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    Construction of Suitable Polymeric Membrane by Thermal Induce Phase Separation (TIPS) for using in the Membrane Bioreactor (MBR)

    , M.Sc. Thesis Sharif University of Technology Jahanbakhshi, Nader (Author) ; Farhadi, Fathollah (Supervisor) ; Mousavi, Abbas (Supervisor)
    Abstract
    In this study, the response surface methodology (RSM) based on the central composite design (CCD) were used to prepare a polypropylene grafted maleic anhydride (PP-g-MA) microporous flat sheet membrane via thermally induced phase separation (TIPS) method. Mixture of dibutyl phthalate (DBP) and dioctyl phthalate (DOP) were used as diluent. The effect of the polymer composition and coagulation bath temperature on the morphology and performance of the fabricated microporous membranes in a bioreactor (MBR) were investigated. Analysis of variance (ANOVA) was used to determine which variables and interactions between variables have a significant effect on our responses. The ANOVA revealed that the... 

    Preparation of TEG Supported Liquid Membrane with Nano Particles of LTA Type Zeolite and Investigation of The Membrane Performance in Gas Separation

    , M.Sc. Thesis Sharif University of Technology Esmaeili, Nazila (Author) ; Bastani, Daryush (Supervisor) ; Kazemian, Hossein (Supervisor)
    Abstract
    The purpose of this research project was to improve the performance of TEG liquid membrane in separation of gas mixtures by adding zeolite LTA nanoparticles. Therefore, the NaA zeolite particles with nano size were synthesized with hydrothermal method at optimized condition. The supported liquid membrane with hydrophilic PVDF membrane and triethylene Glycol (TEG) was prepared in two different conditions. In the first one, the pores of the supporting membrane were filled with triethylene Glycol, whereas in the second one the pores were filled with the mixture of triethylene Glycol along with the 5 wt% and 10 wt% zeolite nanoparticles. The performances of prepared membranes were investigated... 

    Preparation and Performance Assessment of Polymer-SAPO-34 Mixed Matrix Membrane for Separation of CO2 from Other Gases

    , M.Sc. Thesis Sharif University of Technology Meshkat Alsadat, Shadi (Author) ; Soltanieh, Mohammad (Supervisor) ; Mohammadi, Aliasghar (Supervisor)
    Abstract
    In this research incorporation of SAPO-34 zeolite filler into polycarbonate membrane was investigated for fabrication of mixed matrix membrane (MMM). The main purpose of addition of zeolite in polymer matrix is to enhance the separation properties of pure membrane by means of the selective pores of SAPO-34. SAPO-34 possesses pores with proper size for separation of CO2 from CH4 by molecular sieving mechanism. Pure polycarbonate membrane and PC/SAPO-34 MMM was prepared by solvent evaporation method using dichloromethane as solvent. Zeolite loading was varied between 5-30%wt. First of all, polycarbonate was characterized by DSC, FTIR and viscometer analysis in order to determine all the... 

    WT-SOBI Method Towards Blind System Identification of Structures

    , M.Sc. Thesis Sharif University of Technology Saremi, Shervin (Author) ; Kazemi , Mohammad Taghi (Supervisor)
    Abstract
    Blind source separation methods such as independent component analysis (ICA) and second order blind identification (SOBI) have shown considerable potential in the area of ambient vibration system identification. The objective of these methods is to separate the modal responses, or sources, from the measured output responses, without the knowledge of excitation. Several frequency domain and time domain methods have been proposed and successfully implemented in the literature. Whereas frequency-domain methods pose several challenges typical of dealing with signals in the frequency-domain, popular time domain methods such as NExT/ERA and SSI pose limitations in dealing with noise, low sensor... 

    Relation Between Stochastic Integrals the Geometry of Banach Spaces

    , M.Sc. Thesis Sharif University of Technology Rashtian, Hanif (Author) ; Zohuri Zangeneh, Bijan (Supervisor)
    Abstract
    n this article, we find necessary conditions for the existence of Ito Integral in a Banach space with respect to compensated Poisson random measure (cPrm). Ito integrals with values on M-type 2 Banach spaces F of the above form exist for all measurable, adapted functions f square integrable w.r.t. β ⊗ d t (f ∈ M2T;_(E/F)),with β being Lévy measure associated with cPrm, and have strong second moments. We show that, for general separable Banach spaces F, an inequality of the type resulting for M-type 2 Banach spaces with constant depending on cPrm is necessary and sufficient for the existence of Ito integral having second moment finite for all f ∈ M2 T;_(E/F). It is shown that M2 T;_(E/F) is... 

