Sharif Digital Repository

Amount of strain has been always considered as the primary parameter affecting the microstructural and strength evolutions during Severe Plastic Deformation (SPD). However, these evolutions unavoidably saturate in large strains under deformation with constant conditions, i.e. constant deformation temperature, strain rate and strain path. In this study, effects of these factors on the microstructural and flow behavior of Ultra-Fine Grain (UFG) aluminum (AA 1050 and AA 5052) processed by Accumulative Roll-Bonding (ARB) are investigated. The flow behavior and its time-dependent aspect are evaluated up to large strains by Plane Strain Compression (PSC) and Stress Relaxation (SR) tests. ... 

Many efforts have been put into increasing the efficiency of dye-sensitized solar cells that part of it has been devoted to structure and chemical composition of photoanode electrode. In this thesis, the effect of changes in the composition and its influence on light scattering ability in photoanode of dye sensitized solar cells was studied.First, the nanoparticles of titanium dioxide powder through solvothermal method as well as spherical particle and barium titanate powder by sol-gel method were synthesized. XRD and FE-SEM analyses indicated that synthesized powders are in good size and morphology regarding the intended chemical composition. Optical properties of TiO2 particles were... 

Regarding high importance of casing pipes in oil industry also considering that they have not been producing domestically (with specific features), the main object of this research is feasibility study of establishment of a casing pipe threading plant which produces such kind of pipes. Usage of Casing PipesIs defining as a separator between wall of oil well and its core. The operation starts with driving and fixing a casing pipe to the oil well to avoid its collapsing during excavation process , then next casing pipes will be driven to the well and will be fixed to the previous pipes. During current research, after gathering all related financial and technical data, evaluation of “Net... 

The Dye-sensitizers loading on TiO2 is decreasing the electron excitation energy and therefore improving the photocatalytic performance from the increasing the sensitivity under visible light irradiation.in this project CoPCTS , Mordant dye and N3(Ruthenium 535) used as dye-sensitizers. Also The addition of VIII group metals on TiO2 is improving the photocatalytic activity that increasing the photocatalytic reaction rate because of the intermediation role of them for moving the conduction band electrons to electron acceptors and increasing the pair electron-holes long-life that in this case Pt loading used as a VIII group metal. In this project Titanium Isopropoxide as a precursore and... 

During the last five decades, interest in High Speed Marine Vehicleshas been increasing for both commercial and military use, leading to newconfgurations and further development of already existing configurations to fill the gap between the low speed ships by high payload capacity to low construction cost, and high speed aircrafts by low payload capacity to high construction cost. Therfore Wing-In-Ground effect crafts (WIG)were introduced as the new marine vehicles family memberwhich have the potential for payload capacities closer to fast marine crafts and the cost of construction is much lower than aircraftswhile they are capablefly close to the water surface. On the whole, in this... 

Dye-sensitized solar cell (DSSCS) is the third-generation of solar cells based on semiconductors formed between a photo sensitized anode and counter cathode which make a photo electrochemical system. They haven’t been commercially marketed due to their lower efficiency than the previous generations. In order to achieve the higher efficiency, the electron injection and light absorption must be increased. One way to increase electron injection is doping the semiconductor with an external ion to reduce lattice band gap. In this work, we made powder and Nano-structured film of titanium dioxide doped with various molar ratios of Mg by the sol-gel process. The effect of Mg:Ti molar ratio on... 

Structure and morphology of titanium dioxide have an excessive effect on the photovoltaic properties of dye-sensitized solar cells (DSCs). Different approaches have been used to improve the efficiency of these cells. One is using a scattering layer. Studies have been shown that properties of scattering layer such as composition and morphology have great effect on photovoltaic properties of solar cell. In this project, the effect of cubic morphology of TiO2 as a scattering agent in photoanode of DSCs is studied. Titanium dioxide with various morphologies including nanoparticles, solid and hollow cubic structures have been synthesized by solvothermal and hydrothermal methods, respectively. The... 

In this project single sided dye sensitized solar cell is introduced as a new design that has both of electrodes in one side. These electrodes can be separated vertically by a thin insulator layer such as SiO2 or horizontally by lithographic method. First a metallic thin film is patterned by lithography, and then thickened by electrochemical deposition of Chromium. Platinum is electrodeposited on the substrate of counter electrode and a thin spacer layer is deposited on Platinum layer to separate it from Titanium dioxide layer.
In Chapters 1, 2 & 3 basic science and methods which are needed for doing this project is introduced. In chapter 1 material for making a standard dye sensitized... 

Groundwater is the primary source of freshwater in many coastal areas and small islands around the world. The most important hazard to groundwater quality in coastal aquifers is seawater intrusion (SWI) resulting from over pumping, prolonged drought conditions and sea level rise due to climate change impacts. Numerical models of SWI are an important tool in the management of coastal aquifers. However, numerical modeling of SWI is one of the most challenging problems in groundwater hydrology. One of the reasons for the challenging nature of SWI numerical modeling is the relatively large level of uncertainty associated with the estimation of the model input parameters. This study focused on... 

This research investigated the seismic performance of gravity dam in the reliability and sensitivity analysis framework under earthquake loading. The performance criteria were defined using crest displacement and tensile stress. The uncertainty due to the material properties of the dam was considered for the reliability approach, in addition to the different ground motion intensity levels for parametric analysis. The exceedance probability of the limit-state functions was computed for varying threshold values through Mean-Value Second-Moment, First-Order Reliability Method and improved Latin Hypercube sampling. Approximation methods were applied along with the sampling method for considering... 

