Sharif Digital Repository

Usage of concrete-filled pultruded glass fiber-reinforced polymer (GFRP) tubes (CFPGT) as columns can increase the service life of structures. However, marine structures such as oil platforms are always prone to fire because of the low resistance to the elevated temperatures. The purpose of this investigation is to evaluate the effects of concrete core strength (30 and 60 MPa), and exposure temperature (25, 100, 200, 300, and 400 °C) and time (60 and 120 min) on the compressive and bond behavior of CFPGTs. The properties of unexposed and exposed concrete core, pultruded GFRP hollow tubes, and CFPGTs were determined via compressive and disk-split tests. Also, the push-out test was used to... 

In this research, the application of equal channel angular extrusion process to produce both the cold-welded and diffusion-bonded Al/Cu bimetallic rods is assessed. The joints shear strength for both of the methods are measured and compared. The microstructure examinations were also carried out using scanning electron microscope equipped with EDX system and x-ray diffraction analysis. The results exhibit that the strength of the bond in cold-welded specimens is dependent on the amount of stretch and pressure at the materials interface. But in the diffusion-bonded specimens, it is depended on the struggle between the oxidation rate of the mating surfaces accompanied by inter-metallic... 

We report a study on hydrogen storage in Ca, Co, Fe, Ni, and Pd decorated multiwalled carbon nanotubes (MWCNTs) by using two techniques: volumetric and electrochemical. The results showed that hydrogen molecules are adsorbed on the defect sites and transported to the spaces between adjacent carbon via diffusion through both defect sites and opened tips into the layers. Hydrogen storage capacity can be improved in the decorated MWCNT by Co, Fe, Ni, and Ca metals in two approaches: (i) H2 adsorption via Kubas interaction and (ii) dissociation of H2 molecules on the metal particles. The results reveal that Pd are more effective catalyst for hydrogen storage process. It was found that... 

The behavior of Alsteel bilayer sheets produced by cold roll welding is investigated through the wedge tearing process. It is observed that through tearing the energy absorbed by cold roll welded bilayer sheets is larger than that of non-welded ones, even though all parameters are identical. Also bilayer sheets with low bond strength have the same energy absorbed by non-welded bilayer sheets. By investigating all contributing mechanisms in tearing and mechanical properties of composite layers and developing theoretical equations, it is concluded that bending of sheets through wedge tearing plays a major role in difference of energy absorbed by welded and non-welded bilayer sheets. Moreover,... 

Bond durability of FRP bars and concrete is an important issue to the overall integrity and long-term performance of a strengthening structure. This paper examines the bond durability of GFRP bars embedded in different types of concrete (Normal, self-compacting, light weight, and high strength) exposed to aggressive environments, namely, sea water, alkaline, and acid. A total of 132 specimens were tested in direct pull-out. The development lengths of both control and conditioned specimens were obtained and compared to the current standards. The results revealed bond strength reductions of 0–21% for the light weight, 1–16% for the normal, 5–9% for the high strength, and 4–12% for the... 

The advantages of fiber reinforced polymer (FRP), such as high specific strength, resistance against corrosion and formability, have made it a more acceptable alternative to conventional materials regarding repairing and retrofitting of structures. Although investigations in recent years have proved the concern of civil engineers about the environmental effects on the bond between FRP and concrete or masonry (especially moisture and temperature), only few researches have been reported on FRP-wood interfaces. This research investigated the effect of five different environments on the bond at the interface between FRP and wood. A series of pull-out tests were performed on 375 wood specimens... 

The unusual monosaccharaides such as deoxy-hexose sugars, including methyl-pentose and aldo-pentose, are promising and important sugars in life science. However, little research on H-bond interactions in these systems has been reported. The aldo-pentose has a proton instead of the CH2OH group on C5; conversely, methyl-pentose has a CH3 group on C5. The aim of the present study is to investigate the role and nature of intramolecular H-bonds on acidity of CH3-pentose sugars (L-fucose and L-rhamnose) and aldo-pentose sugars (D-xylose, L-lyxose, D-ribose, and L-arabinose) using B3LYP/6-311++G (d, p) level. The calculated acidity values (ΔHacid) of these Dexoy-hexose were found to be from 343 to... 

The effect of grit blasting parameters on the surface roughness of Ti-6Al-4V alloy as the substrate for plasma-sprayed hydroxyapatite (HA) coatings was examined using the factorial and Taguchi designs of experiments. In this study, two grit materials (Al2O3 and SiO2) each at two sizes, and two types of blasting systems (pressure and suction) were used. An equivalent surface roughness of 3.51 μm was obtained in three optimum conditions. The results of the Taguchi designed experiments were analyzed using signal to noise ratio. The tensile bonding strength of HA coatings deposited on the roughened substrates at the three different optimum conditions was measured by the standard adhesion test... 

