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    Manufacture, Mechanical Properties and Interfacial Corrosion of 316L/17-4PH Bimetals with a Nanostructured Ni Layer

    , M.Sc. Thesis Sharif University of Technology Salahi, Armita (Author) ; Simchi, Abdol Reza (Supervisor) ; Dolati, Abol Ghasem (Supervisor)
    Abstract
    Transient liquid phase (TLP) bonding of 316L/17-4PH bimetals using a thin layer of nanostructured nickel was studied. The nanostructured nickel interface was deposited through pulse current coating in a Watt bath. The TLP bonding was performed at different temperatures ranging from 1000 °C to 1300 °C using a nickel interface having different thicknesses (2-17µm) and crystallite size (14-67 nm). The microstructure of the joint bimetals and phase formation were studied using the optical and scanning electron microscopes and X-ray diffraction (XRD) method. The mechanical properties of the bimetals were evaluated by micro-hardness and shear tests. To evaluate the corrosion behavior of the... 

    Damage Detection and Evaluation of Repair Materials and Techniques for Concrete Bridges

    , M.Sc. Thesis Sharif University of Technology Karimi, Roya (Author) ; Joghataie, Abdoreza (Supervisor)
    Abstract
    Poor maintenance of concrete bridges in the past years in Iran, caused serious damages, so most of them need rehabilitation. The majority of repaired members are exposed to repeated damage because compatibility of repair material to substrate concrete not considered as well as weather and loading conditions. This study attempts to improve the repair achievement and durability of concrete bridges. This investigation contains two phases: preliminary study and experimental phase. Preliminary study attends to detect different types of damages of concrete bridges and their causes along with their propagation. The next part of this study discusses about various types of repair materials. In... 

    Investigation on Stainless Steel - Copper Roll Bonding

    , M.Sc. Thesis Sharif University of Technology Bagherian Talkhoonche, Nasrolla (Author) ; Akbarzade, Abbas (Supervisor)
    Abstract
    Roll bonding process is commonly used for the production of multilayer sheets. In the present study, using the roll bonding process, two layer sheets of copper - stainless steel were produced. In this case bonding strength was measured by peeling test at different statges and the quality of bonding was evaluated by SEM and Stereo Electron Microscope. The cross-sections of the bonding of rolled and annealed samples was investigated by optical microscopy. Also using EDAX analysis and EDS, the chemical composition of formed transition layer and the size of its interface at different temperature are measured respectively and the change in mechanical properties was investigated by tensile test... 

    Analytical and Experimental Studies on Interface between Different Mortars and Brick

    , M.Sc. Thesis Sharif University of Technology Azimi Resketi, Nima (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Usage of masonry materials in a country like Iran is still significantly high. As most of the failures during an earthquake in this system is failure caused by low ductility of cement mortars and also the high rate of carbon dioxide produced by cement. Experiences of Kermanshah earthquake in 2017 in Iran has doubled the importance of this issue. Hence, in the present investigation, an attempt to enhance the shear bond characteristics of structures constructed by masonry using green materials has been made. “Taftan” natural Pozzolan and two types of rice husk ash (RHA) was used in mix design of used mortars as a green material. In this investigation, a direct shear test (DST) device is... 

    Role of Molecular Weight and Molecular Weight Distribution on Weldability and Joint Strength of Polypropylene by Hot Plate Welding

    , M.Sc. Thesis Sharif University of Technology Azhdari, Moein (Author) ; Kokabi, Amir Hossein (Supervisor) ; Bagheri, Reza (Supervisor)
    Abstract
    In this study, role of molecular weight and Molecular Weight Distribution (MWD) on joint strength of polypropylene was investigated by hot plate welding. Standard tensile specimens of three different co-polypropylene with low, medium and high Melt Flow Index (MFI) values (MR230C, 440L and 548R respectively) were injected and welded after cutting. Hot plate welding device was used to join specimens. Melt Flow Index and dynamic rheology tests were employed in order to study the rheological behavior of polymers melt. Furthermore tensile test was done to investigate joint strength of specimens at 150, 175 and 200 ͦ C. It was observed that in constant temperature, increasing viscosity (typically... 

