmed by DFT theoretical calculations at the B3LYP/6-311++G (d, p) level of theory. It was also proved that ranitidine has the form of... 

Polyvinylalcohol/magnetite nanocomposite films were fabricated via solution casting. Magnetite (Fe3O4) nanoparticles were prepared by means of co-precipitation method and modified by citric acid. The nanoparticles and nanocomposites were characterized by scanning electron microscopy (SEM), x-ray diffraction (XRD), vibrating sample magnetometer (VSM), fourier transform infrared spectroscopy (FTIR) and mechanical measurement. The results reveal that magnetite nanoparticles have a spherical shape with an average diameter of 19.7nm and are superparamagnetic at room temperature. The nanoparticles are observed to be uniformly dispersed in the polymer matrix due to a strong interaction between the... 

Oxidation reactions in organic chemistry were applied as one of the most important methods to change the functional groups to desired one. Oxidation of alcohols to aldehydes or oxidative coupling of thiols to disulfids is two well-known examples of these conversions. The mention reactions are using commonly because of availability and simple synthesis of the alcohols and thiols. Recently the application of immobilized reagents in solid surfaces is increased because of environmental advantages.
In this study, The 1,4-diazabicyclo[2.2.2] octane (DABCO) tribromide was immobilized on two different supports by employing 3-chloropropyltrimethoxy silane: Silica Support (SS), and Nanoparticles... 

Magnetic Resonance Imaging (MRI) is a non-invasive imaging modality which can represents the structure, metabolism and the function of inner tissues and organs. Unlike other imaging modalities MRI does not use ionizing radiation.Reducing the imaging time will result in cost reduction and patient comfort. Therefore since the invention of MRI, increasing the speed of imaging has drawn a lot of attention. This was mainly done by improving and upgrading the data collecting hardware of the imaging module.With the advances in technology, a point has been nearly reached, that due to the physical and physiological constraints, such as nerve stimulation, quickening the hardware is impractical.... 

Breast cancer is considered as the most common type of cancer in women worldwide and mammography is currently utilized as the principal method for screening the breast cancer. Breast Magnetic resonance imaging (MRI) can be used as a complementary imaging technique besides mammography. MRI technique involves scanning a patient before and repeatedly after the injection of the contrast agent (DCE-BMRI). This examination often takes 7-10 minutes and any movement of the patient’s breasts due to breath, heartbeat or deliberate movement, made in this relatively long acquisition period, leads to a distortion in images called motion artifact. This problem makes the quantitative analysis of the images... 

In this work, magnetite (Fe3O4) nanoparticles with an average siz21.9nm
modified by oleic acid were prepared by the coprecipitation method, which can linked well with organic molecules because of the presence of C-O-C on their surface. Then magnetic poly(lactic acid) (PLA)/ poly(ethylene glycol) (PEG) microspheres were prepared by the single emulsion solvent evaporation technology. The incorporation of magnetit nanoparticles and dox into the PLA matrix was confirmed by FTIR. XRD and VSM confirmed the existence of MNPs in the microspheres which maintained superparamagnetic behavior with a saturation magnetization of 50.69 emu/g.Electron microscopy SEM showed that the magnetic microspheres... 

Image registration is defined as matching two or more than two images which are taken from a same scene in different times, from various views and using different sensors. By matching, we mean finding the transformation function between the images. Image registration
has many application in medical domains such as analyzing changes in body limbs, supervision of the tumors growth, and robotic surgery. The challenges of image registration are unavailability of the transformation function, existence of the outliers in the images, changes in the images intensity, changes in the image geometry, noise, etc. Image registration consists of four steps: (i) feature extraction, (ii) choosing a... 

In this study the effect of nanoparticles on the mass transfer of dispersed phase in the liquid-liquid extraction systems, containing toluene with acetic acid as dispersed phase and saturated water of toluene as continues phase was investigated. For the ease of dispersion of nanoparticles in nonpolar organic dispersed phase, with the use of a novel method, hydrophobic tiania nanoparticles were synthesized and during producing with the sole-gel method were modified by adding Tetraethyl Ortho titanate as modifying agent, also the smallest hydrophobic nanoparticles of magnetite were synthesized by co-precipitating method and then, under optimum thermal condition were coated by adding Oleic... 

Circular polarization (CP) is one of the common polarization types used in wireless systems for frequency identification (RFID), global positioning (GPS) and wireless local area networks (WLAN), since it can provide greater flexibility in orientation angle between transmitter and receiver, and better mobility and weather penetration than the linearly polarized antennas. Magnetic permeability in ferrites can be tuned by external magnetic field ; So ferrites can be good candidates for new reconfigurable CP antenna technology. In this project, we will consider circularly polarized slot antenna with a wide axial ratio beamwidth that consists of a normally magnetized ferrite substrate mounted... 

Magnetic resonance imaging is one of non-invasive methods to measure the hemodynamic and morphologic parameters of tissues, especially brain tissues. Hemodynamic parameters monitoring in brain tissue is of significant importance in many majors such as detection of tumor occurrence, brain abnormalities, and track of treatment procedures. Blood is a suspension, comprised of plasma, red blood cells, white blood cells, platelet, etc. Plasma is a Newtonian fluid which is composed of proteins and has a constant viscosity in body temperature. Rheological properties of blood are highly dependent on mechanical and rheological properties of its cells and this dependence is multiplied in narrow vessels... 