The bond of fiber-reinforced polymer (FRP) reinforcement is expected to be more sensitive to the strength and geometry of the ribs than conventional steel reinforcement. In this study, the effect of carbon fiber mat anchorage on the pullout behavior of glass fiber-reinforced polymer (GFRP) bars embedded in normal concrete is studied. The studied parameters were the compressive strength of the concrete (16 MPa, 24 MPa, and 37 MPa), and, the length and diameter of the anchorage. In total, 15 variables were studied. Ribbed GFRP bars with 10 mm nominal diameter and 80 mm embedment length, ld, (which is 8 times the bar diameter) were considered. Based on the results for concretes with the... 

Bromophenols are known as antioxidant radical scavengers for some biomolecules such as those in marine red alga. Full understanding of the role played by bromophenols requires detailed knowledge of the radical scavenging activities in probable pathways, a focus of ongoing research. To gain detailed insight into two suggested pathways, H-atom transfer and electron transfer, theoretical studies employing first principle quantum mechanical calculations have been carried out on selected bromophenols. Detailed investigation of the aforementioned routes revealed that upon H-atom abstraction or the electron transfer process, bromophenols cause an increase in radical species in which the unpaired... 

Accumulative roll bonding (ARB) is used as a novel method to produce particle reinforced metal matrix composites (MMCs). Roll bonding of the sheets with layers of powder on their surfaces is the main stage in this process and it has been found that quality of the bonding has an important role in properties of the product. In this work, the behavior of alumina particles layer at interface during the rolling is investigated and the effects of particle size and amount of particle at interface on bonding of the commercial pure aluminum sheets are also studied. The results of peeling test indicate that presence of the powder at interface reduces the bond strength. However, it is shown that by... 

The aim of this work is to produce two layered thin-walled Cu/Al composite tube by the spin-bonding process. The process is utilized to bond the aluminum tube into the copper one at thickness reductions of 20-60% and process temperatures of 25°C, 130°C, and 230°C. The bond strength is measured by T-peeling test, and the bond interfaces are examined by metallography and scanning electron microscopy (SEM). The results show that after a threshold thickness reduction of about 30%, the bond strength increased with the amount of deformation. SEM fractography of the peel surfaces confirms that the copper oxide film is broken in a shear manner during deformation. Severe shear strains applied during... 

The effects of intermediate nickel layer on seal strength and chemical compatibility of seal glass and interconnect materials for solid oxide fuel cells (SOFCs) were investigated. Two types of samples (metal/glass/metal sandwiches and glass coated metals) were prepared with the sheet of AISI 430 (nickel plated and uncoated) and slurry of compliant silicate sealing glass (SCN-1). The joined and coated samples were heated at 850 °C for different time durations (0.5-100 h). Tensile and impact tests were performed and SEM micrographs were used to analyze the glass/metal interaction. The results indicate that nickel plated AISI 430 shows higher adhesion strength at short durations of heating due... 

HAp and HAp/ZrO2 composite coatings were successfully electrodepesited on 316L stainless steel substrates in the solutions containing ZrO2 particles at different concentrations. The effects of ZrO2 content on characteristics of the coatings were investigated using X-ray diffraction (XRD), Fourier transform infrared spectra (FT-IR), scanning electron microscopy (SEM) and bonding strength test. Polarization and electrochemical impedance spectroscopy measurements were carried out in order to evaluate corrosion behavior of the coatings. In-vitro test in SBF and further SEM observations were performed to examine bioactivity of the coatings. HAp/ZrO2 composite coatings showed better... 

Gold nanoparticles (Au NPs) were synthesized by co-deposition of RF-sputtering and RF-PECVD from acetylene gas and Au target on the carbon nanotubes (CNTs). The CNTs were prepared by thermal chemical vapor deposition (TCVD) and Pd nanoparticles catalyst. TEM image shows that high-density and uniform distribution of Au NPs were grown on the CNTs. XRD analysis indicates that Au NPs have fcc crystal structure and CNTs have a good graphite structure. Raman spectroscopy results suggest that our sample includes double-walled CNTs. It is resulted that intensity of D-band reduces and G-band intensity raises and radial breathing mode (RBM) is changed by immobilizing of Au NPs on the CNTs. Raman...