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    Effect of Electromagnetic Field on Membrane Fouling in Filtration Process

    , M.Sc. Thesis Sharif University of Technology Rouina, Mohammad (Author) ; Kariminia, Hamid Reza (Supervisor) ; Mousavi, Abbas (Supervisor)
    Abstract
    Current research studies the effect of electromagnetic field on reducing precipitation on membrane surface in reverse osmosis. Reverse osmosis is one of the most widely applied methods for water desalinization. Despite its advantages over other desalinization techniques, suffers from shortcomings such as blockage of membrane surface. Use of magnetic fields for reducing precipitation in process equipment, the so-called magnetic treatment, has been studied and practiced for decades. This research intends to study the effect of electromagnetic field on water and its mineral content, and the possibility of its application as a method for reducing precipitation and blockage in reverse osmosis... 

    Treatment of Blow-down water to Reuse by Membrane Processes, Nanofiltration and Reverse Osmosis

    , M.Sc. Thesis Sharif University of Technology Davood Abadi Farahani, Mohammad Hossein (Author) ; Borghei, Mehdi (Supervisor)
    Abstract
    Petrochemicals, refineries and power plants are among the biggest water-consuming industries. Of all systems in mentioned complex, most water is consumed in the cooling tower system, of which the feed water of the cooling tower accounts for the largest portion of water demand. Drainage loss (blowdown) which constitutes the biggest portion of the feed water losses, varies greatly with changes in source water quality and cooling water treatment. Scarcity of water, large quantities of cooling tower blowdown water and increasing of water price lead to activities for blowdown water treatment to reuse. In this project two pre-treatment methods and two final membrane treatment methods were... 

    Biofouling Reduction in Reverse Osmosis Membrane for the Purification Brackish Water

    , M.Sc. Thesis Sharif University of Technology Niknamfar, Rasool (Author) ; Soltanieh, Mohammad (Supervisor) ; Mousavi, Abbas (Supervisor)
    Abstract
    In this project, modification of reverse osmosis membrane was investigated in order to reduce the biofouling in treatment of brackish water. Furthermore, the technique which is used to attain the favorable results is graft polymerization to modify the membrane’s surface with grafting acrylic acid as hydrophilic monomer onto polyamide exploited as last layer in reverse osmosis membrane. This technique is a free radical grafting, andfree radicals which are needed for grafting are provided by the redox system potassium persulfate-sodium metabisulfite which was used as initiator. To figure out the best concentration of acrylic acid, initiator and process time in order to achieve a new membrane... 

    Enhance the Chlorine Resistance of Reverse Osmosis Membrane

    , M.Sc. Thesis Sharif University of Technology Kehtari Anvar, Mahmood (Author) ; Mousavi, Abbas (Supervisor) ; Abdekhodaei, Mohammad Jafar (Supervisor)
    Abstract
    Reverse osmosis membrane one of the common methods used for water desalination, today membrane, thin film composite(TFC) include three layers, top the these layers named selection layer, this poly amid layer contacted with feed water, sensitivity to chlorine in polyamide layer lead to high membrane chlorine sensitive. Difference methods used for enhance the chlorine resistance in polyamide membrane that categorized in three general categories, covering and protection of sensitive areas method has best results in comparison to other methods. In this research protection method choose and used, material that used, sanitized by result from surface analysis of commercial membrane manufactured in... 

    Constructing Reverse Osmosis Membrane of High Flux & Rejection for Salty Water by Supercritical System

    , M.Sc. Thesis Sharif University of Technology Jafarzadeh, Sina (Author) ; Goudarz Nia, Iraj (Supervisor) ; Mousavi, Seyed Abbas (Co-Advisor)
    Abstract
    This research aims to construct a membrane using supercritical system which can be used in the process of brackish water filtration.
    For this purpose solutions of polysulfone with desired concentrations were prepared and set to be stretched on glass or nonwoven polyester with adjustable thickness. Then the film of solution was transferred into supercritical cell. Carbon dioxide was used as anti-solvent and it causes super saturation in solution.
    In order to investigate the effect of operating parameters on membrane structure, pore size and porosity were considered as a symbol of membrane structure. These parameters include cell pressure and polysulfone concentration.
    Generally,... 

