Sharif Digital Repository

Recently nanostructure materials have used in various technologies and hence an extensive part of research focused on preparing and optimization of growth of nanostructure materials. Usually common procedure is based on a two-step process. First, construction a pre-layer by means of different deposition methods and then formation a nanostructure with a thermal treatment which increases the cost of research. Hence with one step method such as glancing angle deposition (GLAD ( it is possible to form a desirable structure with low cost. In this research Nano columns of tungsten was deposited on Si(133) by means of GLAD-RF sputtering without any heat treatment at substrate rotational speed ( )... 

Catalytic Reforming is a chemical process to convert naphtha feed stock into aromatic hydrocarbons and high-octane products. This process firstly was used in 1940s and since then has been considering as one the main units in oil refineries. It involves several complicated reactions which occur at high temperature and pressure in three or four series of reactors. There are various technologies for regeneration of the catalysts. The latest technology for this process is continuous catalytic regeneration.
The aim of this study was to optimize the catalytic reforming process by minimizing the deposited coke on catalyst surface and maximizing the octane number. To reach this aim, the... 

In this research, metal oxides and hydroxides with carbon materials and conductive polymers (CPs), as well as transition metal oxysulfide nanostructures (TMOS), hybrid of Tin oxide and sulfie and polyphasphate-reduced graphene oxide (PPO-RGO) have been used as an active electrode materials for supercapacitors. In the first section of thesis, Tiron and graphene oxide (GO) were used as an anionic dopants to increase the capacity and stability of polypyrrole (PPy). In order to increase the capacity of Tiron/PPy/GO nanocomposite, vanadium oxide (V2O5) was used. The Tiron/PPy/GO/V2O5 nanocomposite was deposited on a stainless steel (SS) as a substrate via one-step electrochemical deposition... 

Formation, precipitation and deposition of heavy organic compounds of petroleum fluids including, but not limited to, asphaltene in oil reservoirs and production systems have been by far the most important and challenging flow assurance problems. Therefore, preventative actions to control organic deposits in oil formations and production systems which can lead inevitably to reduction or cessation in production, have always been a main challenge for oil producers.In this thesis, a one dimensional simulator have been developed to study asphaltene precipitation, aggregation and deposition in an oil well column at isothermal and non-isothermal conditions. While the previously proposed PC-SAFT... 

In this thesis, by focusing on the hydraulics of three phase flow in vertical tubing to investigate asphaltene deposition problem, the solid particles behaviors in a turbulent flow is fully studied. Reasonable size distribution for particles (based on previous works and researches) was assumed and a model for 2 sections of a Marrat oil field well to evaluate their asphaltene deposition problem was developed. Three phase liquid-gas-solid flow in the well tubing was simulated. Asphaltene deposition profile on the well tubing, mean and maximum of the deposition rate and particle concentrations in the flow regime were calculated and compared with real field data. Better agreement with field data... 

During 1980s Additive Manufacturing technologies for the purpose of prototyping with fast and less expensive, under the name of Rapid Prototyping was invented. But nowadays under the vast progress made in this field, it possesses a notable place in different industries such as automobile manufacturing, aerospace, architecture, medicine and so on for part manufacturing. In all AM machines, the CAD model design part is manufactured by adding layered to each other. In this research, at first by explaining manufacturing process and current different technologies, the place of this manufacturing process in today and future industry, is analyzed. For discussing replacement of this method instead... 

Crude oil is made up of dozens of chemicals which based on their structural similarity, SARA test separate it into four categories: saturates, aromatics, resins and asphaltene. Asphaltenes are recognized as the largest, heaviest and the most polarizable fraction of the crude oil which are in thermodynamic equilibrium with oil at reservoir conditions. Each of the physical, chemical, electrical or mechanical disruption of this balance during production can result in instability and asphaltene precipitation may occur and eventually led to deposition in the reservoir, wells, pipelines, etc. Due to the fact that most changes in temperature and pressure will generated in the wells, thus... 

Carbon nanotubes, due to their extraordinary electronic and physical properties, have attracted much attention in the last decade. Some of their potential applications are in CNT-field effect transistor, field emission devices, physical and chemical sensors, micro and Nanoelectromechanical systems and Nano antenna. In this thesis, we have first reviewed some features of carbon nanotubes and the advantages of PECVD method compared with thermal CVD. In the second part the role of some of the materials (such as H2/NH3/C2H4) in CNT growth are studied. We created a square pattern on the silicon wafer by photolithography. Afterwards, titanium and nickel deposition is done on the mentioned pattern.... 

Nowadays, silicon based devices especially carbon nanotubes received lots of attentions and advancement from researchers and industries. Because of amazing electrical and mechanical properties and wide range of applications, CNTs are received a lot of attention from nanoelectronics experts. There are lots of CNT growth methods such as: Arc Discharge, Laser Ablation, Surface Decomposition, CVD and PECVD.
In this thesis, we are going to use PECVD method to synthesis CNT. A typical PECVD system includes two parallel electrodes that have been packed in vacuum chamber and gases like argon, hydrogen and NH3 are introduced to chamber as a reactant gas.
In this thesis, firs we had fixed... 

In First part, the electrophoretic deposition method was utilized to immobilize TiO2 particles on stainless steel substrates. In addition, for the first time, statistics-based experimental design using response surface methodology (RSM) was employed to investigate the effect of four key coating parameters (i.e. applied voltage, calcination temperature, photocatalyst weight percentage, and deposition time) on the photocatalytic degradation. Analysis of variance revealed that the proposed model was adequate. X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to evaluate the effects of the parameters on degradation efficiency. The optimum applied voltage, calcination... 

