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Synthesis of β-hydroxy dithiocarbamate derivatives via regioselective addition of dithiocarbamate anion to epoxide in water

Ziyaei Halimjani, A ; Sharif University of Technology | 2006

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  1. Type of Document: Article
  2. DOI: 10.1139/V06-150
  3. Publisher: 2006
  4. Abstract:
  5. The reactions of different dithiocarbamate anions with epoxides were investigated in water. With this method, β-hydroxy dithiocarbamate derivatives were synthesized in high yields. The reaction was also carried out in DMF in the presence of lithium perchlorate with a simple work-up procedure, and the results are compared. © 2006 NRC
  6. Keywords:
  7. Dithiocarbamate anion ; Hydroxy dithiocarbamate ; Derivatives ; Negative ions ; Synthesis (chemical) ; Water ; Esters ; Amine ; Beta hydroxy dithiocarbamate derivative ; Carbamic acid derivative ; Epoxide ; Lithium ; Perchlorate ; Styrene oxide ; Unclassified drug ; Addition reaction ; Chemical interaction ; Chemical reaction ; Chemical structure ; Hydrogen bond ; RNA translation ; Spectroscopy ; Synthesis
  8. Source: Canadian Journal of Chemistry ; Volume 84, Issue 11 , 2006 , Pages 1515-1519 ; 00084042 (ISSN)
  9. URL: https://cdnsciencepub.com/doi/10.1139/v06-150