    Bonding Feasibility, Mechanical Properties and Formability of Three-layered St/AZ31/St Composites Fabricated by Roll Bonding

    , M.Sc. Thesis Sharif University of Technology Abedi, Reza (Author) ; Akbarzadeh, Abbas (Supervisor)
    Abstract
    New materials as hybrid materials or laminate composites, due to combination of many properties, can be used in many industries. The aim of this research is bonding of three-layered St/AZ31/St composite by roll-bonding process. The roll-bonding process was performed at three preheating temperatures, 340, 400 and 450 ⁰C, with thickness reduction of 30 to 68% and different thicknesses of intermediate layer (AZ31). In order to improve the bonding strength, the as-rolled specimens were annealed at constant temperature of 375 ⁰C. For evaluation of bond strength and investigating the formation of a diffusion layer, the results of peel test and microscopic images were studied. Tensile specimens... 

    Experimental Investigation of Formability and Mechanical Properties of Composites Manufactured by Direct Roll Bonding

    , M.Sc. Thesis Sharif University of Technology Maleki, Payam (Author) ; Akbarzadeh, Abbas (Supervisor)
    Abstract
    In this study, the ST14 low carbon steel sheet was used as a skin layer in the construction of three-layer laminates. The use of this steel was due to its high mechanical properties and excellent formability. A thermoplastic polyurethane sheet was also used as the core layer. The selection criteria of this polymer were no need for adhesive (for bonding metal to polymer) as well as proper mechanical properties (elongation and strength) and physical (density). The perfect process for manufacturing three-layer laminates is the roll bonding process. To manufacturing a laminate with the desired properties of the designer, the rolling parameters (rolling speed and thickness reduction) must be... 

    Compressive and Bond Behavior of Concrete-Filled Pultruded GFRP and PE Tubes Under Elevated Temperatures

    , Ph.D. Dissertation Sharif University of Technology Tabatabaeian Nimavard, Mojtaba (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    Concrete-filled GFRP and PE tubes are composite systems using the polymeric tubes as confinement for the marine structures to extend their service life. However, elevated temperatures and thermal cycles in marine environments can affect the behavior of such composite systems. In this investigation, the effect of elevated temperatures and thermal cycles on the performance of concrete-filled pultruded GFRP tubes (CFPGT) and concrete-filled polyethylene tubes (CFPT) is assessed, respectively. For this, different parameters such as concrete core strength (30 and 60 MPa), exposure temperature (25, 100, 200, 300, and 400°C), time exposure (60 and 120 min.), number of thermal cycles (50, 100, and... 

    The impact of climate condition on the optimal size of direct coupled photovoltaic-electrolyzer systems

    , Article Simulation Series, 26 July 2015 through 29 July 2015 ; Volume 47, Issue 10 , July , 2015 , Pages 224-229 ; 07359276 (ISSN) Sayedin, F ; Maroufmashat, A ; Sattari khavas S ; Elkamel, A ; Aladwani, S ; Sharif University of Technology
    The Society for Modeling and Simulation International  2015
    Abstract
    Solar energy exists extensively in all parts of the world. However the intermittency of solar energy presents critical challenges to PV system. The intermittency can be covered by storing solar energy in chemical bonds such as hydrogen. This process can be performed by photovoltaic powered electrolysis of water. The energy transfer efficiency between PV and electrolyzer is subject to the distance between maximum power points (MPP) of PV module and operating points. The operating points can be adjusted by optimizing the design parameters of the electrolyzer but the maximum power points are function of PV module characteristics, solar radiation and ambient temperature. Therefore the weather... 