    Leaching of Titanium-bearing Concentrate of Solid-state Reduction of Titanomagnetite Ores

    , M.Sc. Thesis Sharif University of Technology Babanejad, Safoura (Author) ; Askari, Masoud (Supervisor)
    Abstract
    Some of the low-grade titanium resources which are located in the country are titanomagnetite placer deposits. In current study, beneficiation of titanium-bearing concentrate of a placer deposit containing 6.13wt.% TiO2 was investigated by acidic leaching in order to remove impurities. To beneficiate the concentrate, based on the optimum conditions obtained in previous studies, solid-state reduction, magnetic separation, and calcination of non-magnetic product were performed. Afterwards, by studying temperature, time, acid concentration and L:S ratio, the final product was leached under optimal conditions were as follows: H2SO4 concentration of 15wt.%, L:S ratio of 20:1 (mL:g), reaction... 

    EEG Denoising Using Combination of Kalman Filtetring and Blind Source Separation Approaches for Epileptic Components Extraction

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Marzieh (Author) ; Shamsollahi, Mohammad Bagher (Supervisor)
    Abstract
    Epilepsy is a neurological disorder whose prevalence is estimated to be 1% of the world population. Electroencephalogram (EEG) is one of the best and convenient non-invasive tools used in diagnosis and analysis of this disease. Epileptic components extracted from EEG recordings are widely used in neuroscience in the diagnosis analysis like epilepsy source localization. However, epileptic components are often contaminated and covered with artifacts of physiological origin (baseline, EMG, ECG, EOG, etc.) or instrument noises (power supply, electrode, etc.). So, preprocessing and denoising is necessary for precise analysis of epilepsy EEG recording. Heretofore, several methods have been... 

    Convective-Reactive Transport and Unstable Density-Driven Flow in Fractured Porous Media

    , M.Sc. Thesis Sharif University of Technology Shafabakhsh, Paiman (Author) ; Ataie-Ashtiani, Behzad (Supervisor)
    Abstract
    The goal of this study is to explore the density-driven flow and study the effect of fracture as well as chemical processes and reactions on convective transport. Convective flow is used in connection with the density-driven flow where the flow is driven by density differences in the fluid, which can be affected by the ambient rocks. Several studies of density-driven flow in porous media have focused on the effect of heterogeneity on the mixing convection; however, they neglect the key processes of geochemical reactions in fractured porous media. This study aims to address this gap by investigating the combined effect of heterogeneity (as fractures) and the existing geochemical reactions on... 

    Supersonic Separation

    , M.Sc. Thesis Sharif University of Technology Daryaie, Mohammad Reza (Author) ; Moosavi, Ali (Supervisor) ; Nouri Borujerdi, Ali (Supervisor)
    Abstract
    Supersonic separators with neither rotating parts nor chemical process, physically separate particles in a multi-phase flow. In comparison with general separation techniques, which are utilized in industries, specifically this equipment is cheaper, smaller and lighter. Condensation and separation at supersonic velocity is the key to achieve a significant reduction in both capital and operating costs. In this study, a two dimensional de Laval nozzle and few three-dimensional supersonic separator have been modeled. The 3D models modified in shape and dimensions. Impellers were created to form swirl flow. The models were simulated by the use of CFD software ANSYS FLUENT. Diverse inlet pressures... 

    Separation of CO2 Using Mixed Matrix Rubbery Membrane

    , M.Sc. Thesis Sharif University of Technology Arbabpour Jannatabadi, Atiyeh (Author) ; Bastani, Dariush (Supervisor) ; Ghadimi, Ali (Supervisor)
    Abstract
    In this study, ZIF-8 was synthesized at room temperature and Then ZIF-8/PEGDA mixed matrix membranes with 5 and 10% of ZIF-8 were prepared by UV photopolymerization to analyze the separation CO2 from natural gas for the first time. The permeation results of gases in mixed matrix membranes in the temperature range of 35-75 degrees centigrade and in pressure ranging from 4-15 bar show the permeability of gases in mixed matrix membranes with 5 and 10% increase more than a pure polymer nearly 14.3 and 31%, respectively, But, CO2=CH4 selectivity decreases. The gas sorption in ZIF-8 was measured in the temperature range up to 75 ◦C and pressure ranging from 2-5 bar. The adsorption isotherm follows... 