Considering the extensive developments achieved up to now in the fields of trade and international transportation, as well as the key role of the freight transportation in the economical development of a zone or a country, the present research, titled “A Study of the Trade and Transportation Trends”, was planned. The available data concerning the trade of six types of the goods according to The United Nations Classification (SITC), within the period 1965-2005, have been analyzed in this research. The study has been focused on the Asian Multimodal Network constituted of 31 countries. Trading centre of each country in the selected network is assumed to be located in its capital town. The... 

A two-dimensional, two-phase, nonisothermal model was developed in this work to investigate the water transport characteristic and water distribution in a direct methanol fuel cell (DMFC). Emphasis is placed on exploring the water distribution in different layers of DMF. The water and methanol crossover through the membrane were considered with the effect of diffusion, electro-osmotic drag, and convection. Governing equations including the prton and electron transport, continuity, momentum, species transport for methanol, water, and gases species, and the auxiliary equations are coupled to determine the output parameters. These parameters are the concentration distribution of the species,... 

Tire is one component of the suspension system and has beneficial effects on reducing vibrations caused to the vehicle. This study aims to determine the factors affecting the damping and stiffness of the tire is carried out. The modeling of factors were identified. For testing the modeling effort is to be made to the instruments used to measure the damping and stiffness of the tires. To make the structural static analysis, dynamic and modal was to have sufficient structural strength and the displacements and stresses are sensibly placed. Factors that have influence on the hardness of the ring diameter, the outer diameter of the tire, tire pressure, tire tread depth, tire wall thickness,... 

A numerical algorithm for the optimal design of two components functionally graded materials under thermomechanical loadings is introduced in the present study. It is based on the topology optimization method. The objective function, to be minimized, is defined as the weighted combination of the thermal and mechanical compliance of structure. The design variables are defined as the local volume fractions of contributing phases. The set of constraints includes bound constraints on local volume fractions and a global constraint on the total volume fraction of the matrix phase. The corresponding heat and elasticity equations are solved by the finite element method. The local material properties... 

Atomic force microscope (AFM) has a significant capability of imaging surface topography on an atomic scale. It is also widely used for Nanolithography in MEMS/NEMS (micro/nanoelectromechanical systems). Conventional AFMs consist of a cantilever with a sharp conical or pyramidal tip located at the free end of the cantilever that plays an important role in AFM measurements. Scanning across a surface, AFM interacts with the sample surface through its tip. Although the dynamic behavior of the AFM cantilever is complicated, the researchers have been interested in studying AFM dynamic behavior because it has a great influence on the surface imaging process. The imaging rate and contrast of... 

Atomic force microscope (AFM) has a significant capability of imaging surface topography on an atomic scale. It is also widely used for Nanolithography in MEMS/NEMS (micro/nanoelectromechanical systems). Although the conventional AFMs have a significant capability of nano-scale surface measurements, their probe tips cannot come in close proximity to the sidewalls, no matter how sharp they are. Therefore, no accurate nano-scale measurements at sidewalls and edges can be achieved by these conventional AFMs. In addition, regarding the increasing applications of micro-structures such as micro nozzles, micro gears, micro holes and micro trenches which all of them have sidewalls and edges,... 

Proton precession magnetometers are one of the most sensitive scalar magnetic sensors. Their function is based on Zeeman effect and also nuclear magnetic resonance phenomena. In this project we have designed and implemented needed coils, swithching and signal detection circuits. Because of extremely high sensitivity of this sensor to induced noises and also gradient of earth’s magnetic fileld, detection of precession signal needs design of low noise electronic circuits with special EMC considerations. The implemented system in this project contains different blocks, such as switching circuit and its related control unit, amplifier, filter and frequency meter. Using this system, the obtained... 

Dye-sensitized solar cells (DSSCs) have been intensively studied duringthe last decade as a promising third solar cellgeneration due to their potential low-cost manufacturingprocess. DSSCsare based on a semiconductor (i.e., TiO2), formed between a photo-sensitized anode and an electrolyte. In order to reach high conversion efficiencies, it isimportant to increase the electron injection and opticalabsorption. One promising solution to increase the electroninjection is to decrease the large band gap of TiO2 bydoping a foreign ion into TiO2 lattice.
In the present study, Ag- doped TiO2 powders and films with different Ag:Ti molar ratios are reported. The effect of dopant at.%, annealing... 

In this thesis, we focus on studying and fabrication of doped titanium dioxide electrodes and their application in nanostructured dye sensitized solar cells (DSSCs). For this purpose, non-metallic nitrogen (N) and metallic neodymium (Nd) elements were selected. N-doped titanium dioxide nanoparticles were synthesized via solvothermal method and their structural and optoelectrical properties were investigated in comparison to undoped titanium dioxide synthesized by the same method. Based on the obtained results, doping of titanium dioxide by nitrogen resulted in shifting the Fermi level up-ward, increase in charge carriers density, shift of optical absorbance to higher wavelength, and decrease... 

Because of increasing demands for using of rotating systems in high accuracy and high speed applications, in addition of specific condition of rotating systems, it is necessary to analysis these rotating systems characteristics. In addition to the dimensional and geometrical errors of mechanical system parts and assembly errors, manufacturing quality directly depends on Non Repetitive Run-Out (NRRO) errors; so the results of NRRO errors as an ultra-precision characteristic should be studied in required outputs. In this paper by analyzing dimensional and geometrical tolerances as tolerance zone, the variations of system outputs because of tolerances is calculated in both static and dynamic...