    Environmental effects on the bond at the interface between FRP and wood

    , Article European Journal of Wood and Wood Products ; Volume 76, Issue 1 , 2018 , Pages 163-174 ; 00183768 (ISSN) Yarigarravesh, M ; Toufigh, V ; Mofid, M ; Sharif University of Technology
    Springer Verlag  2018
    Abstract
    The advantages of fiber reinforced polymer (FRP), such as high specific strength, resistance against corrosion and formability, have made it a more acceptable alternative to conventional materials regarding repairing and retrofitting of structures. Although investigations in recent years have proved the concern of civil engineers about the environmental effects on the bond between FRP and concrete or masonry (especially moisture and temperature), only few researches have been reported on FRP-wood interfaces. This research investigated the effect of five different environments on the bond at the interface between FRP and wood. A series of pull-out tests were performed on 375 wood specimens... 

    The effect of titanium dioxide (TiO2) nanoparticles on hydroxyapatite (HA)/TiO2 composite coating fabricated by electrophoretic deposition (EPD)

    , Article Journal of Materials Engineering and Performance ; Volume 27, Issue 5 , May , 2018 , Pages 2338-2344 ; 10599495 (ISSN) Amirnejad, M ; Afshar, A ; Salehi, S ; Sharif University of Technology
    Springer New York LLC  2018
    Abstract
    Composite coatings of Hydroxyapatite (HA) with ceramics, polymers and metals are used to modify the surface structure of implants. In this research, HA/TiO2 composite coating was fabricated by electrophoretic deposition (EPD) on 316 stainless steel substrate. HA/TiO2 composite coatings with 5, 10 and 20 wt.% of TiO2, deposited at 40 V and 90 s as an optimum condition. The samples coated at this condition led to an adherent, continuous and crack-free coating. The influence of TiO2 content was studied by performing different characterization methods such as scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDS), corrosion resistance in simulated body fluid (SBF),... 

    Evaluation and selection of optimal oxygen/fuel ratio for best mechanical properties, oxidation resistance and microstructure of HVOF NiCoCrAlY coatings using AHP–VIKOR method

    , Article Oxidation of Metals ; Volume 89, Issue 3-4 , April , 2018 , Pages 429-451 ; 0030770X (ISSN) Salehi Doolabi, M ; Ghasemi, B ; Sadrnezhaad, S. K ; Habibolahzadeh, A ; Jafarzadeh, K ; Sharif University of Technology
    Springer New York LLC  2018
    Abstract
    This work describes coating of NiCoCrAlY on IN-738LC superalloy by high-velocity oxygen fuel (HVOF) process. Properties of the coatings are significantly influenced by oxygen/fuel ratio and other spraying parameters. The effect of oxygen/fuel ratio on the oxidation behavior, bond strength, hardness, roughness and microstructure including porosity, inclusion formation and unmelted particles are discussed here. The porosity and inclusion in C1 coating are maximal. C2 coating with oxygen/fuel ratio of 2 has the highest bond strength and the lowest unmelted particles. C3 coating with the lowest total porosity and inclusion has the minimal roughness and the highest oxidation resistance and... 

    High content of boride-forming elements in in617 nickel-based superalloy enables short isothermal solidification time during transient liquid phase bonding

    , Article Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science ; Volume 51, Issue 11 , 2020 , Pages 5715-5724 Hosseini, M ; Ghasemi, A ; Pouranvari, M ; Sharif University of Technology
    Springer  2020
    Abstract
    Isothermal solidification stage during transient liquid phase bonding is the key to preclude intermetallic phase formation during solidification of the liquid phase. The rate of isothermal solidification is controlled by solid-state diffusion. Therefore, the bonding time required to complete isothermal solidification is generally long. This paper reports a very short isothermal solidification time for transient liquid phase bonding of IN617 solid solution nickel-based superalloy using a boron-containing filler metal. A eutectic-free bond with limited grain growth in the base material with high shear strength is achievable by utilizing a short (i.e., 5 minutes) thermal bonding strategy. The... 