    Bilnd Source Separation in Nonlinear Mixtures

    , Ph.D. Dissertation Sharif University of Technology Ehsandoust, Bahram (Author) ; Babaiezadeh, Massoud (Supervisor) ; Jutten, Christian (Co-Supervisor) ; Rivet, Bertrand (Co-Supervisor)
    Abstract
    Blind Source Separation (BSS) is a technique for estimating individual source components from their mixtures at multiple sensors, where the mixing model is unknown. Although it has been mathematically shown that for linear mixtures, under mild conditions, mutually independent sources can be reconstructed up to accepted ambiguities, there is not such theoretical basis for general nonlinear models. This is why there are relatively few resultsin the literature in this regard in the recent decades, which are focused on specific structured nonlinearities.In the present study, the problem is tackled using a novel approach utilizing temporal information of the signals. The original idea followed in... 

    Multimodal Blind Source Separation

    , Ph.D. Dissertation Sharif University of Technology Sedighin, Farnaz (Author) ; Babaie-Zadeh, Massoud (Supervisor)
    Abstract
    Blind Source Separation (BSS) is a challenging task in signal processing which aims to separate sources from their mixtures when no information is available about the sources or the mixing system. Different approaches have already been proposed for source separation.However, during the last decade, new approaches based on multimodal nature of phenomena have been proposed for source separation. Different aspects of a multimodal phenomenon can be measured by means of different instruments where each of the measured signals is called a modality of that phenomenon. Although the modalities are different signals with different features, due to the same physical origin, they usually have some... 

    Separation of Carbondioxide from CO2-Air Mixture Using ILM Membrane Containg DGA-TEG

    , M.Sc. Thesis Sharif University of Technology Davardoost, Farzad (Author) ; Bastani, Dariush (Supervisor)
    Abstract
    In this research, initially the Triethylene glycol and Diglycol amine liquid membrane which is supported by PVDF, was prepared in order to separate the Carbone dioxide from CO2-Air mixture. A polyvinylidene fluoride (PVDF) membrane was chosen to have chemical resistance to solution. The effect of Pressure, Concentration of TEG and DGA solution and the percentage of carbon dioxide in feed; in rate and permeability of CO2, N2 and O2 and also selectivity of CO2/ N2 , CO2/ O2 and N2/ O2 was investigated. Transport of CO2 was facilitated due to reversible chemical reaction between CO2 and amine solution. The experiments were done in 0.4, 0.6 and 0.8bar and different concentration of solution.... 

    Separation of Plasma from Blood Using a Dielectrophoresis-Assisted Microfluidic Device

    , M.Sc. Thesis Sharif University of Technology Shams, Mehran (Author) ; Mohammadi, Ali Asghar (Supervisor) ; Soltanieh, Mohammad (Supervisor)
    Abstract
    % of human blood makes up of plasma, that this plasma is a rich source of proteins that can be used as biomarkers for a variety of clinical diseases and laboratory research, therefore, it is necessary that the plasma be separate by a high purity percentage. Using a centrifuge It is a common method used to separate plasma from blood, but because it requires large equipment and a large volume of blood, as well as stress caused by centrifugal force, increases the probability of damage to the biomarkers, so it has been tried today that Use methods that are easy to transport and require a small amount of blood. The idea of using the microfluidic device has been put forward for the purpose of... 

    Separation and Preconcentration of Gold and Silver Nanoparticles Using Cloud Point Extraction

    , M.Sc. Thesis Sharif University of Technology Zare-moghadam, Mousa (Author) ; Hormozi-Nezhad, M.R (Supervisor)
    Abstract
    Separation and identification of metal nanoparticles in surface water samples such as river water is very important. Nanoparticles specially metal nanoparticles have small dimensions can easily pass through from the body's outer immune system and disrupt biological function. Most of the nanoparticles have active surface so environmental contaminants can be absorbed on their surface and then can penerated in the body, and they may cause disease. Therefore determination of nanoparticles type and concentrations and their separation from the surrounding environment, especially surface waters is important. Separation and preconcentration of metal nanoparticles was done by using cloud point... 