Stormwater-borne solids are a major contributor to water quality degradation. A large portion of water quality impaired surface waters is located in urban areas and stormwater runoff is a major source of contamination. Sediments have been identified as the most widespread pollutant in urban river and streams. Water quality of urban streams in Tehran was characterized by determining the PSD, total phosphorus (TP), orthophosphate, NO3, NO2, NH3, TSS, TDS, heavy metals and turbidity in six storm events and base flow. A total of 45 road-deposited sediment (RDS) samples were collected from three different land-use types (residential, intense traffic and educational) in Tehran for characterization... 

Magnesium and its alloys are biodegradable materials with mechanical properties similar to the bone tissue, therefore these materials are suitable for producing orthopedic implants. Unfortunately Magnesium and its alloys are corroded too fast in physiological environment which is the main obstacle for usage of these materials as orthopedic implants. Producing Hydroxyapatite(HA) coatings on surface of Magnesium and its alloys is one of the popular and useful methods for reducing the corrosion rate in physiological environment. HA is a biocompatible and bioactive coating with the ability to bond chemically with the bone tissue and therefore it is largely used as a bioactive coating on the... 

In this work, a novel type electrode based on RuO2 nanoparticles-modified vertically aligned carbon nanotubes (RuO2/MWCNTs) was investigated. ThisRuO2/MWCNTs electrode not only shows a high capacity nature,but also possesses a good response to the pH value. In order to develope this sensor, aligned carbon nanotubes were synthesized by the chemical vapor deposition at first and then modified with RuO2 nanopartcles by sol-gel method. Various parameters affecting the growth of nanotubes, such as substrate type, surface finishing, surface roughness, the growth temperature and carbon feed rate was studiedand and optimal conditions for growth were obtained. At last, aligned nanotubes with a... 

Dye Sensitized Solar cell (DSC) is the third class of solar cell, which consists of a nanocrystalline, mesoporous of semiconductor(The best one is Tio2), covered with a monolayer of dye molecules, platinum coated on FTO as a counter electrode and a redox electrolyte. This Photovoltaic cell which is promising low-cost materials, works on electron separation of dye molecule, and electron injection to semiconductor’s conduction photo- electrode structure and its porosity is affected the DSC’s performance. Recently, use of electrophoretic deposition (EPD) for TiO2 electrode (which best found for photo-electrode in DSC) fabrication has gained increased interests. In this method charged particles... 

Asphaltene deposition, considered as the heaviest and the most polarizable fraction of crude oil, can cause severe problems in oil production and extraction systems. Oil production companies annually bear huge reduction or even cessation in production and, in turn, costs due to asphaltene precipitation and deposition in wellbore or production tubings. To gain more and better insight into asphaltene formation in production systems, the conceptual investigation on the mechanisms of asphaltene adsorption and deposition on a solid surface is indispensable. In this study Asphaltene's particle adsorption and deposition onto the metal surface under the effect of flow is investigated by experimental... 

Asphaltene precipitation and deposition are sources of a number of problems for petroleum industry. Thus, solving the problem of precipitation and deposition is very important. In order to measure deposition level, study of other asphaltene flocculation is vital; since there is a time interval between precipitation and deposition. Use of chemical inhibitors is one of the best methods for prevention of asphaltene precipitation that could postpone precipitation point and prevent formation of huge flocculations. In this study, effects of asphaltene flocculation size on deposition with or without using inhibitors were investigated. In this regard, QCM was used for measuring the amount of... 

In the upstream asphaltene flow assurance community, both academics and industries are actively involved to predict the asphaltene deposit profile in wellbores and pipelines. The main objective of this study is to contribute to the thermodynamic and transport modeling of asphaltene in order to predict its precipitation, aggregation and deposition. For a better knowledge of the flow properties of asphaltene containing crude oils, it is necessary to understand how asphaltene affect the rheological properties. In this work, the information on such rheological properties of oil-asphaltene slurry systems is provided. The results of rheological experiments for two Iranian crude oils show that the... 

In the last decade, a great deal of attention has been paid to the study of synthesis of Nanoparticles, because of the widespread use of this material in applications involving Fuel cells and magnetic devices. In this thesis, we report some interesting features in the electrodeposition of metallic nanoparticles. The electrochemical phase formation of rhenium and nickel on the surface of P-Si (100) substrate plus morphological, topographical and fractal aspects of the accumulated surface were investigated in this research by means of chronoamperometry method and by utilization of AFM and SEM. The nucleation and growth mechanisms on silicon electrode are characterized using cyclic voltammetry... 

In this thesis, Silicon nanowires were synthesized using carbothermal method via Vapor-Liquid-Solid mechanism catalyzed by gold nanoparticles deposited on various substrates. Silicon nanowires just grew on (100) and (111)-oriented silicon substrates. For a particular set of process parameters, we observed a critical thickness of the nucleating gold film, that had depened on a kind of various substrates. We studied the dependence of the Au-Si alloy droplet size and size distribution on the starting gold film thickness and the annealing conditions. We used a modified heating sequence that deconvoluted the effect of various substrates consumption and gas-phase silicon supply on the Au-Si alloy... 

Silicon carbide due to its noticeable mechanical and thermal properties, uses in various industries either main substrate or reinforcement. SiC has low specific surface area according to its resistivity against sintering. Recently, a lot of scientists have been worked on SiC in order to fabricating small ones ; subsequently, better sintering will be achieved. Chemical vapor deposition method (CVD) is a method to produce fine SiC with deposition of products by reacting of initial materials from gas environment. In this study normal CVD as proper method and hydrogen, silicon tetrachloride and activated carbon as initial materials are chosen. Using of iron and nickel catalysts in temperature...