    Synthesis of magnetic ions-doped QDs Synthesized Via a facial aqueous solution method for Optical/MR dual-modality imaging applications

    , Article Journal of Fluorescence ; Volume 31, Issue 3 , 2021 , Pages 897-906 ; 10530509 (ISSN) Gharghani, S ; Zare, H ; Shahedi, Z ; Fazaeli, Y ; Rahighi, R ; Sharif University of Technology
    Springer  2021
    Abstract
    This research reports the preparation and examination of Cadmium Telluride (CdTe) Quantum Dots and doping CdTe QDs with Europium (Eu), Gadolinium (Gd), and Manganese (Mn) prepared in aqueous solution using TGA as a capping agent. Magnetic QDs (MQDs) are important agents for fluorescence (FL) /magnetic resonance (MR) dual-modal imaging due to their excellent optical and magnetic properties. Herein, the chemical bonds, structural, fluorescence, and magnetized properties of CdTe QDs and effect of Mn, Eu, and Gd ions doping on their properties were examined by X-ray powder diffraction (XRD), high-resolution transmission electron microscopy (HRTM), Energy-dispersive X-ray spectroscopy (EDX),... 

    Influence of H-bonds on acidity of deoxy-hexose sugars

    , Article Journal of Physical Organic Chemistry ; Volume 33, Issue 10 , June , 2020 Mosapour Kotena, Z ; Fattahi, A ; Sharif University of Technology
    John Wiley and Sons Ltd  2020
    Abstract
    The unusual monosaccharaides such as deoxy-hexose sugars, including methyl-pentose and aldo-pentose, are promising and important sugars in life science. However, little research on H-bond interactions in these systems has been reported. The aldo-pentose has a proton instead of the CH2OH group on C5; conversely, methyl-pentose has a CH3 group on C5. The aim of the present study is to investigate the role and nature of intramolecular H-bonds on acidity of CH3-pentose sugars (L-fucose and L-rhamnose) and aldo-pentose sugars (D-xylose, L-lyxose, D-ribose, and L-arabinose) using B3LYP/6-311++G (d, p) level. The calculated acidity values (ΔHacid) of these Dexoy-hexose were found to be from 343 to... 

    Gold at crossroads of radical generation and scavenging at density functional theory level: Nitrogen and oxygen free radicals versus their precursors in the face of nanogold

    , Article Journal of Physical Organic Chemistry ; Volume 34, Issue 1 , 2021 ; 08943230 (ISSN) Ahmadi, A ; Kassaee, M. Z ; Ayoubi Chianeh, M ; Fattahi, A ; Sharif University of Technology
    John Wiley and Sons Ltd  2021
    Abstract
    In our previous report (J. Phys. Org. Chem., 2017), we discussed the dual behavior of gold nanocluster (Au3 NC), where it scavenged reactive oxygen species (ROS) while promoted their generation to a lesser extent. Continuing this quest, we investigate the effects of Au3 NC on common reactive nitrogen species (RNS: O=N˙ and O=N-O) and their precursors (O=N-H and O=N-O-H, respectively), at B3LYP/LACVP+* level of theory. We compare the results with those of prevalent ROS (H-O˙ and H-O-O˙) and their precursors (H-O-H and H-O-O-H, respectively). To this end, various parameters are probed such as binding energy (Eb), bond dissociation energy (BDE), bond lengths, Mullikan spin density (MSD),... 

    Gold at crossroads of radical generation and scavenging at density functional theory level: Nitrogen and oxygen free radicals versus their precursors in the face of nanogold

    , Article Journal of Physical Organic Chemistry ; Volume 34, Issue 1 , 2021 ; 08943230 (ISSN) Ahmadi, A ; Kassaee, M.Z ; Ayoubi-Chianeh, M ; Fattahi, A ; Sharif University of Technology
    John Wiley and Sons Ltd  2021
    Abstract
    In our previous report (J. Phys. Org. Chem., 2017), we discussed the dual behavior of gold nanocluster (Au3 NC), where it scavenged reactive oxygen species (ROS) while promoted their generation to a lesser extent. Continuing this quest, we investigate the effects of Au3 NC on common reactive nitrogen species (RNS: O=N˙ and O=N-O) and their precursors (O=N-H and O=N-O-H, respectively), at B3LYP/LACVP+* level of theory. We compare the results with those of prevalent ROS (H-O˙ and H-O-O˙) and their precursors (H-O-H and H-O-O-H, respectively). To this end, various parameters are probed such as binding energy (Eb), bond dissociation energy (BDE), bond lengths, Mullikan spin density (MSD),... 