    Forward Osmosis Membrane Preperation for Seawater Desalination

    , M.Sc. Thesis Sharif University of Technology Haji Ghahreman Zadeh, Parisa (Author) ; Soltanieh, Mohammad (Supervisor) ; Mousavi, Abbas (Co-Advisor)
    Abstract
    One of the encouraging technologies for resolving the lack of clean water in the world is forward osmosis process (FO). Reaching to a optimized development of FO membranes is essential to make fo process commercially viable.
    This study’s aim is to develop a thin film composites (TFC) membrane with high FO performance (good water flux and high salt rejection) in order to seawater desalination.
    Polyacrylonitrile (PAN), a hydrophilic polymer, is a less considered polymer in fabricating support layer for TFC FO membranes .TFC membranes consist of a selective polyamide active layer formed by interfacial polymerization on top of a support layer fabricated by non-solvent induced phase... 

    Preparing an Appropriate UF Membrane from PVC to Use it as Substrate in Sea Water Desalination RO Membranes

    , M.Sc. Thesis Sharif University of Technology Sabzi Dizajeyekan, Behnam (Author) ; Bastani, Daruoosh (Supervisor) ; Musavi, Abbas (Supervisor)
    Abstract
    In this study the main goal is preparing an appropriate UltraFiltration membrane from PolyVinyl Chloride for using as substrate in producing efficient Reverse Osmosis membranes to use in sea water desalination. each membrane should have some specifications to use it as reverse osmosis membrane’s substrate. One of the most important specifications is the appropriate pore sizes. To investigate this subject pure water flux and PolyEthylene glycol rejection of prepared membranes is tested. After investigation of this parameters and proving them, RO membranes are prepared using this membranes.
    Salt rejection of Brackish water (2000ppm) and sea water (Persian gulf,32000ppm) are measured in... 

    Optimization of the Surface Properties of the Reverse Osmosis Membrane for Desalination of Seawater

    , M.Sc. Thesis Sharif University of Technology Jahangiri, Foad (Author) ; Farhadi, Fatola (Supervisor) ; Musavi, Abbas (Supervisor)
    Abstract
    Surface modification of thin-film composite (TFC) polyamide reverse osmosis membrane was carried out using CO2-laser irradiation and Dielectric barrier discharge (DBD) plasma to improve performance and antifouling properties of the prepared RO membranes. Firstly, TFC polyamide RO membranes were synthesized via interfacial polymerization of trimesoyl chloride (TMC) and m-phenylenediamine (MPD) monomers over porous polysulfone ultrafiltration support. Next, CO2-laser irradiation with 10,000-40,000 pulses and DBD plasma with 15, 30, 60 and 90 seconds duration were used for the surface modification. The surface properties were characterized by ATR-FTIR, SEM, AFM, and contact angle measurements.... 

    Synthesis of Ultra-Low Pressure Reverse Osmosis (ULPRO) Membrane

    , M.Sc. Thesis Sharif University of Technology Karimi, Hossein (Author) ; Soltanieh, Mohammad (Supervisor) ; Mousavi, Abbas (Co-Advisor)
    Abstract
    The aim of this project is to achieve a semi permeable high flux membrane with a reasonable salt rejection for the treatment of low osmotic pressure water. A thin film composite membrane consists of three polymeric layers was studied in this project. These layers were polyester support, polysulfone sub layer and polyamine selective layer. The polyester support provides the mechanical resistance against the operating pressure. The polysulfone sub layer provides the suitable area for polyamide synthesize, and the polyamide layer is the selective active layer of membrane.
    The resistance to water penetration in sub layer was reduced first and then, the pores in the polyamide layer refined by... 

    Preparation of Thin-Film Nanocomposite Membranes Based on Metal-Organic Frameworks (Mofs) and Study of their Performance in Forward Osmosis (Fo) Process

    , Ph.D. Dissertation Sharif University of Technology Bayrami, Arshad (Author) ; Bagherzadeh, Mojtaba (Supervisor)
    Abstract
    The forward osmosis (FO) process is a high potential emerging membrane process in the seawater desalination and contaminated water treatment fields. One of the main challenges facing this process is the weak separation (high reverse solute flux, low water flux, and insufficient selectivity) and antifouling performances of its membranes. Various sections of this study focus on the development of FO membranes and their performance improvement. For this purpose, thin-film composite membranes with the same combination of polyethersulfone/polyamide (PES/PA) have been used to investigate the effect of metal-organic frameworks (MOFs) introduction on their performance. The support layer in all cases... 

