Sharif Digital Repository

Nowadays precise nano positioning plays an important role in micro systems. Precise positioning at nano scale plays a basic role in nano science such as micro -robotics, solid state physics and photonics. Manipulating matter in a molecular scale creates a dramatic change and restruturing in macro scale engineering. During this research a novel TEM micro actuator is designed and fabricated based on calibration criteria. This structure was fabricated with SOI wafer (silicon on insulator) in micro scale level for the first time in Iran. This compliant consists of 12 TEM actuators end in 3DOF (In-plane) motion. The new micro actuator operates based on the thermal expansion due to voltage. Each... 

The band gap offset is an effect of coordination numbers (CNs) of atoms reduction at the edge of transversal cross-section Si nanowires (SiNWs) which would be of increasingly important for greater shell-core ratio sections. In this paper, a hierarchical multi-scale modeling has been developed to simulate edge effect on the band gap shift of SiNWs due to geometry effect induced strain in the self-equilibrium state. Classical Molecular Dynamics (MD) approach and Finite Element Method (FEM) are used in the micro (atomic) and macro scale levels, respectively. Using the Cauchy-Born (CB) hypothesis as a correlator of continuum and atomic properties, the atomic positions are related to the... 

Nuclear energy is one of the most important sources of energy from the economical point of view and also in terms of cleanliness and safety. Hence, strategically, uranium is one of the most basic elements of the earth and nowadays, the importance of this element is more marked due to the nuclear industry developement. Therefore, uranium recovery from the wastes generated during nuclear fuel production in Isfahan’s uranium conversion plant- in which yellow cake is converted to uranium hexafluoride- is quite pivotal. In this experimental research, we have to remove Fluoride from waste after dissolution by several methods like precipitation. After that uranium is extracted from the sludge of... 

In this study, to synthesize molybdenum disilicide nano powder, mixed powder of Mo and Si were ball milled for 15, 30, 45 and 55 hours. By the results of the analyses, milled powders for time intervals of 55 hours were heat treated to release the stresses. This process was carried out in an argon vacuum tube furnace at 1000˚C for 1 hour. XRD analysis was carried for sample. Finally, MoSi2 powder with 86.62 nm crystallite size was used as reinforcement. Cu-MoSi2 composite powder with 2, 3, 5wt% were produced. Cu-MoSi2 with 2wt% reinforcement was milled for 60 hours. Powder composite was compacted by Spark Plasma Sintering . Microstructure of composite was investigated by scanning electron... 

Silicon carbide due to its noticeable mechanical and thermal properties, uses in various industries either main substrate or reinforcement. SiC has low specific surface area according to its resistivity against sintering. Recently, a lot of scientists have been worked on SiC in order to fabricating small ones ; subsequently, better sintering will be achieved. Chemical vapor deposition method (CVD) is a method to produce fine SiC with deposition of products by reacting of initial materials from gas environment. In this study normal CVD as proper method and hydrogen, silicon tetrachloride and activated carbon as initial materials are chosen. Using of iron and nickel catalysts in temperature... 

In this thesis, Silicon nanowires were synthesized using carbothermal method via Vapor-Liquid-Solid mechanism catalyzed by gold nanoparticles deposited on various substrates. Silicon nanowires just grew on (100) and (111)-oriented silicon substrates. For a particular set of process parameters, we observed a critical thickness of the nucleating gold film, that had depened on a kind of various substrates. We studied the dependence of the Au-Si alloy droplet size and size distribution on the starting gold film thickness and the annealing conditions. We used a modified heating sequence that deconvoluted the effect of various substrates consumption and gas-phase silicon supply on the Au-Si alloy... 

Metal matrix composites (MMC) and metal foams (MF) have been the topic of numerous researches during the last decades. The appropriate mechanical and physical properties of these materials make them useful in various industries. In this research, a unique approach is introduced for producing MMCs and MFs in which accumulative roll bonding (ARB) is employed in order to achieve a homogeneous distribution of ceramic particles in the metal matrix. Also, foamed structures can be made by subjecting Al/TiH2 composite to an appropriate annealing heat treatment where TiH2 particles decompose to hydrogen and titanium. In this work, the effect of number of ARB cycles on the size and distribution of... 

The photovoltaic (PV) industry is in rapid growth and a large supply of PV feedstock materials must be provided to maintain this growth. Since silicon is still the dominant material for the fabrication of solar cells, low-cost solar-grade silicon (SoG-Si) feedstock is demanded. The most cost-effective and direct approach for producing SoG-Si is to purify and upgrade metallurgical-grade silicon. The major impurities in silicon are Al, Fe and Ca. other impurities present are Cu, Ti , Zn, Ni, Cr, Mn, Cd, B and P. In this study The effects of the acid leaching process parameters, including the particle size of silicon, the acid type (HCl, HNO3, H2SO4, and their combination), tmepreture and the... 

The silicon vacancy in silicon carbide is a strong emergent candidate for applications in quantum information processing. 4H, 6H and 3C polytypes of SiC all host coherent and optically addressable defect spin states. Electron paramagnetic resonance (EPR) and optically detected magnetic resonance (ODMR) investigations suggest that silicon vacancy point defects in SiC possess properties similar to those of the NV center in diamond. We provide a new theoretical frame to explain a wider range of experimental results. Employing a proposed generalized Hubbard model, with the help of electronic structure programs, DFT, second quantization, and various computational approaches, we obtain new... 