In wireless communication systems increasing the gain of antennas is seminal to increase in coverage and data transmission rate, and reducing the possible errors. One of the main factors for improving the antenna gain is matching the polarizations of the transmitter and the receiver antennas. Towards this end, both the transmitter and the receiver antennas should have the same axial ratio, specific direction and polarizations. As far as the flexibility of the direction angle between the transmitter and the receiver is concerned, the so-called circular polarization is preferred do the linear polarization. The antennas with circular polarizations are prominently utilized in satellites,... 

There are many industries in the world that produce colorized wastewater. Because of the complex structure and good solubility of dyes, such industries have problem treating this wastewaters. On the other hand, because of the toxicity of these materials for water living, dye removal from discharged wastewater of these industries is very important. In recent years, researchers have become interested in the synthesis of dye Nano adsorbents and they have published many works on this subject. The important parameters in the synthesis of such adsorbent include; non-toxicity, high adsorption capacity and easy separation. In this project, cellulose was extracted from bagasse and then CMC was... 

Age-related macular degeneration (AMD) is the most common cause of vision loss in those aged over 50. There are two main types of AMD, Wet and Dry form. Wet AMD is more severe though more treatable. There are three conventional treatments for AMD including laser therapy, surgery and intravitreal injection of anti-VEGF into the eye. Delivery of drugs to the posterior segment of the eye is still challenging and several implants and devices are currently under investigation for their ability to stimulate the retina, producing visual percepts. The application of intravitreal bevacizumab (Avastin) has expanded tremendously from the time of its introduction into ophthalmic care since 3 years ago.... 

Elastic joints in 2-mass drive systems, because of their limited stiffness, can decrease the performance of the control system and lead to motor and load speed oscillation. Shaft torque ignoring can also stress both mechanical and electrical drive components. Because of low degree of freedom, conventional controllers, such as the PI controllers, cannot improve the performance of the system and keep the system stable at the same time. In this thesis, the dynamic response and stability of the 2-mass systems is improved using state controller. State estimation of 2-mass system is required for state space controller . In the thesis, different state observer is analyzed and compared with each... 

Magnetic Resonance Imaging is one of the most advanced medical imaging procedure that noninvasively played in most applications. However, this imaging method is a good resolution, but not in the conventional high speed imaging method, in fact, the main problem is slow. In recent years many studies have been done to accelerate MRI that compressed sensing can be mentioned among them. Such methods, however, have had very good results but MRI systems are very complex. This project investigates the reconstruction of MR images using data from partial non-Cartesian samples aimed at reducing sampling time and also speed up the process of reconstruction of MR images have been studied. In this regard,... 

Porosity and high surface area is a profound concept for creating advance materials. Nanofibers are an important class of nanomaterials with high surface to volume ratio as a result of long lengths and nano-to-micro-scale diameters. Electrospinning is a simple method for producing nanofibers from different polymers and composites and prepare highly efficient sorbents. Polymeric nanocomposites are claimed to exhibit markedly improved mechanical, magnetic, thermal and electrical properties. Magnetic iron oxide nanoparticles have gained great attentions due to their low toxicity, stability and biocompatibility and have been extensively used to induce magnetic property to the desired sorbents.... 

Salicylaldehyde-amino acid Schiff base complexes are used as non-enzymatic models for the metal-pyridoxal (Vitamin B6) amino acid Schiff base systems which are key intermediates in many metabolic reactions of amino acids catalyzed by enzymes which require pyridoxal as a cofactor (transamination, decarboxylation, α and β elimination, racemization, etc.). In addition, complexes of amino acid Schiff bases are considered to constitute new kinds of potential anticancer, antitumor, antiradical and antibacterial reagents. On the other hand nuclear magnetic resonance imaging (MRI), has become a powerful tool for clinical diagnostics thanks to the development of a new class of pharmaceuticals... 

Direct Torque Control (DTC) is one of the vector methods to control Permanent Magnet Synchronous Machines (PMSM). In order to achieve an appropriate control in vector control methods, an accurate estimation of flux is indispensable. Flux estimation should be fulfilled in a wide speed range without considerable dependence on motor parameters. Prevalent flux estimation methods are based on integration of stator voltage which is not feasible in low speed, or performed based on assumption of decoupled equations on d and q axis which is not precise for applications with fast dynamic. Different flux estimation methods are investigated in this thesis with the aim of improving the flux estimation in... 

In the framework of the Standard Model of Particle Physics, Quantum Chromodynamics (QCD) is known to be the only theory which describes the strong nuclear force. Because of the property of asymptotic freedom, perturbative methods fail to describe QCD at low energies. Here, mesons and baryons build the main degrees of freedom of QCD. To describe the dynamics of mesons at low energies, nonperturbative methods are used. The Nambu–Jona-Lasinio (NJL) model is one of the most important effective models, which is used to study the nonperturbative phenomena of QCD at low energies. The Lagrangian density of this model includes a local four-fermion term,which descibes the interaction between the... 

In this thesis a novel non-rotating space tethered configuration is introduced which its relative positions are controlled using electromagnetic forces. The attitude dynamics is controlled by three reaction wheels in the body axes. The nonlinear coupled orbital dynamics of a dumbbell tethered satellite formation flight are derived through a constrained Lagrangian approach. These equations are presented in the leader satellite orbital frame. The advantage of using equations in the Cartesian coordinate system over presenting the equations of satellite formation plane angles is the appearance of gravity gradient and Earth’s magnetic field effects. The tether is assumed to be mass-less and...