    Preparation of Polyethersulfone/Polyamide (PES/PA)Thin Film Composite Membranes based Modified Nanoclays for Forward Osmosis-Disalination

    , M.Sc. Thesis Sharif University of Technology Veisi, Vahab (Author) ; Bagherzadeh, Mojtaba (Supervisor)
    Abstract
    In this study, two layer nanocomposite membrane of polyethersulfone (support layer) and polyamide (active layer) were prepared for the purpose of desalination of water by forward osmosis method. In order to take more advantage of this membrane, montmorillonite nanoparticles which had been modified by graphene oxide were placed in it. To bind the nanoparticle components together, at first, montmorillonite was functionalized by (3-Aminopropyl) triethoxysilane to increase its nucleophilicity, and for graphene oxide to increase its electrophilicity, thionyl chloride was added. The two compounds were mixed and stirred for 24 hours in the presence of triethylamine base by magnetic stirrer at 30°C... 

    Investigation Methods to Optimize the Operation of the RO Plant of Hakim Farabi Agri Industrial Co

    , M.Sc. Thesis Sharif University of Technology Maryami, Fatemeh (Author) ; Hashemian, Jamaloddin (Supervisor) ; Mousavi, Reza (Co-Advisor)
    Abstract
    Membrane fouling is the main cause of permeate flux decline and loss of product quality in reverse osmosis (RO) systems, so good pretreatment of the feed solution was required to prevent membrane fouling. One of the most common applied pretreatment methods to prevent or control the scaling of different salts in feed water is to add scale inhibitors. Due to the great variety of commercial scale inhibitors RO plant operators must evaluate these chemicals before use in real plants. In this project three different types of antiscalants at concentrations of 10 ppm and one type of magnetic descaler on the RO pilot for the R.O plant feed water of agro-industrial Hakim Farabi evaluated and function... 

    Monitoring & Optimizing of the Returned Condensated Water as Boiler Make up Water at the Agro-Industry Hakim Farabi Boilers

    , M.Sc. Thesis Sharif University of Technology Askary Bozayeh, Hossein (Author) ; Alamolhoda, Ali Asghar (Supervisor) ; Pourjavadi, Ali (Co-Advisor)
    Abstract
    Vapor in agro-industry hakim farabi production electricity, Turbines force and thermal energy for Yellow and white sugar in sugar production. In the utilization to supply water for the boiler , condensate water return use Until plant be able to do its work ¬good quality of condensate water decrease cost of destruction energy in blow down and can save energy, reduce cost of chemical operation for optimum boiler water and costs associated with wastewater treatment. unclean condensate water consist of sugar and Electrical conductivity more than permissive is not suitable for use in The boiler because Increase the total dissolved solids and decreasing pH lower than the Extent permitted. The... 

    Three-dimensional simulation of urine concentrating mechanism in a functional unit of rat outer medulla. I. Model structure and base case results

    , Article Mathematical Biosciences ; Vol. 258 , 2014 , pp. 44-56 ; ISSN: 00255564 Sohrabi, S ; Saidi, M. S ; Saadatmand, M ; Banazadeh, M. H ; Firoozabadi, B ; Sharif University of Technology
    Abstract
    The urine formation and excretion system have long been of interest for mathematicians and physiologists to elucidate the obscurities within the process happens in renal tissue. In this study, a novel three-dimensional approach is utilized for modeling the urine concentrating mechanism in rat renal outer medulla which is essentially focused on demonstrating the significance of tubule's architecture revealed in anatomic studies and physiological literature. Since nephrons and vasculatures work interdependently through a highly structured arrangement in outer medulla which is dominated by vascular bundles, a detailed functional unit is proposed based on this specific configuration.... 

    Thermodynamic properties of aqueous salt containing urea solutions

    , Article Fluid Phase Equilibria ; Volume 325 , July , 2012 , Pages 71-79 ; 03783812 (ISSN) Sadeghi, M ; Held, C ; Samieenasab, A ; Ghotbi, C ; Abdekhodaie, M. J ; Taghikhani, V ; Sadowski, G ; Sharif University of Technology
    2012
    Abstract
    Urea and inorganic ions are present in some of the physiological systems, e.g. urine. Understanding the interactions in urea/salt/water is a preliminary step to shed light on more complicated behavior of multi-component physiological systems. State-of-the-art models as well as thermophysical properties can be applied to understand the interactions in these systems. In order to determine such interactions densities, mean ionic activity coefficients (MIACs), osmotic coefficients, and solubility were measured in aqueous solutions of urea and different salts. Densities were determined at temperatures 293.15, 303.15, and 313.15K for urea concentrations up to 3molal and up to 1molal for NaCl.... 

