Sharif Digital Repository

Magnetic Shape Memory Alloys (MSMAs) are a category of active materials which can be excited by magnetic field. These alloys have been used in sensor and actuator applications recently. MSMAs posses special properties such as large magnetic field-induced strains (up to %10) and high actuation frequency (about 1kHz), while ordinary Shape Memory Alloys can’t act in frequencies above 5Hz due to the time involved with heat transformation. In this thesis, MSMAs are modeled by means of incremental modelling which is a useful method in analysis of nonlinear behaviour of materials. Furthermore, stress-strain curve of MSMA is approximated using an analytical expression whose parameters can simply be... 

In this work, the effect of chemical composition on structural, mechanical, electrical and magnetic properties of nanocrystalline Finemet-type alloys with the composition of Fe73.5Si13.5B9Nb3Cu1 , Fe77Si11B9Nb2.4Cu0.6 and (〖Fe_0.5 Co_0.5)〗_77 Si_11 B_9 Nb_2.4 Cu_(0.6 )was investigated. The samples were prepared by vacuum arc melting of high purity constitution in order to obtain a nanocrystalline structure. The amorphous ribbons were then annealed under vacuum with the same conditions of temperatures and time to compare their properties. The structural and thermal properties of the samples were analyzed using various techniques such as X-ray Diffraction (XRD) and Differential Scanning... 

In this project rotational barrier around the C-N bond in 4-ethyle-morpholine- carboxylate has been studied using DNMR spectroscopy. Spectra were taken at variable temperature, and then with simulation of bandshape broadening pattern at coalescence region, rate constants of exchange were obtained for all temperatures. For simulation of line-shape broadening Spinworks software was used, that with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from simulations, were used for calculation of thermodynamic activation parameters (∆G#, ∆H#, ∆S# and Ea). ∆G# 298 value of 13.66 Kcal/mol for 4-ethyle-morpholine- carboxylate... 

The Barrier of the internal rotation around C-N bond in O-ethyle morpholine-4-carbotioate were calculated using dynamic NMR spectroscopy (DNMR) in DMSO solvent. 1H and 13C NMR spectra were recorded at different temperatures (295-350K). Band shape broadening patterns at coalescence regions were simulated to extract rate constants of NMR spectera. Transition state thermodynamic properties of internal rotation around C-N bond in O- ethyle morpholine -4- carbotioate are estimated: , , , . To assay reliability of the estimated values, transition state thermodynamic properties were calculated using PCM model at method and basis set B3LYP/6-311++G(d,p). Theoretical values of thermodynamic... 

Prediction and calculation of shielding tensors of H, C, F and P nuclei of different molecules has been the subject of much research, because these nuclei have the greatest importance in NMR experiments. The optimum wave functions and calculation method were obtained using empirical models and factorial design. Based on preliminary experiences, the following four factors at two levels were selected: electron correlation, triple-ξ valence shell, diffuse function and polarization function. The wave functions for calculating gas phase 1H and 13C chemical shifts of various types of alcohols, amines and simple hydrocarbons were optimized using empirical model. The B3LYP/6-311+G wave function is... 

Image segmentation is a technique which divides an image into significant parts. The accuracy of this technique plays an important role when it applies on medical images. Among various image segmentation methods, clustering methods have been extensively investigated and used. Since it is an unsupervised method, the existence of a small amount of side-information which is extracted from a specific application (in this case, medical image) could improve its accuracy. Using this side-information in clustering methods introduces a new generation of clustering approaches called semi-supervised clustering. This information usually has a format of pair-wise constraints and can be prepared easily... 

In this research a special Three-Phase to Single-Phase converter has been proposed to connect a three-phase Permanent Magnet Synchronous Generator (PMSG) of a wind turbine to a single-phase network. Common back-to-back converter used for this application employs a bulk capacitor in its DC link to generate the pulsating component of the single-phase side instantaneous power. This capacitor is costly and reduces system overall reliability. This problem is alleviated in this work by providing the single-phase load pulsating power using the PMSG large inductances. The proposed system leaves the PMSG torque ripple-free while providing the single-phase load power. With the help of this method,... 

In this thesis one of the sensorless methods which exploits the existing anisotropies of the rotor is utilized to estimate rotor position. In order to implement this method, first a high frequency voltage is injected in a specific, time-varying direction and then the corresponding current response would be observed in order to estimate the rotor saliency position. The estimation of rotor position would be more precise as the magnetic anisotropy due to rotor saliency increases and as a result the effect of noise and different disturbances in estimation of rotor position would be decresed. The effect of stator resistence is one of these disturbances which is usually neglected as a result of... 

Permanent-magnet synchronous generators have attracted more attention in recent years due to their special advantages which make them a suitable option for variable-speed wind turbines.Low-voltage ride through capability is one of the main concerns in widespread use of wind turbines in electric grids. Nowadays wind turbines are expected to remain connected to the grid during voltage dips and support the voltage recovery process by supplying reactive power.This thesis aims at behavior analysis and performance improvement of permanent-magnet synchronous generator-based wind turbines during grid faults. A simple method is presented to overcome the over current problem of the grid-side converter... 