    Bioinspired TiO2/chitosan/HA coatings on Ti surfaces: Biomedical improvement by intermediate hierarchical films

    , Article Biomedical Materials (Bristol) ; Volume 17, Issue 3 , 2022 ; 17486041 (ISSN) Rahnamaee, S. Y ; Ahmadi Seyedkhani, S ; Eslami Saed, A ; Sadrnezhaad, S. K ; Seza, A ; Sharif University of Technology
    Institute of Physics  2022
    Abstract
    The most common reasons for hard-tissue implant failure are structural loosening and prosthetic infections. Hence, in this study, to overcome the first problem, different bioinspired coatings, including dual acid-etched, anodic TiO2 nanotubes array, anodic hierarchical titanium oxide (HO), micro- and nanostructured hydroxyapatite (HA) layers, and HA/chitosan (HA/CS) nanocomposite, were applied to the titanium alloy surfaces. X-ray diffraction and FTIR analysis demonstrated that the in situ HA/CS nanocomposite formed successfully. The MTT assay showed that all samples had excellent cell viability, with cell proliferation rates ranging from 120% to 150% after 10 days. The HO coating... 

    Effect of intermediate nickel layer on seal strength and chemical compatibility of glass and ferritic stainless steel in oxidizing environment for solid oxide fuel cells

    , Article International Journal of Hydrogen Energy ; Volume 40, Issue 46 , 2015 , Pages 16434-16442 ; 03603199 (ISSN) Fakouri Hasanabadi, M ; Nemati, A ; Kokabi, A. H ; Sharif University of Technology
    Elsevier Ltd  2015
    Abstract
    The effects of intermediate nickel layer on seal strength and chemical compatibility of seal glass and interconnect materials for solid oxide fuel cells (SOFCs) were investigated. Two types of samples (metal/glass/metal sandwiches and glass coated metals) were prepared with the sheet of AISI 430 (nickel plated and uncoated) and slurry of compliant silicate sealing glass (SCN-1). The joined and coated samples were heated at 850 °C for different time durations (0.5-100 h). Tensile and impact tests were performed and SEM micrographs were used to analyze the glass/metal interaction. The results indicate that nickel plated AISI 430 shows higher adhesion strength at short durations of heating due... 

    Microstructural, optical, and electrical characteristics of Ni/C doped BST thin films

    , Article Ceramics International ; Volume 45, Issue 5 , 2019 , Pages 5503-5510 ; 02728842 (ISSN) Emadi, F ; Nemati, A ; Hinterstein, M ; Adabifiroozjaei, E ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    In the present work the effect of simultaneous doping of carbon and nickel on the microstructural, optical, and electrical properties of barium strontium titanate (BST) is investigated. Thin films of BST were prepared by the sol-gel method in six different compositions ((Ba0.6Sr0.4)(NixCyTi1-x-y)O3): x = y = 0.00 (BST), x = 0.04 y = 0.00 (BST4N), x = 0.04 y = 0.01 (BST4N-1C), x = 0.04 y = 0.02 (BST4N-2C), x = 0.04 y = 0.03 (BST4N-3C), and x = y = 0.04 (BST4N-4C). Structural features and chemical bonds of the films were studied by TGA/DSC, XRD, FT-IR, and FE-SEM. The electrical and optical properties of the films were analysed by impedance spectroscopy and UV–VIS spectroscopy. The results...