Since 2005, processor designers have increased core counts to exploit Moore’s Law scaling, rather than focusing on single-core performance. For decades, this approach provides desired performance for parallel and multithreaded workloads. On the other hand, rising of utilization wall limits the number of transistors that can be powered on in chip and result in a large region to be dark. So, same as before trend for performance scaling in future multi processor, an appropriate architecture is essential. There are some structures for this era which used specialization approach to cope with the limited power budget. Therefore, in this thesis, we propose a general-purpose platform that provides... 

Optical computing has emerged as a promising candidate for real-ime and parallel continuous data processing. Optical devices that perform spatial and spatiotemporal transformations of optical signals are of great interest for a wide range of applications including ultrafast all-optical information processing and analog optical computations. Although plasmonic metasurfaces(for analog computing applications) was investigated in the past, they are not realizable. Consequently the silicon photonics is a good alternative for realizing these applications.Firstly, the optical computing and its important features explained and a common architecture was introduced. in addition, another two structures... 

Due to outstanding advantages of polymeric insulators such as: hydrophobicity, impact resistance and lower weight, their application in the high voltage transmission and distribution lines is increased significantly, in recent years. The most important feature of these insulators is their hydrophobicity. Contamination and aging are some of the factors that weaken this important feature and reduce the reliability of these insulators. Due to aging effects partial discharges start on the surface of the composite insulators and increase by impact of external factors. This thesis examines the occurrence of partial discharge signals on polymeric insulators under: varying amounts of contamination,... 

Electricity distribution companies always strive to operate the power network efficiently and reliably so that their network be able to satisfy the growing needs for electricity. To achieve these goals in a power network, a comprehensive asset management plan with a sound policy for inspection, periodic maintenance, replacement, and disposal of depreciated equipment is required. One of the high-risk sectors of the electricity grid is the insulation section of distribution and transmission lines. In recent years, composite insulators have been used more widely because of their desirable characteristics such as: hydrophobicity, lower price, and lower weight if compared with the another... 

The new generation of electronic devices including 5G internet, wearable electronics, LED optoelectronics or cloud computing devices have higher power density as their computing power increases and their sizes reduce. The increase in power density leads to higher heat generation and consequently higher operating temperature which reduces their lifetime and reliability. In recent years development of novel solutions for electronic cooling has been persued. Thermal interface material that inserted between heat source and heat sink is the main component in electronic cooling. These materials consists of a polymeric base that filled with highly thermally conductive solid particles. By emergence... 

The development of new wrought magnesium alloys for automotive industry has increased in recent years due to their high potential as structuralmaterials for low density and high strength/weight ratio demands. However, the poor mechanical properties of the magnesium alloys have led tosearch a new kind of magnesium alloys for better strength and ductility.In this research,a new type of magnesium alloy based on Mg-Zn-Si-Ca system has been developed using the permanent gravity casting process. For comparison, an alloy without Siby the same method was also produced. The effects of trace Si addition on the microstructure and mechanical properties in magnesium alloy with composition of... 

Many researches have been made on super hydrophobic and photocatalyst nano coatings in the last decades as a solution to some environmental issues. Among all semiconductors chosen for this property, titanium dioxide is often used because of it's low cost, ease of accessibility and stability in different chemical circumstances to break up organic pollutions. Mixing this property of TiO2 with hydrophobic manner of SiO2 causes a superhydrophobe & photocatalyst nano coating. Doping TiO2 with another semiconductor may also improve photocatalytic behavior of coating by increasing surface area of reaction or decreasing the band-gap.In this research TiO2-SiO2 hybrid nano coating is made via... 

By employing first principles density functional theory-based (DFT) molecular dynamics (MD), the influences of dangling and floating bonds as well as distorted tetrahedral bonds are studied on the mechanical, physical, and electronic properties of amorphous Si (a-Si). For further examination of the effects of these geometrical defects, two distinct amorphous samples, namely as-quenched and annealed are generated and examined. To verify the validity of the representative cells, the obtained radial distribution function, pair correlation function, and cohesive energy are compared with those corresponding results presented in the literature. Moreover, the surface energy is calculated at final... 

Accumulative roll bonding has been used as novel method to produce the composite with ultra fine grain microstructure. This method has two steps, impose the particles as reinforcement between the layers by roll bonding process and then distribute the particles in matrix and generat an ultra fine grain microstructure during the ARB passes. In the present work, ARB process was performed to produce the Al/SiC and Al/Al2O3 nano-composites with various particles size and different volume fraction of reinforcement. Microscopic observations such as OM, SEM and TEM and XRD analyses were used to investigate the microstructure of produced composites and the distribution of the particles in matrix... 

In this thesis, the thermal and thermoelectric properties of graphene-based nanostructures are numerically investigated. The transport parameters, including Seebeck coefficient, electrical conductance, and thermal conductance are obtained as well as the thermoelectric figure of merit. The Hamiltonian matrix is set up using a third nearestneighbor atomistic tight-binding approximation and the dynamical matrix using a 4th nearest neighbor force constant approximation. Both ballistic and diffusive regimes are considered in this work. For transport investigation, the Landauer formula and the nonequilibrium Green’s function techniques are used. The role of temperature, geometrical parameters,... 

According to the creation of high-rise buildings and structures due to the increase in urbanization and population concentration in cities and attention to the beauty of these structures and the impact of this beauty on the morale of urban people, owners or municipalities costs a lot of money for cleaning the building facade every year. On the other hand, removing contaminants from high-rise buildings facades is difficult and lifethreatening. Today, with the advancement of science and the use of self-cleaning super hydrophobic coatings, many of these costs, as well as threats to life, can be prevented. On the other hand, protection of ancient structures as a cultural capital of a country,...