After the review of formation of Landau levels (LL) in non-relativistic quantum mechanics, we have obtained LL in a certain gauge A_μ=(0,-B_0/2 y,B_0/2 x) at 2+1 &3+1 dimension. then give a summary of Quantum Field Theory at non-zero temperature . obtaining LL and two-point Green function in non-uniform magnetic field which determined with A_μ=(0,0,√qB ξe^(-(t+x) ),0).Next we calculate magnetic susceptibility of in such a field with finite chemical potential and temperature. Finally we compare the obtained results with uniform magnetic field one  

In this project rotational barrier around the C-N bond in Ethyl N-(pipyridin carbotioate) has been studied by using DNMR spectroscopy. Spectra were taken at various temperatures , and then with simulation of bandshape broadening pattern at coalescence region, the exchange rate constant of were obtained for all temperatures. For simulation of line-shpe broadening Spinworks software was used, that with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from the simulation were used for calculation of thermodynamic activation parameters (... 

Nowadays, in many financial markets, policy makers impose daily price limit to prevent investors from making emotional decisions, which can lead to abnormal price volatility. A number of theoretical and empirical studies have been conducted on the effectiveness of setting price limit, some supporting the idea and other rejecting. In this research, we begin with a detailed analysis of magnet effect as one of the consequences of setting price limit. Then we study the stock price of five firms listed in Tehran Stock Exchange (TSE) by means of an autoregressive model with explanatory variables to determine whether or not the magnet effect exists. These five firms, put together, comprise 23% of... 

Superconducting Quantum Interference Devices (SQUIDs) are one of the most sensitive magnetic flux detectors. According to their high sensitivity, these sensors have many applications such as magnetic imaging, magnetocardiography and magnetoencephalography. In this project we have designed and implemented a fluxgate based active shield that would be used in magnetocardiography. One of the main concerns in RF-SQUID applications is suppression of the low and high frequency noises. These noise sources includes earth magnetic force, humming noise and RF noise caused by cell phones. These sources could unlock RF-SQUID sensors and hence needs to be shielded. Low frequency noise suppression could be... 

In this project rotational barrier of C-N bond in Ethyl N-(pyrrolidine carbotioate) has been studied using DNMR spectroscopy. Spectra were taken at various temperatures, and then with simulation of bandshape broadening pattern, rate constants of exchanges were obtained for all temperatures. For simulation of line-shape broadening SpinWorks software was used,which with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from simulations, were used for calculation of thermodynamic activation parameters (?G#, ?H#, ?S# and Ea#).Experimental ?G# 298value(Experimental) of 18.3 Kcal/mol for Ethyl N-(pyrrolidine... 

The continuous rise in electricity demand and the ever growing power generation in different power networks over the world have caused the short circuit level in the power systems to exceed the operational rating of the installed power devices (including cables, circuit breakers and buses). Replacing these devices with new higher rating devices is an expensive solution. From this point of view, utilizing fault current limiters is an economical solution. Superconducting fault current limiters form an efficient category of current limiters. This type is expected to be studied and used widely in future due to their advantages. In this thesis, the first chapter reviews the superconductivity... 

A Flying Electric Generator (FEG) can be a wind turbine which operates at high altitudes, where there is a continuous fast flow of air and converts wind energy to electrical power.The related field is an interdisciplinary area and is mostly related to the Aerospace Engineering and Energy Conversion. We focused on Iran, as one of the few lands in the northern hemisphere that has a high overall amount of high altitude wind energy for at least half of the year over it, according to the information of atlas of airborne wind energy in this work.So to install the FEGs in Iran, we had to find, places with a safe aerial space overhead which grant us reliable spots over country. These places found by... 

Synchronous machines is one of the most popular machines in industry and in power plants. Because the dynamic of this machine is nonlinear, it can exhibit complex behaviors. In this project we have studied a special case in Permanent Magnet Synchronous Machines. A case in which speed of rotor, frequency, currents amplitude and voltages amplitude change in an irregular manner. This special case is called chaos. Chaos occurs for some specific values of parameters and inputs. In this study in the first step, we have tried to find the chaotic area of parameters of system (Prediction of chaos). Then in the next step, we have designed some controllers which can eliminate chaos in the system. The... 

In this study, the micro and nano particles of substituted strontium hexaferrites with nominal composition of SrFe12-xTix/2Znx/2O19 (x=0, 0.5, 1, 1.5, 2 and 2.5) were prepared by a co-precipitaion method. Ferrite-PVA composites (70:30) with thickness of 1.8mm were prepared at 220°C and 50Mpa. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), energy dispersive spectrometer (EDS), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) were employed for characterization of synthesized powders and composites. XRD and FTIR results showed that single phase hexaferrite were obtained for almost all of the... 

In this work we have studied conformation of ranitidine by dynamic nuclear magnetic resonance spectroscopy (DNMR) in four different solvents: chloroform, acetone, dimethylsulfoxide, and deuteriumoxide. Ranitidine has three tatumeric forms of enamine, nitoic acid, and imine, but its stable structure is enamine. Temperature dependent 1HNMR spectra of ranitidine which reportet at 500MHz were consistent with the following free activation of energies ΔG# (kcal mol-1): chloroform = 16.2; acetone = 15.4; dimethylsulfoxide = 15.1. The experimental results were confirmed by DFT theoretical calculations at the B3LYP/6-311++G (d, p) level of theory. It was also proved that ranitidine has the form of... 

Polyvinylalcohol/magnetite nanocomposite films were fabricated via solution casting. Magnetite (Fe3O4) nanoparticles were prepared by means of co-precipitation method and modified by citric acid. The nanoparticles and nanocomposites were characterized by scanning electron microscopy (SEM), x-ray diffraction (XRD), vibrating sample magnetometer (VSM), fourier transform infrared spectroscopy (FTIR) and mechanical measurement. The results reveal that magnetite nanoparticles have a spherical shape with an average diameter of 19.7nm and are superparamagnetic at room temperature. The nanoparticles are observed to be uniformly dispersed in the polymer matrix due to a strong interaction between the...