    The effect of fuel cell operational conditions on the water content distribution in the polymer electrolyte membrane

    , Article Renewable Energy ; Volume 36, Issue 12 , December , 2011 , Pages 3319-3331 ; 09601481 (ISSN) Tavakoli, B ; Roshandel, R ; Sharif University of Technology
    2011
    Abstract
    Models play an important role in fuel cell design and development. One of the critical problems to overcome in the proton exchange membrane (PEM) fuel cells is the water management. In this work a steady state, two-dimensional, isothermal model in a single PEM fuel cell using individual computational fluid dynamics code was presented. Special attention was devoted to the water transport through the membrane which is assumed to be combined effect of diffusion, electro-osmotic drag and convection. The effect of current density variation distribution on the water content (λ) in membrane/electrode assembly (MEA) was determined. In this work the membrane heat conductivity is considered as a... 

    Modeling of osmotic pressure of aqueous poly(ethylene glycol) solutions using the artificial neural network and free volume flory huggins model

    , Article Journal of Dispersion Science and Technology ; Volume 32, Issue 7 , 2011 , Pages 1054-1059 ; 01932691 (ISSN) Naeini, A. T ; Pazuki, G. R ; Vossoughi, M ; Alemzadeh, I ; Sharif University of Technology
    2011
    Abstract
    In this work, the modified Flory-Huggins coupled with the free-volume concept and the artificial neural network models were used to obtain the osmotic pressure of aqueous poly(ethylene glycol) solutions. In the artificial neural network, the osmotic pressure of aqueous poly(ethylene glycol) solutions depends on temperature, molecular weight and the mole fractions of poly(ethylene glycol) in aqueous solution. The network topology is optimized and the (3-1-1) architecture is found using optimization of an objective function with batch back propagation (BBP) method for 134 experimental data points. The results obtained from the neural network in obtaining of the osmotic pressure of aqueous... 

    Ro brine treatment and disposal methods

    , Article Desalination and Water Treatment ; Volume 35, Issue 1-3 , Aug , 2011 , Pages 39-53 ; 19443994 (ISSN) Afrasiabi, N ; Shahbazali, E ; Sharif University of Technology
    Taylor and Francis Inc  2011
    Abstract
    More than 50 percent of countries in the world will likely face water stress or water shortages by 2025, and by 2050, as much as 75 percent of the world's population could face water scarcity. Desalination technologies, particularly the reverse osmosis (RO) process, have increasingly been adopted to produce freshwater from alternative sources such as seawater and brackish water due to water scarcity. However, desalination applications have always been limited by the disposal costs of RO brine and the adverse impact of brine on the receiving environment. The scope of this paper is to identify technically and commercially RO brine disposal and treatment methods such as deep well injection,... 

    GAMS based approach for optimal design and sizing of a pressure retarded osmosis power plant in Bahmanshir river of Iran

    , Article Renewable and Sustainable Energy Reviews ; Volume 52 , 2015 , Pages 1559-1565 ; 13640321 (ISSN) Naghiloo, A ; Abbaspour, M ; Mohammadi-Ivatloo, B ; Bakhtari, K ; Sharif University of Technology
    Elsevier Ltd  2015
    Abstract
    Osmotic power generation is one of the cleaner and sustainable methods for energy generation. This paper presents a study on the optimal size and design of pressure retarded osmosis (PRO) power plant as a viable source of renewable energy in the selected site in Bahmanshir river of Iran. The optimal sizing and design problem is formulated as a Non-Linear Programming (NLP) optimization problem and solved using the standard optimization software titled generalized algebraic modeling system (GAMS). The objective function is minimizing the total cost while considering the technical and economic constraints. Optimization results show that the optimal capacity of the PRO osmotic power plant is... 

    A new flat sheet membrane bioreactor hybrid system for advanced treatment of effluent, reverse osmosis pretreatment and fouling mitigation

    , Article Bioresource Technology ; Volume 192 , 2015 , Pages 177-184 ; 09608524 (ISSN) Hosseinzadeh, M ; Bidhendi, G. N ; Torabian, A ; Mehrdadi, N ; Pourabdullah, M ; Sharif University of Technology
    Abstract
    This paper introduces a new hybrid electro membrane bioreactor (HEMBR) for reverse osmosis (RO) pretreatment and advanced treatment of effluent by simultaneously integrating electrical coagulation (EC) with a membrane bioreactor (MBR) and its performance was compared with conventional MBR. Experimental results and their statistical analysis showed removal efficiency for suspended solids (SS) of almost 100% for both reactors. HEMBR removal of chemical oxygen demand (COD) improved by 4% and membrane fouling was alleviated according to transmembrane pressure (TMP). The average silt density index (SDI) of HEMBR permeate samples was slightly better indicating less RO membrane fouling. Moreover,...