    Separation and Purification of Conjugated Linoleic Acid Isomers from Vegetable Oils

    , M.Sc. Thesis Sharif University of Technology Hajizadeh, Mohammad (Author) ; Alemzadeh, Iran (Supervisor)
    Abstract
    Conjugated linoleic acid (CLA), a mixture of positional and geometrical isomers of linoleic acid with conjugated double bonds, has gained considerable attention because of its anticarcinogenic and obesity treatment properties. The most biologically active CLA isomers are 9c, 11t-18:2 and 10t, 12c-18:2. The aim of this study is to separate and purify the two essential isomers via enzymatic method by Candida rugosa lipase and chemical method by urea crystallization and also optimization of reaction conditions in order to better separation. For enzymatic purification, L-menthol and Lauryl alcohol were used separately. Optimization of reaction conditions by enzyme content, time and the ratio of... 

    Separation and Purification of Industrial Proteins by Chromatography and Aqueous two Phase System

    , M.Sc. Thesis Sharif University of Technology Yavari, Milad (Author) ; Vossoughi, Manouchehr (Supervisor) ; Seifkordi, Ali Akbar (Supervisor)
    Abstract
    Separation of biomolecules such as enzymes is the most important part of biotechnology process which 10-90 % of costs is for separation and purification. There are several methods for purification of bio materials and one of them is chromatography which use in enzyme purification but this method have several problem such as cost ,time consuming and scale up Because of this a suitable alternative demands for industrial separation. An alternative is aqueous two-phase systems (ATPS). In this project was studied about partial purification of alkaline protease produced by Bacillus licheniformis ATCC 21424 in aqueous two-phase system and comparison with chromatography method. an aqueous two-phase... 

    Separation and Microfluidic Analysis of one Cancer Biomarker (Exosome) by Means of Microfluidic Chip Microfluidc Analysis Exosome Toward Liquid Biopsy for Cancer Tumor Cell

    , M.Sc. Thesis Sharif University of Technology Madani, Mohammad (Author) ; Saidi, Mohammad Said (Supervisor) ; Firouzabadi, Bahar (Co-Supervisor)
    Abstract
    The recent breakthroughs in the lab-on-a-chip technology will not be directly used as clinical devices unless the specific applications are carefully tested and certified. As there is a growing trend towards microfluidic devices for biomedical research, an active microfluidic device was developed. Common microfabrication methods were used to develop a microchip to separate and concentrate exosome and particular cell based on the dielectrophoresis phenomenon. Unique capabilities of the dielectrophoresis phenomenon make it a powerful tool for micro particle manipulation in micro scale. In this research, geometry for the mentioned purpose is designed and optimized. Three-dimensional... 

    Hydrogen separation from gas mixtures using polymeric membranes

    , M.Sc. Thesis Sharif University of Technology Abdollahi, Yaser (Author) ; Mousavi, Abbas (Supervisor) ; Bastani, Darioush (Supervisor) ; Sadatnia, Behrooz (Co-Advisor)
    Abstract
    Because of higher hydrogen demand in recent years, study of hydrogen separation from gas mixtures is highly regarded. Because of some parameters such as high surface to volume ratio and ability to withstanding high pressure, polymeric hollow fiber membranes have a good potential of hydrogen recovery. So in this study, fabrication of single-layer and dual-layer hollow fiber membranes have been investigated. Selective polymer that used in both single and dual layer membranes is polyethersulfone. Membranes were fabricated by dry-wet phase inversion method and effects of extrusion rates and their ratio, composition and temperature of polymer solution, composition of bore fluid, coating and air... 

    Separating Colored Points

    , M.Sc. Thesis Sharif University of Technology Assadian, Navid (Author) ; Zarei, Alireza (Supervisor)
    Abstract
    Separating colored points is one of the important problems in computational geometry. In separating colored points problems a set of colored points in Euclidean space are given that each color designates a set of certain data.Different problems can be defined in the colored points subject. Among them,separating colored points is studied in this thesis. It is supposed that two sets of blue and red points are given. It is desired to find the minimum number of rectangles that separate the blue points from the red points. It is demonstrated hat if P ̸= NP then there is no polynomial time algorithm for solving this problem. Then, a constant factor approximation algorithm is introduced and applied...